scholarly journals Determination of the total petroleum hydrocarbons in aquatic products by fluorescence spectrophotometry

2020 ◽  
Vol 474 ◽  
pp. 052029
Author(s):  
Hongli Ye ◽  
Liangliang Tian ◽  
Yongfu Shi ◽  
Huijuan Yu ◽  
Youqiong Cai ◽  
...  
Keyword(s):  
Petroleum Hydrocarbons ◽  
Total Petroleum Hydrocarbons ◽  
Aquatic Products ◽  
Fluorescence Spectrophotometry

Determination of Petroleum Hydrocarbons Content in Soils From Suplacu de Barcău, Romania

2020 ◽  
Vol 65 (2) ◽  
pp. 57-64
Author(s):  
Loredana Mihaela Şeute ◽  
Keyword(s):  
Soil Pollution ◽  
Petroleum Hydrocarbons ◽  
Fluorescence Spectrometry ◽  
Total Petroleum Hydrocarbons ◽  
Intervention Thresholds ◽  
Petroleum Extraction

The level of pollution with petroleum compounds was evaluated in Suplacu de Barcău area based on the assessment of total petroleum hydrocarbons (TPH) concentrations in soil. As source of contamination, one active and another inactive petroleum extraction wells were chosen, and the concentrations were determined by fluorescence spectrometry. The results indicated alarming exceedances of the intervention thresholds, especially in the area where the activity is stopped, thus indicating long-term accumulation of pollutant and persistence in soil. Keywords: petroleum hydrocarbons, soil pollution, TPH, fluorescence spectrometry

scholarly journals Effects of Moisture Content and Solvent Additive on Headspace Solid-Phase Microextraction of Total Petroleum Hydrocarbons from Soil

2012 ◽  
Vol 14 (4) ◽  
pp. 331 ◽  
Author(s):  
M.B. Alimzhanova ◽  
B.N. Kenessov ◽  
M.K. Nauryzbayev ◽  
J.A. Koziel
Keyword(s):  
Moisture Content ◽  
Petroleum Hydrocarbons ◽  
Water Surface ◽  
Solid Phase Microextraction ◽  
Extraction Efficiency ◽  
Solid Phase ◽  
Soil Samples ◽  
Total Petroleum Hydrocarbons ◽  
Water Mixture

Present paper describes optimization of the method of quantitative determination of total petroleum hydrocarbons in soil samples using headspace solid - phase microextraction (SPME) in combination with gas chromatography - mass spectrometry (GC-MS). Effects of moisture content and solvent additives<br />were studied. It was established that an increase of the moisture content in soil leads to an increase of the response of petroleum hydrocarbons reaching its maximum at 15-20% depending on the soil type and concentration of total petroleum hydrocarbons followed by its gradual decrease. For the same concentration of petroleum hydrocarbons, an increase of moisture content in soil from 0 to 20% may lead to a 15x increase of total petroleum hydrocarbons response by solid - phase microextraction. Determination of total petroleum hydrocarbons in soils by SPME -GC-MS without moisture control of samples may lead to large errors, especially at low concentrations. It was established that addition of the solvent to a soil-water mixture allows dissolution of an oil film on the water surface and provides better extraction of hydrocarbons from soil to water phase. To avoid effect of moisture content on the extraction efficiency and more precise analysis of the real samples, addition of the excess distilled water must be done. Addition of the polar organic solvent to a soil-water mixture (10% isopropanol) allows dissolution of an oil film on the water surface and provides linear dependence of extraction efficiency vs total petroleum hydrocarbons content in soil. Testing of the optimized method on model soil samples provided quantitative data, results being in 30-120% range from the real values.

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