scholarly journals Towards implementing hierarchical porous zeolitic imidazolate frameworks in dye-sensitized solar cells

2019 ◽  
Vol 6 (7) ◽  
pp. 190723 ◽  
Author(s):  
Hani Nasser Abdelhamid ◽  
Ahmed M. El-Zohry ◽  
Jiayan Cong ◽  
Thomas Thersleff ◽  
Martin Karlsson ◽  
...  

A one-pot method for encapsulation of dye, which can be applied for dye-sensitized solar cells (DSSCs), and synthesis of hierarchical porous zeolitic imidazolate frameworks (ZIF-8), is reported. The size of the encapsulated dye tunes the mesoporosity and surface area of ZIF-8. The mesopore size, Langmuir surface area and pore volume are 15 nm, 960–1500 m 2 · g −1 and 0.36–0.61 cm 3 · g −1 , respectively. After encapsulation into ZIF-8, the dyes show longer emission lifetimes (greater than 4–8-fold) as compared to the corresponding non-encapsulated dyes, due to suppression of aggregation, and torsional motions.

2015 ◽  
Vol 3 (40) ◽  
pp. 20366-20374 ◽  
Author(s):  
Nianqing Fu ◽  
Yan Liu ◽  
Yanchun Liu ◽  
Wei Lu ◽  
Limin Zhou ◽  
...  

Hierarchical TiO2architecture with a remarkably improved surface area and light scattering effect was preparedviaone-step post-treatment for dye-sensitized solar cells, achieving a high efficiency of 8.82%.


Nanomaterials ◽  
2019 ◽  
Vol 9 (12) ◽  
pp. 1645 ◽  
Author(s):  
Seong Il Cho ◽  
Hye Kyeong Sung ◽  
Sang-Ju Lee ◽  
Wook Hyun Kim ◽  
Dae-Hwan Kim ◽  
...  

At an elevated temperature of 90 °C, a chemical bath deposition using an aqueous solution of Zn(NO3)2·6H2O and (CH2)6N4 resulted in the formation of both nanoflowers and microrods of ZnO on F-doped SnO2 glass with a seed layer. The nanoflowers and microrods were sensitized with dyes for application to the photoelectrodes of dye-sensitized solar cells (DSSCs). By extending the growth time of ZnO, the formation of nanoflowers was reduced and the formation of microrods favored. As the growth time was increased from 4 to 6 and then to 8 h, the open circuit voltage (Voc) values of the DSSCs were increased, whilst the short circuit current (Jsc) values varied only slightly. Changes in the dye-loading amount, dark current, and electrochemical impedance were monitored and they revealed that the increase in Voc was found to be due to a retardation of the charge recombination between photoinjected electrons and I3− ions and resulted from a reduction in the surface area of ZnO microrods. A reduced surface area decreased the dye contents adsorbed on the ZnO microrods, and thereby decreased the light harvesting efficiency (LHE). An increase in the electron collection efficiency attributed to the suppressed charge recombination counteracted the decreased LHE, resulting in comparable Jsc values regardless of the growth time.


2015 ◽  
Vol 139 ◽  
pp. 433-436 ◽  
Author(s):  
Parand Rostami ◽  
Ali Nemati ◽  
Mahdi Malekshahi Byranvand ◽  
Raheleh Mohammadpour ◽  
Hamidreza Faridi

RSC Advances ◽  
2015 ◽  
Vol 5 (90) ◽  
pp. 74107-74114 ◽  
Author(s):  
Ho-sub Kim ◽  
Jung Sang Suh

We have significantly enhanced the power conversion efficiency of dye-sensitized solar cells based on TiO2 nanotube membranes by increasing the inner surface area of the channels.


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