scholarly journals VO2 microcrystals as an advanced smart window material at semiconductor to metal transition

2017 ◽  
Vol 50 (46) ◽  
pp. 465602 ◽  
Author(s):  
Raktima Basu ◽  
P Magudapathy ◽  
Manas Sardar ◽  
Ramanathaswamy Pandian ◽  
Sandip Dhara
Keyword(s):  
2019 ◽  
Vol 13 (01) ◽  
pp. 1951008 ◽  
Author(s):  
Anung Riapanitra ◽  
Yusuke Asakura ◽  
Shu Yin

The monoclinic phase of VO2 has promising application as a smart window material because it possesses a reversible metal-to-semiconductor transformation with a critical temperature of [Formula: see text]C. The high critical temperature must be lowered to achieve a possible application. Anion doping has been widely researched as possible doping of VO2(M) with fluorine is the main option nowadays. However, other halogen elements such as chlorine have not been investigated albeit possessing possible advantages properties. In this work, we report the use of chlorine anion as doping for VO2(M) to lower its critical temperature and to enhance its thermochromic performance. The synthesis was performed using a facile one-step hydrothermal reduction of vanadium pentoxide by hydrazine at 350–[Formula: see text]C, using ammonium chloride as the source of the anion. The result showed that the optimum temperature to synthesize Cl-doped VO2(M) was [Formula: see text]C. The lowest critical temperature that can be achieved by chlorine-doped VO2(M) was at [Formula: see text]C. The thermochromic performance of Cl-doped VO2(M) was improved compared to pristine VO2(M) nanoparticle. This finding provides a novel use of chlorine-doped VO2(M) with a facile one-step hydrothermal method to synthesize chlorine-doped VO2(M) as well as the feasibility of chlorine-doped VO2(M) as a smart window material.


Author(s):  
Xin Zhou ◽  
Yun Meng ◽  
Tuan Duc Vu ◽  
Deen Gu ◽  
Yadong Jiang ◽  
...  

Vanadium dioxide is widely investigated as a thermochromic smart window material. However its mediocre thermochromic property (low solar modulation ability ΔTsol, low luminous transmission Tlum, and high transition temperature (τc))....


2010 ◽  
Vol 130 (9) ◽  
pp. 437-442
Author(s):  
Takafumi Fukumoto ◽  
Naoki Okamoto ◽  
Yoshimi Ohta ◽  
Yasuhiro Fukuyama ◽  
Masaki Hirota ◽  
...  

2021 ◽  
Vol 293 ◽  
pp. 116826
Author(s):  
Yanyi Sun ◽  
Xin Liu ◽  
Yang Ming ◽  
Xiao Liu ◽  
Daniel Mahon ◽  
...  

Crystals ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 440
Author(s):  
Yuan Deng ◽  
Shi-Qin Li ◽  
Qian Yang ◽  
Zhi-Wang Luo ◽  
He-Lou Xie

Smart windows can dynamically and adaptively adjust the light transmittance in non-energy or low-energy ways to maintain a comfortable ambient temperature, which are conducive to efficient use of energy. This work proposes a liquid crystal (LC) smart window with highly efficient near-infrared (NIR) response using carbon nanotubes grafted by biphenyl LC polymer brush (CNT-PDB) as the orientation layer. The resultant CNT-PDB polymer brush can provide the vertical orientation of LC molecules to maintain the initial transparency. At the same time, the smart window shows a rapid response to NIR light, which can quickly adjust the light transmittance to prevent sunlight from entering the room. Different from common doping systems, this method avoids the problem of poor compatibility between the LC host and photothermal conversion materials, which is beneficial for improving the durability of the device.


RSC Advances ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 2390-2396
Author(s):  
Yoon Ji Seo ◽  
Hyung Gyu Lee ◽  
Jun Seok Yang ◽  
Hwanyeop Jeong ◽  
Jeonghun Han ◽  
...  

Magnetic microrods were synthesised from magnetic nanoparticles by alignment using a magnetic field. The transparency difference was maximised and the anisotropic features of the rods were used as a light valve to control the transparency of a smart window.


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