ABSOLUTE INTEGRAL CROSS SECTIONS AND PRODUCT BRANCHING RATIOS FOR THE VIBRATIONALLY SELECTED ION-MOLECULE REACTIONS: N$_{2}^{+}$(X2Σ$_{\rm g}^{+}$;v+= 0-2) + CH4

2013 ◽  
Vol 769 (1) ◽  
pp. 72 ◽  
Author(s):  
Yuntao Xu ◽  
Yih Chung Chang ◽  
Zhou Lu ◽  
C. Y. Ng
2004 ◽  
Vol 6 (5) ◽  
pp. 949 ◽  
Author(s):  
Anneli Ehlerding ◽  
Fredrik Hellberg ◽  
Richard Thomas ◽  
Shirzad Kalhori ◽  
Albert A. Viggiano ◽  
...  

Author(s):  
Vincent Richardson ◽  
Daniela Ascenzi ◽  
David Sundelin ◽  
Christian Alcaraz ◽  
Claire Romanzin ◽  
...  

Experimental and theoretical studies are presented on the reactivity of the radical cation isomers H2CNH+• (methanimine) and HCNH2+• (aminomethylene) with ethyne (C2H2). Selective isomer generation is performed via dissociative photoionization of suitable neutral precursors as well as via direct photoionization of methanimine. Reactive cross sections (in absolute scales) and product branching ratios are measured as a function of photon and collision energies. Differences between isomers’ reactivity are discussed in light of ab-initio calculations of reaction mechanisms. The major channels, for both isomers, are due to H atom elimination from covalently bound adducts to give [C3NH4]+. Theoretical calculations show that while for the reaction of HCNH2+• with acetylene any of the three lowest energy [C3NH4]+ isomers can form via barrierless and exothermic pathways, for the H2CNH+• reagent the only barrierless pathway is the one leading to the production of protonated vinyl cyanide (CH2CHCNH+), a prototypical branched nitrile species that has been proposed as a likely intermediate in star forming regions and in the atmosphere of Titan. The astrochemical implications of the results are briefly addressed.


1998 ◽  
Vol 108 (5) ◽  
pp. 1978-1988 ◽  
Author(s):  
J. R. Peterson ◽  
A. Le Padellec ◽  
H. Danared ◽  
G. H. Dunn ◽  
M. Larsson ◽  
...  

1997 ◽  
Vol 62 (2) ◽  
pp. 154-171 ◽  
Author(s):  
Jan Vojtík ◽  
Richard Kotal

An analysis of the degree of convergence of theoretical pictures of the dynamics of the autoionization event He(23S)-D2(v" = 0) -> [He...D2+(v')] + e is presented for a number of batches of Monte Carlo calculations differing in the number of the trajectories run. The treatment of the dynamics consists in 2D classical trajectory calculations based on static characteristics which include a quantum mechanical treatment of the perturbed D2(v" = 0) and D2+(v') vibrational motion. The vibrational populations are dynamical averages over the local widths of the He(23S)-D2(v" = 0) state with respect to autoionization to D2+(...He) in its v'th vibrational level and the Penning electron energies are related to the local differences between the energies of the corresponding perturbed D2(v" = 0)(...He*) and D2+(v')(...He) vibrational states. Special attention is paid to the connection between the requirements on the degree of convergence of the classical trajectory picture of the event and the purpose of the calculations. Information is obtained regarding a scale of the trajectory calculations required for physically sensible applications of the model to an interpretation of different type of experiments on the system: total ionization cross section measurements, Penning ionization electron spectra, subsequent 3D classical trajectory calculations of branching ratios of the products of the postionization collision process, and interpretation of electron ion coincidence measurements of the product branching ratios for individual vibrational levels of the nascent Penning ion.


2019 ◽  
Vol 199 ◽  
pp. 01014
Author(s):  
K. Piscicchia ◽  
M. Bazzi ◽  
G. Belloti ◽  
A. M. Bragadireanu ◽  
D. Bosnar ◽  
...  

The AMADEUS experiment at the DAΦNE collider of LNF-INFN deals with the investigation of the at-rest, or low-momentum, K− interactions in light nuclear targets, with the aim to constrain the low energy QCD models in the strangeness sector. The 0 step of the experiment consisted in the reanalysis of the 2004/2005 KLOE data, exploiting K− absorptions in H, 4He, 9Be and 12C, leading to the first invariant mass spectroscopic study with very low momentum (about 100 MeV) in-flight K− captures. With AMADEUS step 1 a dedicated pure Carbon target was implemented in the central region of the KLOE detector, providing a high statistic sample of pure at-rest K− nuclear interaction. The first measurement of the non-resonant transition amplitude $\left| {{A_{{K^ - }n \to \Lambda {\pi ^ - }}}} \right|$ at $\sqrt s = 33\,MeV$ below the K̄N threshold is presented, in relation with the Λ(1405) properties studies. The analysis procedure adopted in the serarch for K− multi-nucleon absorption cross sections and Branching Ratios will be also described.


2007 ◽  
Vol 22 (31) ◽  
pp. 5889-5908 ◽  
Author(s):  
M. Abbas ◽  
W. Emam ◽  
S. Khalil ◽  
M. Shalaby

We present the phenomenology of the low scale U(1)B–L extension of the standard model and its implications at LHC. We show that this model provides a natural explanation for the presence of three right-handed neutrinos and can naturally account the observed neutrino masses and mixing. We study the decay and production of the extra gauge boson and the SM singlet scalar (heavy Higgs) predicted in this type of models. We find that the cross sections of the SM-like Higgs production are reduced by ~ 20% – 30%, while its decay branching ratios remain intact. The extra Higgs has relatively small cross sections and the branching ratios of Z′ → l+l− are of order ~ 20% compared to ~ 3% of the SM results.


1992 ◽  
Vol 96 (2) ◽  
pp. 771-775 ◽  
Author(s):  
William F. Cooper ◽  
John F. Hershberger

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