scholarly journals The ability of nitrogen atomic absorption in the formation of iron nitride on flake structure and nodule in cast iron

2021 ◽  
Vol 1869 (1) ◽  
pp. 012104
Author(s):  
W Sujana ◽  
K A Widi ◽  
T Rahardjo ◽  
T N Prihatmi
2008 ◽  
Vol 15 (05) ◽  
pp. 669-674
Author(s):  
M. AHMADI ◽  
M. TEIMOURI ◽  
M. ALIOFKHAZRAEE ◽  
S. M. MOUSAVI KHOEE

Salt bath oxinitriding is a duplex surface treatment developed to improve tribological and corrosion properties of ferrous materials. In this research, gray cast iron samples were nitrided at the temperature range of 480°C–580°C, and then oxidized in an oxidative salt bath. The phase composition of surface layer was identified by X-ray diffraction. Using a microhardness tester, hardness of nitrided gray cast iron was measured. Corrosion behavior of treated (nitrided and oxinitrided) samples was evaluated using potentiodynamic polarization technique in 3.5% NaCl solution. XRD analyses indicate that the surface layer in nitrided and oxinitrided samples is composed of ε-iron nitride ( Fe 2-3 N ) and magnetite ( Fe 3 O 4), respectively. Results show that the corrosion resistance of gray cast iron can be improved up to 170%.


2021 ◽  
pp. 1-13
Author(s):  
WeeLiam Khor ◽  
Jeffery Farrow ◽  
Mike Mulheron ◽  
David A Jesson

Penstocks have been used in the water industry for flow control since the Victorian expansion and consolidation of clean and waste water networks. However, the Victorians were the first to use grey cast iron (GCI) castings to manufacture large scale penstocks. Most of these ageing assets are still in operation, however engineering assessments are necessary to determine a structure’s fitness-for-service. Even today, penstocks in the sewer system tend to be made from GCI, due to ease of manufacturing, resistance to corrosion and cost. One characteristic property of grey cast iron is the graphite flake structure in the material, contributing to its low toughness, inconsistency in material strength and brittle behaviour, despite exhibiting slight hardening properties. Finite element analysis (FEA), is a numerical method which allows the analysis of complex structures by splitting it into finite parts and solving them with a computer processor. Despite the versatility of FEA, appropriate considerations and assumptions are necessary due to the difficulty to obtain data from inspection and unique material behaviour of GCI. The article shows concerns for an analysis of GCI penstocks using FEA, which extends into the application of fracture mechanics approaches for defect assessments.


Author(s):  
Robert E. Ogilvie

The search for an empirical absorption equation begins with the work of Siegbahn (1) in 1914. At that time Siegbahn showed that the value of (μ/ρ) for a given element could be expressed as a function of the wavelength (λ) of the x-ray photon by the following equationwhere C is a constant for a given material, which will have sudden jumps in value at critial absorption limits. Siegbahn found that n varied from 2.66 to 2.71 for various solids, and from 2.66 to 2.94 for various gases.Bragg and Pierce (2) , at this same time period, showed that their results on materials ranging from Al(13) to Au(79) could be represented by the followingwhere μa is the atomic absorption coefficient, Z the atomic number. Today equation (2) is known as the “Bragg-Pierce” Law. The exponent of 5/2(n) was questioned by many investigators, and that n should be closer to 3. The work of Wingardh (3) showed that the exponent of Z should be much lower, p = 2.95, however, this is much lower than that found by most investigators.


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