scholarly journals Investigation of sluggish diffusion in FCC Al0.25CoCrFeNi high-entropy alloy

2021 ◽  
Vol 9 (5) ◽  
pp. 239-246
Author(s):  
Abhishek Mehta ◽  
Yongho Sohn
Keyword(s):  
High Entropy Alloy ◽  
High Entropy ◽  
Sluggish Diffusion

scholarly journals Hydrogen spillover-driven synthesis of high-entropy alloy nanoparticles as a robust catalyst for CO2 hydrogenation

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Kohsuke Mori ◽  
Naoki Hashimoto ◽  
Naoto Kamiuchi ◽  
Hideto Yoshida ◽  
Hisayoshi Kobayashi ◽  
...  
Keyword(s):  
Theoretical Calculations ◽  
Spillover Effect ◽  
Hydrogenation Reaction ◽  
Hydrogen Spillover ◽  
Advanced Materials ◽  
High Entropy Alloy ◽  
High Entropy ◽  
In Situ Techniques ◽  
Wide Range ◽  
Sluggish Diffusion

AbstractHigh-entropy alloys (HEAs) have been intensively pursued as potentially advanced materials because of their exceptional properties. However, the facile fabrication of nanometer-sized HEAs over conventional catalyst supports remains challenging, and the design of rational synthetic protocols would permit the development of innovative catalysts with a wide range of potential compositions. Herein, we demonstrate that titanium dioxide (TiO2) is a promising platform for the low-temperature synthesis of supported CoNiCuRuPd HEA nanoparticles (NPs) at 400 °C. This process is driven by the pronounced hydrogen spillover effect on TiO2 in conjunction with coupled proton/electron transfer. The CoNiCuRuPd HEA NPs on TiO2 produced in this work were found to be both active and extremely durable during the CO2 hydrogenation reaction. Characterization by means of various in situ techniques and theoretical calculations elucidated that cocktail effect and sluggish diffusion originating from the synergistic effect obtained by this combination of elements.

Instant and Persistent Hydrogen Production Using Nano High Entropy Catalyst

2019 ◽  
Author(s):  
Nirmal Kumar ◽  
Subramanian Nellaiappan ◽  
Ritesh Kumar ◽  
Kirtiman Deo Malviya ◽  
K. G. Pradeep ◽  
...  
Keyword(s):  
Formic Acid ◽  
Minimum Energy ◽  
High Entropy Alloy ◽  
Hydrogen Energy ◽  
High Entropy ◽  
Electro Oxidation ◽  
The Individual ◽  
Novel Catalyst ◽  
Cell Anode ◽  
Fuel Cell Anode

<div>Renewable harvesting clean and hydrogen energy using the benefits of novel multicatalytic materials of high entropy alloy (HEA equimolar Cu-Ag-Au-Pt-Pd) from formic acid with minimum energy input has been achieved in the present investigation. The synthesis effect of pristine elements in the HEA drives the electro-oxidation reaction towards non-carbonaceous pathway . The atomistic simulation based on DFT rationalize the distinct lowering of the d-band center for the individual atoms in the HEA as compared to the pristine counterparts. This catalytic activity of the HEA has also been extended to methanol electro-oxidation to show the unique capability of the novel catalyst. The nanostructured HEA, properties using a combination of casting and cry omilling techniques can further be utilized as fuel cell anode in direct formic acid/methanol fuel cells (DFFE).<br></div>

Complex magnetism and magnetoresistance of Gd-Tb-Dy-Ho-Lu hexagonal high-entropy alloy

2018 ◽  
Author(s):  
Janez Dolinšek ◽  
Stanislav Vrtnik ◽  
J. Lužnik ◽  
P. Koželj ◽  
M. Feuerbacher
Keyword(s):  
High Entropy Alloy ◽  
High Entropy

Recent progress in multi-element alloy and nitride coatings sputtered from high-entropy alloy targets

2006 ◽  
Vol 31 (6) ◽  
pp. 723-736 ◽  
Author(s):  
Keng-Hao Cheng ◽  
Chia-Han Lai ◽  
Su-Jien Lin ◽  
Jien-Wei Yeh
Keyword(s):  
Recent Progress ◽  
High Entropy Alloy ◽  
High Entropy ◽  
Nitride Coatings

Ultrastrong Duplex High-Entropy Alloy with 2 GPa Cryogenic Strength Enabled by an Accelerated Martensitic Transformation

2019 ◽  
Author(s):  
Dong Geun Kim ◽  
Yong Hee Jo ◽  
Junha Yang ◽  
Won-Mi Choi ◽  
Hyoung Seop Kim ◽  
...  
Keyword(s):  
Martensitic Transformation ◽  
High Entropy Alloy ◽  
High Entropy

Phase Stability and Microstructural Evolution in a Ductile Refractory High Entropy Alloy Al 10Nb 15Ta 5Ti 30Zr 40

2019 ◽  
Author(s):  
V. Soni ◽  
Oleg N. Senkov, PhD ◽  
Jean-Philippe Couzinie, PhD ◽  
Yufeng Zheng, PhD ◽  
Bharat Gwalani, PhD ◽  
...  
Keyword(s):  
Microstructural Evolution ◽  
Phase Stability ◽  
High Entropy Alloy ◽  
High Entropy

Microstructure and Properties of a Co-Free Fe50mn27ni10cr13 High Entropy Alloy

2020 ◽  
Author(s):  
Raymond Kwesi Nutor ◽  
Muhammad Azeemullah ◽  
Q. P. Cao ◽  
X. D. Wang ◽  
D.X. Zhang ◽  
...  
Keyword(s):  
High Entropy Alloy ◽  
High Entropy ◽  
Microstructure And Properties
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