Preparation of polyaniline in organic liquid crystal solvent

Author(s):  
Ryo Miyashita ◽  
Hiromasa Goto
1996 ◽  
Vol 118 (3) ◽  
pp. 510-515 ◽  
Author(s):  
S. Morishita

This paper describes a new electrically controllable damper that uses a liquid crystal (LC) as the working fluid. LC is a homogeneous organic liquid characterized by the long-range order of its molecular orientation. The sample LC used in this work is a thermotropic, low molecular-weight LC which appears in the nematic phase, and was originally developed for display devices. The molecular orientation of the nematic phase is characterized by slender ellipsoidal shape molecules, the main axis of which can be controlled by applying an electric or magnetic field. When an electric field is applied to a LC, the orientation order of the molecules becomes parallel to the applied electric field, causing the apparent viscosity to increase. This phenomenon is known as the electroviscous effect. To study the application of the electroviscous effect of a LC to a controllable mechanical damping device, a prototype controllable damper was constructed and its performance was examined. In this damper, a piston, equipped with several concentric cylindrical electrodes attached to the piston rod, moves in the liquid crystal. During the reciprocal movement of the electrodes, LC flow through the electrodes is controlled by applying electric voltage to the latter. Damper performance was investigated under various DC electric field strengths, piston oscillation amplitudes and frequencies. The results show that the controllable damping force was three times larger with the application of an electric field than that without, and that the range of force variation was kept at the same level regardless of the frequency and amplitude of piston motion.


2020 ◽  
Vol 16 ◽  
pp. 674-680 ◽  
Author(s):  
Zeguo Fang ◽  
Nawaf Al-Maharik ◽  
Peer Kirsch ◽  
Matthias Bremer ◽  
Alexandra M Z Slawin ◽  
...  

This paper describes the synthesis of a series of organic liquid crystals (LCs) containing selectively fluorinated cyclopropanes at their termini. The syntheses used difluorocarbene additions to olefin precursors, an approach which proved straightforward such that these liquid crystal candidates could be efficiently prepared. Their physical and thermodynamic properties were evaluated and depending on individual structures, they either displayed positive or negative dielectric anisotropy. The study gives some guidance into effective structure–property relationships for the design of LCs containing selectively fluorinated cyclopropane motifs.


Nature ◽  
2002 ◽  
Vol 418 (6894) ◽  
pp. 162-164 ◽  
Author(s):  
Chong-yang Liu ◽  
Allen J. Bard

Tribology ◽  
2005 ◽  
Author(s):  
Yoshiki Matsumura ◽  
Toshihiko Shiraishi ◽  
Shin Morishita

This paper describes the viscosity variation of a liquid crystal under electric field, and its application to a controllable step bearing. Liquid crystal is known as a homogeneous organic liquid characterized by the long-range order of its molecular orientation. When an electric field is applied to a liquid crystal film as lubricant, the orientational order of molecules becomes parallel to the applied field, which causes apparent viscosity variation. In this paper, a controllable step bearing system was constructed and its dynamic characteristics were studied. When a step load, sinusoidal or earthquake excitation was applied to the bearing pad, the film thickness was successfully controlled to the appointed value by a conventional PID controller. The response frequency was also studied in the experiment.


2021 ◽  
Vol 14 ◽  
Author(s):  
Mursyida Abdul Rahim ◽  
Guan-Yeow Yeap ◽  
Wai Kit Tang ◽  
Chi-Kit Siu

: A new series of organic liquid crystal tetramers containing two symmetrical mesogenic units of 4-(4’-phenoxylimino)methyl)phenol joined by methylene –(CH2)m- spacer wherein m varied from 5 to 10 has been synthesized. The length for each of the mesogenic units was extended further via connection with two chiral entities of (S)-2- methylbutyl-4-(4’-bromobutyloxyphenyl)benzoate situated at both terminal ends. The structures of these tetramers were elucidated using elemental analysis and spectroscopic techniques (FT-IR and 1H-NMR) while the texture and the phase transition temperatures were studied using polarizing optical microscopy (POM) along with differential scanning calorimetry (DSC). All the homologues in this series are enantiotropic mesogens exhibiting oily streak texture or fan shaped texture characteristic of chiral nematic phase. The odd-even effect can be observed upon increasing the methylene spacer length. The structure-properties connectivity has demonstrated that the phase transition temperature for tetramers with even- numbered methylene units in the spacer is relatively higher in comparison with the odd- numbered members. The computational study via constraint molecular dynamics performed at the DFTB level of theory has further supported that more energy is required for the even- numbered tetramer than the odd-numbered member to undergo the structural transition from folded to extended geometries.


Sign in / Sign up

Export Citation Format

Share Document