Hydride Generation and Condensation Flame Atomic Absorption Spectroscopic Determination of Antimony in Raw Coffee Beans and Processed Coffee

1982 ◽  
Vol 65 (5) ◽  
pp. 1146-1149
Author(s):  
Roy W Kuennen ◽  
Mark H Hahn ◽  
Fred L Fricke ◽  
Karen A Wolnik
Keyword(s):  
Atomic Absorption ◽  
Inductively Coupled Plasma ◽  
Hydride Generation ◽  
Dry Weight ◽  
Atomic Emission ◽  
Standard Reference Materials ◽  
National Bureau ◽  
Total Acid ◽  
Flame Atomic Absorption ◽  
Coffee Beans

Abstract A method was developed for determining Sb at nanogram per gram levels in raw coffee beans and processed coffee. The procedure uses either total acid digestion or extraction with 6M HCl followed by hydride generation/condensation with subsequent revolatilization of stibine (SbH3) and detection by flame atomic absorption spectroscopy. The lowest quantifiable level, based on a 2 g (dry weight) sample, is 2 ng Sb/g. The results of recoveries on spiked samples, precision studies on composited coffee samples, and the analysis of National Bureau of Standards Standard Reference Materials demonstrate the reliability and accuracy of the procedure. Sb concentrations in coffee samples were verified by neutron activation analysis and inductively coupled plasma atomic emission spectroscopy. Advantages of the method compared with the AOAC colorimetric procedure and hydride generation without condensation are discussed.

An Exploration Geochemical Technique for the Determination of Preconcentrated Organometallic Halides by ICP-AES

1988 ◽  
Vol 42 (7) ◽  
pp. 1293-1296 ◽  
Author(s):  
J. M. Motooka
Keyword(s):  
Atomic Absorption ◽  
Inductively Coupled Plasma ◽  
Atomic Emission ◽  
Operating Parameters ◽  
Plasma Atomic Emission ◽  
Geochemical Exploration ◽  
Inductively Coupled ◽  
Flame Atomic Absorption ◽  
Lower Limits

An atomic absorption extraction technique which is widely used in geochemical exploration for the determination of Ag, As, Au, Bi, Cd, Cu, Mo, Pb, Sb, and Zn has been modified and adapted to a simultaneous inductively coupled plasma-atomic emission instrument. The experimental and operating parameters are described for the preconcentration of the metals into their organometallic halides and for the determination of these metals. Lower limits of determination are equal to or improved over those for flame atomic absorption (except Au), and ICP results are very similar to the accepted AA values, with precision for the ICP data in excess of that necessary for exploration purposes.

Experimental and Theoretical Comparison of the Precision of Flame Atomic Absorption, Fluorescence, and Emission Measurements

1981 ◽  
Vol 35 (3) ◽  
pp. 317-324 ◽  
Author(s):  
N. W. Bower ◽  
J. D. Ingle
Keyword(s):  
Atomic Absorption ◽  
Flicker Noise ◽  
Power Spectra ◽  
Inner Filter Effect ◽  
Atomic Emission ◽  
Noise Power ◽  
Experimental Conditions ◽  
Noise Characteristics ◽  
Fluorescence Measurements ◽  
Flame Atomic Absorption

Theoretical equations and experimental evaluation procedures for the determination of the precision of flame atomic absorption, emission, and fluorescence measurements are presented. These procedures and noise power spectra are used to evaluate the precision and noise characteristics of atomic copper measurements with all three techniques under the same experimental conditions in an H2-air flame. At the detection limit, emission and fluorescence measurements are limited by background emission shot and flicker noise whereas absorption measurements are limited by flame transmission lamp flicker noise. Analyte flicker noise limits precision at higher analyte concentrations for all three techniques. Fluctutations in self-absorption and the inner filter effect are shown to contribute to the noise in atomic emission and fluorescence measurements.

scholarly journals Arsenic quantification techniques and ISO/IEC 17025 accreditation in Brazil

2019 ◽  
Vol 6 (14) ◽  
pp. 803-817
Author(s):  
Jefferson Luiz Antunes Santos ◽  
Jader Galba Busato ◽  
Rodrigo de Almeida Heringer ◽  
Juscimar da Silva ◽  
Leonardo Barros Dobbss
Keyword(s):  
Atomic Absorption Spectrometry ◽  
Atomic Absorption ◽  
Inductively Coupled Plasma ◽  
Hydride Generation ◽  
Absorption Spectrometry ◽  
Emission Spectrometry ◽  
Icp Oes ◽  
Analytical Technique ◽  
Inductively Coupled ◽  
Icp Ms

The importance of arsenic (As) quantification in environmental compartments is due to its risks to ecosystems and public health. There are reports of high concentrations of this metalloid in Brazil and technological differences between states are observed. The objective of this work was to present and discuss current scenarios of accreditation and compare the limit of quantification (LOQ) of As by analytical technique in Brazil. Data from accredited laboratories were collected on Inmetro website and in state metrological networks and then grouped and analyzed by state, matrix and analytical technique. There are large discrepancies between the number of laboratories per state and a good correlation with gross domestic product (GDP). Almost all laboratories have a LOQ less than the environmental limits. The observed list of techniques sorted from lowest to highest LOQ values is: for liquid samples ICP MS (inductively coupled plasma mass spectrometry), ET AAS (electrothermal atomic absorption spectrometry), HG AAS (hydride generation combined with atomic absorption spectrometry) or HG ICP OES (hydride generation combined with inductively coupled plasma optical emission spectrometry) and UV VIS (visible ultraviolet spectroscopy); for solids samples HG ICP OES, ICP MS, HG AAS, ET AAS and FAAS (flame atomic absorption spectrometry); and for bioindicators ICP MS, HG ICP OES. Analysis of As species is accredited in only one laboratory, but does not include all species.

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