Development of aerosol optical properties for improving the MESSy photolysis module in the GEM-MACH v2.4 air quality model and application for calculating photolysis rates in a biomass burning plume

The photolysis module in Environment and Climate Change Canada's online chemical transport model GEM-MACH (GEM: Global Environmental Multi-scale – MACH: Modelling Air quality and Chemistry) was improved to make use of the online size and composition-resolved representation of atmospheric aerosols and relative humidity in GEM-MACH, to account for aerosol attenuation of radiation in the photolysis calculation. We coupled both the GEM-MACH aerosol module and the MESSy-JVAL (Modular Earth Submodel System) photolysis module, through the use of the online aerosol modeled data and a new Mie lookup table for the model-generated extinction efficiency, absorption and scattering cross sections of each aerosol type. The new algorithm applies a lensing correction factor to the black carbon absorption efficiency (core-shell parameterization) and calculates the scattering and absorption optical depth and asymmetry factor of black carbon, sea salt, dust and other internally mixed components. We carried out a series of simulations with the improved version of MESSy-JVAL and wildfire emission inputs from the Canadian Forest Fire Emissions Prediction System (CFFEPS) for 2 months, compared the model aerosol optical depth (AOD) output to the previous version of MESSy-JVAL, satellite data, ground-based measurements and reanalysis products, and evaluated the effects of AOD calculations and the interactive aerosol feedback on the performance of the GEM-MACH model. The comparison of the improved version of MESSy-JVAL with the previous version showed significant improvements in the model performance with the implementation of the new photolysis module and with adopting the online interactive aerosol concentrations in GEM-MACH. Incorporating these changes to the model resulted in an increase in the correlation coefficient from 0.17 to 0.37 between the GEM-MACH model AOD 1-month hourly output and AERONET (Aerosol Robotic Network) measurements across all the North American sites. Comparisons of the updated model AOD with AERONET measurements for selected Canadian urban and industrial sites, specifically, showed better correlation coefficients for urban AERONET sites and for stations located further south in the domain for both simulation periods (June and January 2018). The predicted monthly averaged AOD using the improved photolysis module followed the spatial patterns of MERRA-2 reanalysis (Modern-Era Retrospective analysis for Research and Applications – version 2), with an overall underprediction of AOD over the common domain for both seasons. Our study also suggests that the domain-wide impacts of direct and indirect effect aerosol feedbacks on the photolysis rates from meteorological changes are considerably greater (3 to 4 times) than the direct aerosol optical effect on the photolysis rate calculations.

Drainage Development in the Dunhuang Basin, NE Tibet, Controlled by Multi-Segment Fault Growth

The Dongbatu Shan (DBTS, also known as the Nanjie Shan), which interrupts the northern Tibetan foreland in the Dunhuang basin, is an active anticline. It has accommodated the northwestern growth of the eastern Altyn Tagh fault system (ATF). Although several thrust faults have been identified around the DBTS, their evolution history and influence on regional landscape have received little attention during the late-Quaternary. In this study, several geomorphic methods are used to investigate the interaction between drainage development and tectonic movement around DBTS. Based on high-resolution satellite images, field investigation, and cosmogenic nuclide 10Be dating method, the fluvial landform sequences around DBTS were constructed. Using quantitative geomorphology methods including landscape relief profile, asymmetry factor (AF), and transverse topographic symmetry factor (T), we hypothesize that drainage deflection is controlled by multi-segment fault growth. Combining the results of the above-mentioned methods, we propose that Yulin He, flowing across the DBTS, had gone through several abandonments since the late mid-Pleistocene due to the lateral propagation of DBTS. Affected by the discharge of channel and multi-segment fault growth, our research confirms that the direction of river abandonment may have decoupled with the mountain range propagation trend. Based on the chronology dating, the DBTS has gone through two severe uplifts since ∼208 ka and the shortening rate across the central DBTS is constrained to be ∼1.47 mm/yr since ∼83 ka. Given the fact that thrust faults are widely developed around DBTS, we propose that the flower-like structure formed by the northward growth of the eastern ATF could better explain the development of the secondary subparallel faults.

