Dynamics of methyl radical formation by 266 nm photolysis of xylenes and mesitylene

The 266 nm photodissociation of three xylene isomers and mesitylene leading to the formation of methyl radical was examined. The kinetic energy release profiles for the methyl radical were almost identical for all the three isomers of xylene and mesitylene, while substantial differences were observed for the corresponding profiles of the co-fragment produced by loss of one methyl group. This observation be attributed to the formation of the methyl radical from alternate channels. The total kinetic energy distribution profiles were rationalized based on the dissociation of {sp2}C–C{sp3} bond in the cationic state, wherein the {sp2}C–C{sp3} bond dissociation energy is lowered relative to the ground state. The dissocaiton in the cationic state follows a resonant three-photon absorption process, resulting in maximum total kinetic energy of about 1.6 – 1.8 eV for the photofragments. A results in. Fitting of the TKER distribution profiles to empirical function reveals that the dynamics of {sp2}C–C{sp3} bond dissociation is insensitive to the position of substitution but marginally dependent on the number of methyl groups.

Controlling H3+ Formation From Ethane Using Shaped Ultrafast Laser Pulses

An adaptive learning algorithm coupled with 3D momentum-based feedback is used to identify intense laser pulse shapes that control H3+ formation from ethane. Specifically, we controlled the ratio of D2H+ to D3+ produced from the D3C-CH3 isotopologue of ethane, which selects between trihydrogen cations formed from atoms on one or both sides of ethane. We are able to modify the D2H+:D3+ ratio by a factor of up to three. In addition, two-dimensional scans of linear chirp and third-order dispersion are conducted for a few fourth-order dispersion values while the D2H+ and D3+ production rates are monitored. The optimized pulse is observed to influence the yield, kinetic energy release, and angular distribution of the D2H+ ions while the D3+ ion dynamics remain relatively stable. We subsequently conducted COLTRIMS experiments on C2D6 to complement the velocity map imaging data obtained during the control experiments and measured the branching ratio of two-body double ionization. Two-body D3+ + C2D3+ is the dominant final channel containing D3+ ions, although the three-body D + D3+ + C2D2+ final state is also observed.

Kinetic Energy Calculation in Granite Particles Comminution Considering Movement Characteristics and Spatial Distribution

Profound knowledge of the movement characteristics and spatial distribution of the particles under compression during the crushing of rocks and ores is essential to further understanding kinetic energy release law. Various experimental methods such as high-speed camera technology, the coordinate method, and the color tracking method were adopted to improve the understanding of particles’ movement characteristics and spatial distribution in rock comminution. The average horizontal velocities of the four size particles α, β, γ, and δ are statistically calculated. The descending order of the particles’ average velocity is γ, β, α, and δ. In comparison, the descending order of the particles’ kinetic energy is α, β, γ, and δ. Moreover, the contribution of α particles to the total kinetic energy exceeds 70%. The spatial distribution characteristics of coarse and fine particles show different results. The probability of fine particles appearing in the range closer to the center area is greater, while the position of large particles appears to be more random. The color tracking results show that super-large particles generated by crushing are on the specimen’s surface, while small particles are generally produced from inside. The above results indicate a connection between the particle generation mechanism, movement characteristics, and spatial distribution in the comminution process.

Dissociative Ionization of Molecular CF2Br2 under 800 and 400 nm Intense Femtosecond Laser Fields

The interaction between the CF2Br2 molecule and 800/400 nm intense femtosecond laser fields is investigated by direct current (dc) sliced velocity mapping imaging implementation. By analyzing the kinetic energy release distribution and angular distribution of fragment ions, the dissociation channels along C-Br bond cleavage have been determined. The isotropic structure of the angular distribution for CF2Br+ ions is attributed to the coupling between the excited states. Additionally, a unique elimination channel of CF2Br2+ → CF2 + Br2+ has been observed and identified in the case of 400 nm laser field, in which the two C-Br bonds break asynchronously.

Electron-ion coincidence measurements of molecular dynamics with intense X-ray pulses

Molecules can sequentially absorb multiple photons when irradiated by an intense X-ray pulse from a free-electron laser. If the time delay between two photoabsorption events can be determined, this enables pump-probe experiments with a single X-ray pulse, where the absorption of the first photon induces electronic and nuclear dynamics that are probed by the absorption of the second photon. Here we show a realization of such a single-pulse X-ray pump-probe scheme on N$$_2$$ 2 molecules, using the X-ray induced dissociation process as an internal clock that is read out via coincident detection of photoelectrons and fragment ions. By coincidence analysis of the kinetic energies of the ionic fragments and photoelectrons, the transition from a bound molecular dication to two isolated atomic ions is observed through the energy shift of the inner-shell electrons. Via ab-initio simulations, we are able to map characteristic features in the kinetic energy release and photoelectron spectrum to specific delay times between photoabsorptions. In contrast to previous studies where nuclear motions were typically revealed by measuring ion kinetics, our work shows that inner-shell photoelectron energies can also be sensitive probes of nuclear dynamics, which adds one more dimension to the study of light-matter interactions with X-ray pulses.

Total kinetic energy release in the fast neutron induced fission of actinide nuclei

The total kinetic energy (TKE) release in the fast neutron-induced fission of various actinide nuclei was measured for neutron energies for En =2.6-100 MeV at the Weapons Neutron Research facility of the Los Alamos National Laboratory. The data are compared to the GEF model of the fission process. The variances of the TKE distributions appear to decrease with increasing Z and A of the fissioning systems.

Flexible Kinetic Energy Release Controllers for a Wind Farm in an Islanding System

To improve frequency nadir following a disturbance and avoid under-frequency load shedding, two types of flexible kinetic energy release controllers for the doubly fed induction generator (DFIG) are proposed. The basic idea is to release only a small amount of kinetic energy stored at the DFIG in the initial transient period (1–3 s after the disturbance). When the frequency dip exceeds a preset threshold, the amount of kinetic energy released is increased to improve the frequency nadir. To achieve the goal of flexible kinetic energy release, a deactivation function based integral controller is first presented. To further improve the dynamic frequency response under parameter uncertainties and external disturbances, a second flexible kinetic energy release controller is designed using a proportional-integral controller, with the gains being adapted in real-time with the particle swarm optimization algorithm. Based on the MATLAB/SIMULINK simulation results for a local power system, it is concluded that the frequency nadir can be maintained around the under-frequency load shedding threshold of 59.6 Hz using the proposed controllers.