Fiber shortening during injection molding of glass fiber-reinforced phenolic molding compounds: fiber length measurement method development and validation

Author(s):  
Robert Maertens ◽  
Annalena Hees ◽  
Ludwig Schöttl ◽  
Wilfried Liebig ◽  
Peter Elsner ◽  
...  
2010 ◽  
Vol 24 (15n16) ◽  
pp. 2555-2560 ◽  
Author(s):  
KAZUTO TANAKA ◽  
TSUTAO KATAYAMA ◽  
TATSUYA TANAKA ◽  
AKIHIRO ANGURI

During an injection molding of composite materials, fiber attrition occurs and the average fiber length is reduced. In order to control the breakage of fibers and degradation of mechanical properties during processing, Flat glass Fiber (FF), that has oval cross-section shape, has been developed to use for glass fiber reinforced thermoplastic (GFRTP). Using FF as reinforcement of GFRTP has advantages as following: (1) Fluidity of FF is better than conventional Normal glass Fiber (NF) with 'circular' cross-section; (2) Fiber breakage during the injection molding process using FF is smaller than that using NF. In this study, the mechanical properties of FF and NF were compared for reinforcement of long fiber thermoplastics pellets (LFT pellets). We have also investigated the effect of screw design on fiber damage and the mechanical properties. The mechanical properties of specimens molded by FF reinforcement LFT (FF-LFT) pellets were superior to these of NF reinforcement LFT (NF-LFT) pellets. The former could give composites with higher fluidity and longer residual fiber length. Moreover, FF was able to strengthen injection-molded samples with higher fiber content than NF. Low shear type screw was effective to prevent the fiber attrition during plasticization process, hence leads to better mechanical properties of GFRTP


Polymers ◽  
2021 ◽  
Vol 13 (15) ◽  
pp. 2492
Author(s):  
Po-Wei Huang ◽  
Hsin-Shu Peng ◽  
Sheng-Jye Hwang ◽  
Chao-Tsai Huang

In this study, fiber breaking behavior, fiber orientation, length variation, and changes in melt flow ability of long glass fiber reinforced polypropylene (L-FRP) composites under different mold cavity geometry, melt fill path, and plasticization parameters were investigated. The matrix material used was polypropylene and the reinforcement fibers were 25 mm long. An ultra-long-fiber composite injection molding machine (with a three-stage plunger and injection mechanism design) was used with different mold cavity geometry and plasticization parameters. Different screw speeds were used to explore the changes in fiber length and to provide a reference for setting fiber length and parameter combinations. Flow-length specimen molds with different specimen thickness, melt fill path, and gate design were used to observe the effect of plasticizing properties on the flow ability of the L-FRP composite materials. The experimental results showed that the use of an injection molding machine with a mechanism that reduced the amount of fiber breakage was advantageous. It was also found that an increase in screw speed increased fiber breakage, and 25 mm long fibers were shortened by an average of 50% (to 10 mm). Long fibers were more resistant to melt filling than short fibers. In addition, the thickness of the specimen and the gate design were also found to affect the filling process. The rounded angle gate and thick wall product decreased the flow resistance and assisted the flow ability and fiber distribution of the L-FRP injection molding.


2020 ◽  
Vol 0 (0) ◽  
Author(s):  
Po-Wei Huang ◽  
Hsin-Shu Peng ◽  
Sheng-Jye Hwang ◽  
Chao-Tsai Huang

AbstractIn this study, an injection molding machine with a low-fracture-fiber mechanism was designed with three stages: a plasticizing stage, an injection stage, and a packing stage. The fiber-fracture behavior is observed under the screw (plasticizing stage) of low-compression/shear ratio for the ultra-long fiber during the molding process. The molding material employed in this study was 25-mm-ultra-long-glass-fiber-reinforced polypropylene (PP/U-LGF). In addition, a thickness of 3 mm and a width of 12 mm spiral-flow-mold were constructed for studying the melt flow length and flow-length ratio through an experiment. The experimental results showed that the use of an injection molding machine with a three-stage mechanism decreased the fiber length when the screw speed was increased. On average, each fiber was shortened by 50% (>15 mm on average) from its original length of 25 mm. Longer glass fibers were more resistant to melt filling, and as the fiber length was reduced, the mixing between the melt and glass fibers was improved. Thus, the melt fluidity and fiber ratios were increased. In addition, the mixing/flow direction of the melt had an impact on the dispersion and arrangement of glass fibers, thus the tensile strength of PP/U-LGF increased.


2019 ◽  
Vol 15 (5) ◽  
pp. 591-598 ◽  
Author(s):  
Haitham Alrabiah ◽  
Ahmed Bakheit ◽  
Sabray Attia ◽  
Gamal A.E. Mostafa

Background: Conivaptan inhibits two of vasopressin receptor (vasopressin receptor V1a and V2). Conivaptan is used for the treatment of hyponatremia, and in some instances, for the treatment of the heart failure. Methods: The present study aimed to develop a simple, sensitive, and accurate HPLC with ultraviolet detection for the assay of conivaptan (CON) in mouse plasma using bisoprolol as internal standard (IS). A precipitation procedure was used to extract CON and the IS from the mouse plasma. CON was chromatographically separated using a C18 analytical column at 25°C. The separation was carried out using a mixture of phosphate buffer (50 mM): acetonitrile (60: 40, v/v, pH 4.5) with a flow rate of 1.0 mL/min and detection was performed at 240 nm. Results: The assay was validated according to the US Food and Drug (FDA) guidelines. The method demonstrated linearity over a concentration range of 150 - 2000 ng/mL (correlation coefficient: r 2 = 0.9985). The mean recovery of CON from the mouse plasma was 101.13%. All validation parameters for CON were within the acceptable range. Conclusion: The investigated method has been shown to be suitable for estimating the CON in plasma samples, and this method is sensitive and highly selective, allowing the estimation of its concentrations up to the nano-scale. The suggested method was successfully used in a pharmacokinetic study of CON in mouse plasma.


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