scholarly journals Fabrication of Au and Ag – Coated AFM Probes for Tip-Enhanced Raman Spectroscopy

2021 ◽  
Vol 2015 (1) ◽  
pp. 012013
Author(s):  
L S Basalaeva ◽  
N N Kurus ◽  
E E Rodyakina ◽  
K V Anikin ◽  
A G Milekhin
Keyword(s):  
Raman Spectroscopy ◽  
Electromagnetic Field ◽  
Localized Surface Plasmon Resonance ◽  
Metal Cluster ◽  
Field Enhancement ◽  
Optical Characterization ◽  
Localized Surface Plasmon ◽  
Tip Enhanced Raman Spectroscopy ◽  
Shape And Size

Abstract In this work, approaches for fabrication metal coated probes for Tip Enhanced Raman Spectroscopy (TERS) are considered. It was proposed to use optical characterization of probes to achieve the effective TERS of semiconductor nanoobjects. The shape and size of the metal cluster at the tip apex determines the position of the localized surface plasmon resonance, the electromagnetic field enhancement and, thus, TERS performance. The possibility of optimizing the characteristics of the probes for TERS studies of nanoobjects has been investigated.

Localized surface plasmon resonance shift and its application in scanning near-field optical microscopy

2021 ◽  
Author(s):  
Jiawei Zhang ◽  
Gitanjali Kolhatkar ◽  
Andreas Ruediger
Keyword(s):  
Raman Spectroscopy ◽  
Surface Plasmon Resonance ◽  
Surface Plasmon ◽  
Plasmon Resonance ◽  
Localized Surface Plasmon Resonance ◽  
Near Field ◽  
Localized Surface Plasmon ◽  
Resonance Shift ◽  
Raman Modes ◽  
Tip Enhanced Raman Spectroscopy

The localized surface plasmon resonance (LSPR) position in tip-enhanced Raman spectroscopy (TERS) is of great importance to the understanding and interpretation of the relative intensity of different enhanced Raman modes....

scholarly journals Sample induced intensity variations of localized surface plasmon resonance in tip-enhanced Raman spectroscopy

2020 ◽  
Vol 28 (18) ◽  
pp. 25998
Author(s):  
Jiawei Zhang ◽  
Azza Hadj Youssef ◽  
Andreas Dörfler ◽  
Gitanjali Kolhatkar ◽  
Alexandre Merlen ◽  
...  
Keyword(s):  
Raman Spectroscopy ◽  
Surface Plasmon Resonance ◽  
Surface Plasmon ◽  
Plasmon Resonance ◽  
Localized Surface Plasmon Resonance ◽  
Localized Surface Plasmon ◽  
Tip Enhanced Raman Spectroscopy

Development and Characterization of a Diamond-Based Localized Surface Plasmon Resonance Interface

2010 ◽  
Vol 114 (8) ◽  
pp. 3346-3353 ◽  
Author(s):  
Sabine Szunerits ◽  
Slimane Ghodbane ◽  
Joanna Niedziółka-Jönsson ◽  
Elisabeth Galopin ◽  
Frederik Klauser ◽  
...  
Keyword(s):  
Surface Plasmon Resonance ◽  
Surface Plasmon ◽  
Plasmon Resonance ◽  
Localized Surface Plasmon Resonance ◽  
Localized Surface Plasmon

Optical characterization of pure vegetable oils and their biodiesels using Raman spectroscopy

Laser Physics ◽  
2016 ◽  
Vol 26 (4) ◽  
pp. 046001 ◽  
Author(s):  
S Firdous ◽  
S Anwar ◽  
A Waheed ◽  
M Maraj
Keyword(s):  
Raman Spectroscopy ◽  
Vegetable Oils ◽  
Optical Characterization

Identification and Characterization of Artists' Red Dyes and Their Mixtures by Surface-Enhanced Raman Spectroscopy

2007 ◽  
Vol 61 (9) ◽  
pp. 994-1000 ◽  
Author(s):  
Alyson V. Whitney ◽  
Francesca Casadio ◽  
Richard P. Van Duyne
Keyword(s):  
Raman Spectroscopy ◽  
Surface Enhanced Raman Spectroscopy ◽  
Localized Surface Plasmon ◽  
Carminic Acid ◽  
Sers Substrates ◽  
Surface Enhanced ◽  
Surface Enhanced Raman ◽  
Lac Dye ◽  
Silver Island

Silver film over nanospheres (AgFONs) were successfully employed as surface-enhanced Raman spectroscopy (SERS) substrates to characterize several artists' red dyes including: alizarin, purpurin, carminic acid, cochineal, and lac dye. Spectra were collected on sample volumes (1 × 10−6 M or 15 ng/μL) similar to those that would be found in a museum setting and were found to be higher in resolution and consistency than those collected on silver island films (AgIFs). In fact, to the best of the authors' knowledge, this work presents the highest resolution spectrum of the artists' material cochineal to date. In order to determine an optimized SERS system for dye identification, experiments were conducted in which laser excitation wavelengths were matched with correlating AgFON localized surface plasmon resonance (LSPR) maxima. Enhancements of approximately two orders of magnitude were seen when resonance SERS conditions were met in comparison to non-resonance SERS conditions. Finally, because most samples collected in a museum contain multiple dyestuffs, AgFONs were employed to simultaneously identify individual dyes within several dye mixtures. These results indicate that AgFONs have great potential to be used to identify not only real artwork samples containing a single dye but also samples containing dyes mixtures.

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