scholarly journals On determining the fraction of metastable ions produced by direct ionization

2017 ◽  
Vol 12 (11) ◽  
pp. C11005-C11005 ◽  
Author(s):  
F. Chu ◽  
S.W. Mattingly ◽  
J. Berumen ◽  
R. Hood ◽  
F. Skiff
1967 ◽  
Vol 20 (4) ◽  
pp. 689 ◽  
Author(s):  
JH Bowie ◽  
RG Cooks ◽  
P Jakobsen ◽  
S Lawesson ◽  
G Schroll

The mass spectra of representative series of simple alkyl acetoacetates, alkyl acetothioacetates, and some unsaturated esters derived from unsaturated alcohols or phenols are reported and discussed. The fragmentation schemes have been established by high resolution measurements, appropriate metastable ions, and by deuterium and 18O labelling. Many of the spectra show significant skeletal rearrangement fragments arising from either loss of carbon monoxide or carbon dioxide.


Physics Today ◽  
1971 ◽  
Vol 24 (3) ◽  
pp. 19-19
Author(s):  
John T. Scott
Keyword(s):  

2010 ◽  
Vol 10 (12) ◽  
pp. 30381-30404 ◽  
Author(s):  
I. G. Usoskin ◽  
G. A. Kovaltsov ◽  
I. A. Mironova ◽  
A. J. Tylka ◽  
W. F. Dietrich

Abstract. Using a new reconstruction of the solar proton energy spectra for Ground Level Enhancement (GLE) events, based on fits to measurements from ground-based and satellite-borne instruments covering a wide energy range, we quantitatively evaluate the possible ionization effects in the low and middle atmosphere for 58 out of the 66 GLE events recorded by the world-wide neutron monitor network since 1956. The ionization computations are based on the numerical 3-D CRAC:CRII model. A table of the ionization effect caused by the GLE events at different atmospheric heights is provided. It is shown that the direct ionization effect is negligible or even negative, due to the accompanying Forbush decreases, in all low- and mid-latitude regions. The ionization effect is important only in the polar atmosphere, where it can be dramatic in the middle and upper atmosphere (above 30 km) during major GLE events.


1974 ◽  
Vol 29 (3) ◽  
pp. 507-512
Author(s):  
T. Keough ◽  
J. H. Beynon ◽  
R. G. Cooks ◽  
C. Chang ◽  
R. H. Shapiro

Loss of ‘OH from the molecular ions of nitrobenzenes having various substituents in the m- and p-positions does not involve substituent randomization and reaction through the ortho-isomer; the kinetic energy release accompanying metastable ion fragmentation shows this latter to be an entirely distinct process. The origin of the hydrogen lost as 'OH in the m- and p-compounds is the ring (mainly the position ortho to the nitro group in methyl p-nitrobenzoate). However, the hydro­gens of the substituent do play a direct role in the reaction as shown by an isotope effect upon the abundances of metastable peaks. Hydrogen atom abstraction by the ionized nitro group apparently occurs independently of participation by the substituent on the nitrobenzene but a second hydrogen transfer from this substituent to the ring precedes fragmentation. Direct interaction between groups o ' the aromatic ring that are not ortho to each other therefore apparently does not occur. Inversion of the rate constants for two reactions, NO' loss and CH2O loss from the methyl p-nitrobenzoate molecular ion in the metastable ion time range, has been observed following isotopic substitution.


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