scholarly journals Application of Molecular Convergent Close-Coupling cross sections in a Collisional Radiative model for the triplet system of molecular hydrogen

Author(s):  
Dirk Wünderlich ◽  
Liam Hall Scarlett ◽  
Stefan Briefi ◽  
Ursel Fantz ◽  
Mark Christian Zammit ◽  
...  
1984 ◽  
Vol 86 ◽  
pp. 44-44
Author(s):  
M. Klapisch ◽  
A. Bar-Shalom ◽  
A. Cohen

We describe a package of programs for the implementation of the collisional-radiative model to complex configurations. The number of levels taken into account may be several hundreds. The heart of the package is a very efficient program for excitation cross sections in the Distorted Wave framework, using the Relativistic Parametric Potential wave functions. The basic jj coupling scheme actually simplified the computations, enabling a useful factorization into radial and angular parts. Intermediate coupling and configuration interactions are accounted for. We computed ratios of intensities of 3d9 − 3d84s (E2) to 3d9 −3d84p (El) transitions as functions of ne and Te in Xe XXVIII and other Co-like spectra. The atomic model involves all the levels of configurations (3p6)3d9; −3d84s, −3d84p, −3d84d, −3d84f, and (3p5) −3d10, −3d94p. (275 levels) and all the transitions between them. Results compare very well with experimental spectra from TFR.


Atoms ◽  
2019 ◽  
Vol 7 (3) ◽  
pp. 75 ◽  
Author(s):  
Liam Scarlett ◽  
Jeremy Savage ◽  
Dmitry Fursa ◽  
Mark Zammit ◽  
Igor Bray

We present convergent close-coupling (CCC) calculations of electron-impact dissociation of vibrationally-excited molecular hydrogen into neutral fragments. This work follows from our previous results for dissociation of molecular hydrogen in the ground vibrational level [Scarlett et al., Eur. Phys. J. D 72, 34 (2018)], which were obtained from calculations performed in a spherical coordinate system. The present calculations, performed utilizing a spheroidal formulation of the molecular CCC method, reproduce the previous dissociation cross sections for the ground vibrational level, while allowing the extension to scattering on excited levels.


1976 ◽  
Vol 31 (3-4) ◽  
pp. 362-368 ◽  
Author(s):  
M. Cacciatore ◽  
M. Capitelli

The non L.T.E. (local thermodynamic equilibrium) properties of optically thin and thick quasistationary oxygen plasmas have been calculated for the temperature range k T = 0.5 - 1.5 eV and for the electron density interval 108 - 1016 cm-3 , by using the collisional-radiative model of Bates, Kingston and McWhirther. The results include1 the coefficients r0(i) and r1(i), which represent the contribution to the population density of the ith quantum level from the continuum and from the ground state, respectively2 the values of α and S, which are the collisional-radiative recombination and ionization coefficients, respectively. The accuracy of the present results is discussed in connection with the adopted plasma model and with the selection of the collisional cross sections for forbidden and allowed transitions. A discussion is also presented of the influence of the two low lying excited states of oxygen atoms (i.e. the states 2p41D, 2p41S) on the non L.T.E. properties of these plasmas. A satisfactory agreement is found with the calculations of Julienne et al. and with the experimental results of Jones.


Author(s):  
Enrico Majorana ◽  
Nabil Souhair ◽  
Fabrizio Ponti ◽  
Mirko Magarotto

AbstractThe present work is part of a wider project aimed at improving the description of the plasma dynamics during the production phase of a Helicon Plasma Thruster. In particular, the work was focused on the development of a chemical model for Argon- and Xenon-based plasma. The developed model consists of a collisional radiative model suitable to describe the dynamics of the 1s and 2p excited levels. The model is meant to be complementary to 3D-VIRTUS, a numerical tool which enforces a fluid description of plasma, developed by the University of Padova to analyse helicon discharges. Once identified, the significant reactions for both propellants, the reaction rate coefficients, have been integrated exploiting cross sections from literature and assuming a Maxwellian velocity distribution function for all the species. These coefficients have been validated against experimental measurements of an Argon Inductively Coupled Plasma and compared with a well-established code. For Argon, the selected reactions have been reduced through a proposed lumping methodology. In this way, it was possible to reduce the number of equations of the system to solve, and implement them into 3D-VIRTUS. A validation against an experimental case taken from literature was performed, showing good agreement of the results. Regarding the Xenon model, only a verification has been performed against the results of another collisional-radiative model in literature. Finally, a predictive analysis of the propulsive performances of a Helicon Plasma Thruster for both Argon and Xenon is presented.


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