Non-equilibrium chemistry and destruction of CO by X-ray flares

ABSTRACT Sources of X-rays such as active galactic nuclei and X-ray binaries are often variable by orders of magnitude in luminosity over time-scales of years. During and after these flares the surrounding gas is out of chemical and thermal equilibrium. We introduce a new implementation of X-ray radiative transfer coupled to a time-dependent chemical network for use in 3D magnetohydrodynamical simulations. A static fractal molecular cloud is irradiated with X-rays of different intensity, and the chemical and thermal evolution of the cloud are studied. For a simulated $10^5\, \mathrm{M}_\odot$ fractal cloud, an X-ray flux <0.01 erg cm−2 s−1 allows the cloud to remain molecular, whereas most of the CO and H2 are destroyed for a flux of ≥1 erg cm−2 s−1. The effects of an X-ray flare, which suddenly increases the X-ray flux by 105×, are then studied. A cloud exposed to a bright flare has 99 per cent of its CO destroyed in 10–20 yr, whereas it takes >103 yr for 99 per cent of the H2 to be destroyed. CO is primarily destroyed by locally generated far-UV emission from collisions between non-thermal electrons and H2; He+ only becomes an important destruction agent when the CO abundance is already very small. After the flare is over, CO re-forms and approaches its equilibrium abundance after 103–105 yr. This implies that molecular clouds close to Sgr A⋆ in the Galactic Centre may still be out of chemical equilibrium, and we predict the existence of clouds near flaring X-ray sources in which CO has been mostly destroyed but H is fully molecular.