Durability of nanolayer Ti-Al-O-N hard coatings under simulated polycarbonate melt processing conditions

Author(s):  
T. Broegelmann ◽  
Kirsten Bobzin ◽  
Guido Grundmeier ◽  
Teresa de los Arcos ◽  
N. C. Kruppe ◽  
...  
Polymers ◽  
2018 ◽  
Vol 11 (1) ◽  
pp. 25 ◽  
Author(s):  
Rudinei Fiorio ◽  
Dagmar D’hooge ◽  
Kim Ragaert ◽  
Ludwig Cardon

In the present work, statistical analysis (16 processing conditions and 2 virgin unmodified samples) is performed to study the influence of antioxidants (AOs) during acrylonitrile-butadiene-styrene terpolymer (ABS) melt-blending (220 °C) on the degradation of the polybutadiene (PB) rich phase, the oxidation onset temperature (OOT), the oxidation peak temperature (OP), and the yellowing index (YI). Predictive equations are constructed, with a focus on three commercial AOs (two primary: Irganox 1076 and 245; and one secondary: Irgafos 168) and two commercial ABS types (mass- and emulsion-polymerized). Fourier transform infrared spectroscopy (FTIR) results indicate that the nitrile absorption peak at 2237 cm−1 is recommended as reference peak to identify chemical changes in the PB content. The melt processing of unmodified ABSs promotes a reduction in OOT and OP, and promotes an increase in the YI. ABS obtained by mass polymerization shows a higher thermal-oxidative stability. The addition of a primary AO increases the thermal-oxidative stability, whereas the secondary AO only increases OP. The addition of the two primary AOs has a synergetic effect resulting in higher OOT and OP values. Statistical analysis shows that OP data are influenced by all three AO types, but 0.2 m% of Irganox 1076 displays high potential in an industrial context.


Polymer ◽  
2001 ◽  
Vol 42 (23) ◽  
pp. 9513-9522 ◽  
Author(s):  
H.R. Dennis ◽  
D.L. Hunter ◽  
D. Chang ◽  
S. Kim ◽  
J.L. White ◽  
...  

2002 ◽  
Vol 40 (23) ◽  
pp. 2661-2666 ◽  
Author(s):  
Cher H. Davis ◽  
Lon J. Mathias ◽  
Jeffrey W. Gilman ◽  
David A. Schiraldi ◽  
J. Randy Shields ◽  
...  

Polymers ◽  
2021 ◽  
Vol 13 (20) ◽  
pp. 3560
Author(s):  
Zina Vuluga ◽  
Catalina-Gabriela Sanporean ◽  
Denis Mihaela Panaitescu ◽  
George Mihail Teodorescu ◽  
Mihai Cosmin Corobea ◽  
...  

Masterbatches from a linear poly[styrene-b-(ethylene-co-butylene)-b-styrene] (SEBS) and halloysite nanotubes (HNT-QM) were obtained in different conditions of temperature and shear using two co-rotating twin-screw extruders. The influence of screw configuration and melt processing conditions on the morpho-structural, thermal and mechanical properties of masterbatches at macro and nanoscale was studied. A good dispersion of halloysite nanotubes and better thermal stability and tensile and nanomechanical properties were obtained at a lower temperature profile and higher screw speed. The effect of masterbatches, the best and worst alternatives, on the properties of a polypropylene (PP)–glass fiber (GF) composite was also evaluated. Double hardness, tensile strength and modulus and four times higher impact strength were obtained for PP/GF composites containing masterbatches compared to pristine PP. However, the masterbatch with the best properties led further to enhanced mechanical properties of the PP/GF composite. A clear difference between the effects of the two masterbatches was obtained by nanoindentation and nanoscratch tests. These analyses proved to be useful for the design of polymer composites for automotive parts, such as bumpers or door panels. This study demonstrated that setting-up the correct processing conditions is very important to obtain the desired properties for automotive applications.


2009 ◽  
Vol 113 (2) ◽  
pp. 752-756 ◽  
Author(s):  
Supaluk Khunprasert ◽  
Supakanok Thongyai ◽  
Wannee Chinsirikul ◽  
Sirirat Wacharawichanant

2010 ◽  
Vol 95 (9) ◽  
pp. 1800-1809 ◽  
Author(s):  
S. Aslanzadeh ◽  
M. Haghighat Kish ◽  
A.A. Katbab

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