Impact of the Atmospheric Photochemical Evolution of the Organic Component of Biomass Burning Aerosol on Its Radiative Forcing Efficiency: A Box Model Analysis

We present the first box model simulation results aimed at identification of possible effects of the atmospheric photochemical evolution of the organic component of biomass burning (BB) aerosol on the aerosol radiative forcing (ARF) and its efficiency (ARFE). The simulations of the dynamics of the optical characteristics of the organic aerosol (OA) were performed using a simple parameterization developed within the volatility basis set framework and adapted to simulate the multiday BB aerosol evolution in idealized isolated smoke plumes from Siberian fires (without dilution). Our results indicate that the aerosol optical depth can be used as a good proxy for studying the effect of the OA evolution on the ARF, but variations in the scattering and absorbing properties of BB aerosol can also affect its radiative effects, as evidenced by variations in the ARFE. Changes in the single scattering albedo (SSA) and asymmetry factor, which occur as a result of the BB OA photochemical evolution, may either reduce or enhance the ARFE as a result of their competing effects, depending on the initial concentration OA, the ratio of black carbon to ОА mass concentrations and the aerosol photochemical age in a complex way. Our simulation results also reveal that (1) the ARFE at the top of the atmosphere is not significantly affected by the OA oxidation processes compared to the ARFE at the bottom of the atmosphere, and (2) the dependence of ARFE in the atmospheric column and on the BB aerosol photochemical ages almost mirrors the corresponding dependence of SSA.

Morpho-Tectonic Assessment of the Abu-Dabbab Area, Eastern Desert, Egypt: Insights from Remote Sensing and Geospatial Analysis

The Abu-Dabbab area, located in the central part of the Egyptian Eastern Desert, is an active seismic region where micro-earthquakes (≈ML < 2.0) are recorded regularly. Earthquake epicenters are concentrated along an ENE–WSW trending pattern. In this study, we used morphological indexes, including the valley floor width-to-valley floor height ratio (Vf), mountain front sinuosity (Smf), the asymmetry factor index (Af), the drainage basin shape index (Bs), the stream length–gradient index (SL), hypsometric integral (Hi) water drainage systems, and a digital elevation model analysis, to identify the role of tectonics. These indexes were used to define the relative tectonic activity index (RTAI), which can be utilized to distinguish low (RTAI < 1.26), moderate (RTAI = 1.26–1.73), and high (RTAI > 1.73) tectonic activity signals all over the study area. Firstly, our results indicate low to medium tectonic activity and general anomaly patterns detected along the major tectonic zones of the study area. Secondly, based on most of the low to medium tectonic activity distributed in the study area and the detected anomalies, we discuss two potential drivers of the seismicity in the Abu-Dabbab area, which are fault-controlled and deep-rooted activities.

Vertical profile of the clear-sky aerosol direct radiative effect in an Alpine valley, by the synergy of ground-based measurements and radiative transfer simulations

Atmospheric aerosols play an important role in Earth’s radiative balance, directly interacting with solar radiation or influencing cloud formation and properties. In order to assess their radiative impact, it is necessary to accurately characterise their optical properties, together with their spatial and vertical distribution. The information on aerosol vertical profile is often scarce, in particular in mountainous, complex terrains. This study presents the first attempt to evaluate the shortwave aerosol direct radiative effect in the Aosta Valley, a mountainous region in the Northwestern Italian Alps. Ground-based, remote sensing instruments (a sky radiometer and an Automated Lidar Ceilometer) are used to derive two descriptions of the aerosol properties and vertical distribution: a first, more accurate description, which includes the whole spectral information about the aerosol extinction coefficient, phase function and single scattering albedo; a second, more approximate one, which only relies on spectrally constant values of aerosol single scattering albedo and asymmetry factor. This information is used as input for radiative transfer simulations, which allow to estimate, in cloudless conditions, the shortwave aerosol direct radiative effect and the vertical profile of the instantaneous heating rates in the lower layers of the atmosphere. The simulations obtained with the two descriptions do not differ significantly: they highlight a strong surface dimming (between − 25 and − 50 W m− 2) due to the presence of aerosol, with a considerable radiative absorption inside the atmospheric column (around + 30 W m− 2), and an overall small cooling effect for the Earth-atmospheric system. The absorption of solar radiation within the atmospheric column due to aerosol leads to instantaneous heating rates up to 1.5 K day− 1 in the tropospheric layers below 6 km a.s.l. These results show that, in some conditions, the shortwave aerosol direct radiative effect can be considerable even in this Alpine environment, usually considered as relatively pristine (yearly average PM10 concentration about 20 μg m− 3).

Determination of Folic Acid in Multivitamin Preparations by Reversed Phase HPLC

A great variety of components in multivitamin preparations containing folic acid, and a variety of test methods and conditions of folic acid determination proposed by manufacturers, require alignment of test procedures for products with similar composition.The aim of the study was to compare the results of experimental verification of folic acid determination procedures which use reversed phase high-performance liquid chromatography (RP HPLC) with isocratic elution mode. Materials and methods: The Agilent 1260 Infinity II LC system with a diode array detector (280 nm), isocratic elution mode, C8- and C18-bonded silica gel chromatographic columns, model mixtures containing folic acid, cyanocobalamin, ferrous sulfate, and potassium iodide, were used in the study.Results: The lowest relative standard deviation of the folic acid peak area (RSD=0.09%), and the lowest asymmetry factor (As=1.04) for folic acid were observed for the model mixture “ferrous sulfate+folic acid+cyanocobalamin” and the following test conditions. Column: 250×4.0 mm, silica gel for chromatography, octylsilyl (C8), endcapped; mobile phase: methanol‒phosphate buffer (12:88), pH 6.6; column temperature: 25ºС. The study demonstrated the feasibility of using these conditions for determination of pteroic acid impurity with simultaneous precipitation of interfering ferrous ions, using ethylenediaminetetraacetic acid solution, pH 9.5, as a solvent.Conclusions: RP HPLC can be recommended as an optimal aligned test procedure for determination of folic acid in combination products. It is recommended to use a solution containing folic and pteroic acids for system suitability testing.

