KINETICS OF SINGLE AND MULTIPLE METAL ION SORPTION PROCESSES ON HUMIC SUBSTANCES

Soil Science ◽  
1996 ◽  
Vol 161 (8) ◽  
pp. 509-520 ◽  
Author(s):  
X. Jin ◽  
G. W. Bailey ◽  
Y. S. Yu ◽  
A. T. Lynch
Author(s):  
T. Yu. Butenko ◽  
R. Kh. Khamizov ◽  
E. V. Kaplun ◽  
A. P. Golikov ◽  
L. N. Kurilenko ◽  
...  
Keyword(s):  

2001 ◽  
Vol 16 (6) ◽  
pp. 651-658 ◽  
Author(s):  
D.J Bunker ◽  
J.T Smith ◽  
F.R Livens ◽  
J Hilton

1990 ◽  
Vol 55 (8) ◽  
pp. 1984-1990 ◽  
Author(s):  
José M. Hernando ◽  
Olimpio Montero ◽  
Carlos Blanco

The kinetics of the reactions of iron(III) with 6-methyl-2,4-heptanedione and 3,5-heptanedione to form the corresponding monocomplexes have been studied spectrophotometrically in the range 5 °C to 16 °C at I 25 mol l-1 in aqueous solution. In the proposed mechanism for the two complexes, the enol form reacts with the metal ion by parallel acid-independent and inverse-acid paths. The kinetic constants for both pathways have been calculated at five temperatures. Activation parameters have also been calculated. The results are consistent with an associative activation for Fe(H2O)63+ and dissociative activation for Fe(H2O)5(OH)2+. The differences in the results for the complexes of heptanediones studied are interpreted in terms of steric factors.


Author(s):  
Galina G. Talanova ◽  
Longgui Zhong ◽  
Richard A. Bartsch

Sign in / Sign up

Export Citation Format

Share Document