Physics of effective media in plastic polymer-composites using Terahertz time-domain spectroscopy

Author(s):  
Khushboo Singh ◽  
Aparajita Bandyopadhyay ◽  
Amartya Sengupta

Abstract Polymer composites have been an integral part of our lives for centuries and its applicability has increased substantially with recent technological advancements. However, with the vast range of available fillers and polymer materials, it is crucial to have a priori knowledge of the physical and chemical properties of the materials for various applications. Hence, material characterization at different stages of production is one of the most important parts of product development and quality control. In this article we have probed the optical behavior of a few polymer composites, with absorptive and dispersive guests, using THz time-domain spectroscopy. Subsequently, we used quasi-static effective medium theory to investigate the impact of absorptive and dispersive filler materials on the optical properties of the composites. This enables us to address the significance of filler properties on the detection limits of real-life composite compounds.

2020 ◽  
Vol 138 (10) ◽  
pp. 49962
Author(s):  
Klaudia Zeranska‐Chudek ◽  
Anna Lapinska ◽  
Agnieszka Siemion ◽  
Agnieszka M. Jastrzębska ◽  
Mariusz Zdrojek

2021 ◽  
Vol 127 (5) ◽  
Author(s):  
Khadim Hussain ◽  
Shoaib Mehboob ◽  
Izhar Ahmad ◽  
Muhammad Mumtaz ◽  
Abdul Rehman Khan ◽  
...  

Molecules ◽  
2020 ◽  
Vol 26 (1) ◽  
pp. 149
Author(s):  
Karol Leluk ◽  
Stanisław Frąckowiak ◽  
Joanna Ludwiczak ◽  
Tomasz Rydzkowski ◽  
Vijay Kumar Thakur

Recently, biocomposites have emerged as materials of great interest to the scientists and industry around the globe. Among various polymers, polylactic acid (PLA) is a popular matrix material with high potential for advanced applications. Various particulate materials and nanoparticles have been used as the filler in PLA based matrix. One of the extensively studied filler is cellulose. However, cellulose fibres, due to their hydrophilic nature, are difficult to blend with a hydrophobic polymer matrix. This leads to agglomeration and creates voids, reducing the mechanical strength of the resulting composite. Moreover, the role of the various forms of pure cellulose and its particle shape factors has not been analyzed in most of the current literature. Therefore, in this work, materials of various shapes and shape factors were selected as fillers for the production of polymer composites using Polylactic acid as a matrix to fill this knowledge gap. In particular, pure cellulose fibres (three types with different elongation coefficient) and two mineral nanocomponents: precipitated calcium carbonate and montmorillonite were used. The composites were prepared by a melt blending process using two different levels of fillers: 5% and 30%. Then, the analysis of their thermomechanical and physico-chemical properties was carried out. The obtained results were presented graphically and discussed in terms of their shape and degree of filling.


Sign in / Sign up

Export Citation Format

Share Document