Gas-phase generation of dinuclear Au(I)-Au(II) complexes by laser desorption ionization mass spectrometry

Alkali metal chloroaurates(III) were analysed by laser desorption ionization mass spectrometry. Among a number of generated gas-phase ionic clusters, the unusual ions [MAu2Cl5]- (were M stands for Na, K, Rb, Cs) were detected. The spectra of metastable ions and quantum mechanics calculations show the presence of unprecedented Au(I)-Au(II) interactions in the clusters.

Horizontal electric fields from flow of auroral O⁺(²P) ions at sub-second resolution

Electric fields are a ubiquitous feature of the ionosphere and are intimately linked with aurora through particle precipitation and field-aligned currents. We present a unique method to estimate ionospheric electric fields beside a dynamic auroral feature by solving the continuity equation for the metastable O+(2P) ions, which emit as they move under the influence of electric fields during their 5 s lifetime. Simultaneous measurements of emission at 732.0 nm (from the O+(2P) ions), and prompt emissions at 673.0 nm (N2) and 777.4 nm (O), all at high spatial (100 m) and temporal (0.05 s) resolution, are used in the solution of the continuity equation, which gives the dynamic changes of the O+ ion population at all heights in a 3D volume close to the magnetic zenith. Perspective effects are taken into account by a new geometric method, which is based on an accurate estimate of the magnetic zenith position. The emissions resulting from the metastable ions are converted to brightness images by projecting onto the plane of the ground, which are compared with the measured images. The flow velocity of the ions is a free parameter in the solution of the continuity equation; the value that minimizes the difference between the modelled and observed images is the extracted flow velocity at each time step. We demonstrate the method with an example event during the passage of a brightening arc feature, lasting about 10 s, in which the inferred electric fields vary between 20 and 120 mV m−1. These inferred electric fields are compared with SuperDARN measurements, which have an average value of 30 mV m−1. An excellent agreement is found in magnitude and direction of the background electric field; an increase in magnitude during the brightening of the arc feature supports theories of small scale auroral arc formation and electrodynamics.

Role of metastable-adsorbed charges in the stability degradation of carbon-based electrodes for capacitive deionization

The dynamic movement of metastable ions at the surface of aged anodes is illustrated to elucidate the inversion effect.