Novel bentonite particle electrodes based on Fenton catalyst and its application in Orange II removal

Author(s):  
Nannan Qiao ◽  
Jiali Chang ◽  
Mengxiao Hu ◽  
Hongzhu Ma
Nanomaterials ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 533
Author(s):  
Jorge González-Rodríguez ◽  
Lucía Fernández ◽  
Zulema Vargas-Osorio ◽  
Carlos Vázquez-Vázquez ◽  
Yolanda Piñeiro ◽  
...  

Today, the presence of recalcitrant pollutants in wastewater, such as pharmaceuticals or other organic compounds, is one of the main obstacles to the widespread implementation of water reuse. In this context, the development of innovative processes for their removal becomes necessary to guarantee effluent quality. This work presents the potentiality of magnetic nanoparticles immobilized on SBA-15 mesoporous silica as Fenton and photo-Fenton catalysts under visible light irradiation. The influence of the characteristics of the compounds and nanoparticles on the removal yield was investigated. Once the key aspects of the reaction mechanism were analyzed, to evaluate the feasibility of this process, an azo dye (Orange II) and an antibiotic (sulfamethoxazole) were selected as main target compounds. The concentration of Orange II decreased below the detection limit after two hours of reaction, with mineralization values of 60%. In addition, repeated sequential experiments revealed the recoverability and stability of the nanoparticles in a small-scale reactor. The benchmarking of the obtained results showed a significant improvement of the process using visible light in terms of kinetic performance, comparing the results to the Fenton process conducted at dark. Reusability, yield and easy separation of the catalyst are its main advantages for the industrial application of this process.


2004 ◽  
Vol 49 (4) ◽  
pp. 85-90 ◽  
Author(s):  
P.L. Yue ◽  
J.Y. Feng ◽  
X. Hu

A laponite RD clay-based Fe nanocomposite (Fe-Lap-RD) has been synthesized by the so-called pillaring technique. The X-ray diffraction (XRD) results reveal that the Fe-Lap-RD mainly consists of Fe2O3 (maghemite) crystallites and Fe2SiO10(OH)2 (iron silicate hydroxide) crystallites, respectively. The photo-catalytic activity of the Fe-Lap-RD for the degradation of an organic azo dye Orange II is examined. It is found that the rate of mineralization of Orange II is slower than that of discoloration. Under optimal conditions, 100% color and 70% total organic carbon (TOC) of 0.2 mM Orange II can be removed in 45 and 90 minutes, respectively. In addition, the performance of a strongly acidic type of ion exchange resin based catalyst as a heterogeneous photo-Fenton catalyst for the degradation of salicylic acid is also discussed.


1992 ◽  
Vol 57 (11) ◽  
pp. 2272-2278 ◽  
Author(s):  
Václav Koula ◽  
Daria Kučová ◽  
Jiří Gasparič

The combination of ion-pair extraction and differential pulse polarography is shown to be a method suitable for the determination of 10-7 mol l-1 concentrations of organic bases of quaternary ammonium compounds. Orange II (4-[2-hydroxy-1-naphtyl]azobenzenesulfonic acid) was found to be an appropriate polarographically active counter-ion. The proposed method was used for the determination of tetrapentylammonium bromide (as model compound), Septonex ([1-(ethoxycarbonyl)-pentadecyl]trimethylammonium bromide) and codeine.


2011 ◽  
Vol 340 ◽  
pp. 236-240
Author(s):  
Jian Feng Ma ◽  
Jian Ming Yu ◽  
Bing Ying Cui ◽  
Ding Long Li ◽  
Juan Dai

Inorganic-organic-bentonite was synthesized by modification of bentonite by Hydroxy-iron and surfactant, which could be applied in dye removal by adsorption and catalysis. The removal of acid dye Orange II was studied at various factors such as time and pH of solution. The results showed that the inorganic-organic-bentonite could efficiently remove the dye with efficiency of 96.22%. The maximum adsorption capacity is 76 mg/g. The pH of solution has significant effect on both adsorption and catalysis. When pH was 4, the maximum removal efficiency of adsorption and catalysis were 97.57% and 87.23%, respectively. After degradation, the secondary pollution was diminished and the bentonite could be reused.


2021 ◽  
pp. 129741
Author(s):  
Yingying Sun ◽  
Wan Li ◽  
Liqing Zhao ◽  
Fengyong Li ◽  
Yunfei Xie ◽  
...  

Sign in / Sign up

Export Citation Format

Share Document