Using morphometric and geomorphic indices to assess Western São Francisco Craton neotectonic traces

Recently, geomorphometric properties of river networks and catchments have been described and applied as an efficient tool in the investigation of the landforms' response to neotectonics. Geometric parameters of the Cotovelo River catchment extracted from an Alos-Palsar digital elevation model were used to compute morphometric and geomorphic indices to investigate whether the bedrock structure and recent active tectonics influence the local drainage network. The Cotovelo catchment is situated in the Middle to Upper Proterozoic western foreland basin of the São Francisco craton, in northwestern Minas Gerais, Southeastern Brazil; it is presumed to be a stable piece of earth’s crust. The automatically generated streams were processed at the sub-catchment scale to calculate the hypsometric integral, relief ratio, stream frequency, and drainage density morphometric indices as well as supported a geomorphic study based on the basin shape, asymmetry factor, valley floor width-to-height ratio, mountain front sinuosity, transverse topographic symmetry factor, and stream-length gradient index. Achieved results revealed recent and low-rate tectonic activity and structural control on the fluvial morphology. Prominent knickpoints, aligned with mapped fault scarps, disclose straight erosive fronts away from stratigraphic borders, indicating these features are unrelated to lithological changes. Despite the catchment location, the area exhibits impressive fluvial anomalies, and dissection occurs preferentially along ancient faults and fractures densely occurring in the rocky strata. Channel parallelism in context of medium to high relief and steep slopes, remarkably structurally drive fluvial dissection, asymmetric and elongated drainage catchments, and aligned landforms suggest neotectonic influence on the drainage network.

On the asymmetry of cyclones and anticyclones in the cellular regime of rotating Rayleigh-Bénard convection

Rotating Rayleigh-Bénard convection (RRBC) denotes the free convection between two parallel plates with a fixed temperature difference, placed in a rotating reference frame. It is a prototype model of geophysical and astrophysical convection. Rotation breaks the symmetry on its rotating axis, making the cyclones and anticyclones unequal in size and magnitude. Such an asymmetry has long been observed in experiments and simulations, but has not been explained with any theoretical model. A theory of such vorticity asymmetry is proposed specifically for the cellular regime, where background rotation is important and convection is weak. The property that columnar updraft and downdraft plumes are densely packed is shown to make the vertical vorticity profile at the vortex center approximately linear with height via thermal wind relation. This simplification of morphology enables a linkage between the vorticity strength of a plume which is quantified by vorticity Rossby number $\mathrm{Ro_V}$, and the vorticity magnitude difference between the cyclonic and anticyclonic ends of plumes which is quantified with a nondimensional asymmetry factor $\delta$. The lowest order relationship between $\delta$ and $\mathrm{Ro_V}$ is found to be constrained by vertical vorticity equation alone. An approximate analytical solution is found using asymptotic expansion, which shows that the asymmetry is generated mainly by the vertical advection and stretching of vertical vorticity in fluid interior, and is modified by the Ekman layer dynamics.

Geomorphological and Statistical Assessment of Tilt-Block Tectonics in the Garhwal Synform: Implications for the Active Tectonics, Garhwal Lesser Himalaya, India

Active tectonics is manifested in geomorphological features such as drainage basins and drainage patterns. Geomorphic parameters asymmetry factor (AF) and transverse topography symmetry factor (T) is calculated for 94 third order basins of the Garhwal synform to decipher the tilt-block tectonics based on remote sensing and geographical information system (GIS) techniques. The quantitative analysis of the AF suggests that all the 94 basins are asymmetric and gentle to steeply tilted, indicating active tectonics and early and late stage of development, respectively. The mean vector magnitude (θv) of T suggests the migration of the basin stream towards the south in most basins (60%), suggesting a unidirectional tilting of the tectonic block. The χ2 test for statistical significance indicates that the θv is significant for southern and northern limb basins. The χ2 test affirms that the third order basin position on either side of the main channel of the river basin influences the tilt direction. The regional tectonics suggests migration of the Lansdowne klippe towards the south, as the majority of third order basins show southward tilt. The study provides a quick appraisal of tilting in the tectonic blocks of active margins, such as in the Himalayas.