scholarly journals The second law of thermodynamics as variation on a theme of Carathéodory

2021 ◽  
Vol 477 (2253) ◽  
pp. 20210425
Author(s):  
Joe D. Goddard
Keyword(s):  
Energy Balance ◽  
State Space ◽  
Internal Energy ◽  
Second Law Of Thermodynamics ◽  
Irreversible Processes ◽  
Second Law ◽  
Classic Work ◽  
Axiomatic Foundation ◽  
Convexity Properties ◽  
Definition Of

This paper revisits the second law of thermodynamics via certain modifications of the axiomatic foundation provided by the celebrated 1909 work of Carathéodory. It is shown that his postulate of adiabatic inaccessibility represents one of several constraints on the energy balance that serve to establish the existence of thermostatic entropy as a foliation of state space, with temperature representing a force of constraint. To achieve the thermostatic version of the second law, as embodied in the postulates of Clausius and Gibbs, work principles are proposed to define thermostatic equilibrium and stability in terms of the convexity properties of internal energy, entropy and related thermostatic potentials. Comparisons are made with the classic work of Coleman and Noll on thermostatic equilibrium in simple continua, resulting in a few unresolved differences. Perhaps the most novel aspect of the current work is an extension to irreversible processes by means of a non-equilibrium entropy derived from recoverable work, which generalizes similar ideas in continuum viscoelasticity. This definition of entropy calls for certain revisions of modern theories of continuum thermomechanics by Coleman, Noll and others that are based on a generally inaccessible entropy and undefined temperature.

First and second laws of thermodynamics: relationship, “inconsistency”, hidden effects

2020 ◽  
pp. 63-73
Author(s):  
A. M. Savchenko ◽  
Yu. V. Konovalov ◽  
A. V. Laushkin
Keyword(s):  
Free Energy ◽  
Internal Energy ◽  
Second Law Of Thermodynamics ◽  
Second Law ◽  
Entropy Of Mixing ◽  
Ideal Mixing ◽  
Laws Of Thermodynamics ◽  
Relationship Of ◽  
The Relationship

The relationship of the first and second laws of thermodynamics based on their energy nature is considered. It is noted that the processes described by the second law of thermodynamics often take place hidden within the system, which makes it difficult to detect them. Nevertheless, even with ideal mixing, an increase in the internal energy of the system occurs, numerically equal to an increase in free energy. The largest contribution to the change in the value of free energy is made by the entropy of mixing, which has energy significance. The entropy of mixing can do the job, which is confirmed in particular by osmotic processes.

Thermodynamics as a fundamental science of reliability

2016 ◽  
Vol 230 (6) ◽  
pp. 598-608 ◽  
Author(s):  
Anahita Imanian ◽  
Mohammad Modarres
Keyword(s):  
Energy Dissipation ◽  
Entropy Generation ◽  
Damage Model ◽  
Second Law Of Thermodynamics ◽  
Reliability Function ◽  
Cumulative Damage ◽  
Life Assessment ◽  
Irreversible Processes ◽  
Second Law ◽  
Cumulative Hazard

Cumulative hazard and cumulative damage are important models for reliability and structural integrity assessment. This article reviews a previously developed thermodynamic entropy–based damage model and derives and demonstrates an equivalent reliability function. As such, a thermodynamically inspired approach to developing new definitions of cumulative hazard, cumulative damage, and life models of structures and components based on the second law of thermodynamics is presented. The article defines a new unified measure of damage in terms of energy dissipation associated with multiple interacting irreversible processes that represent the underlying failure mechanisms that cause damage and failure. Since energy dissipation leads to entropy generation in materials, it has been shown and experimentally demonstrated that the use of the total entropy generated in any degradation process is measurable and can ultimately be used to represent the time of failure of structures and components. This description therefore connects the second law of thermodynamics to the conventional models of reliability used in life assessment. Any variability in the entropic endurance to failure and uncertainties about the parameters of the entropic-based damage model lead to the time-to-failure distribution. In comparison with the conventional probabilistic reliability methods, deriving the reliability function in terms of the entropy generation can offer a general and more fundamental approach to representation of reliability. The entropic-based theory of damage and the equivalent reliability approach are demonstrated and confirmed experimentally by applying the complex interactive corrosion-fatigue degradation mechanism to samples of aluminum materials.

scholarly journals Diffusive Bejan number and second law of thermodynamics toward a new dimensionless formulation of fluid dynamics laws

2019 ◽  
Vol 23 (6 Part B) ◽  
pp. 4005-4022 ◽  
Author(s):  
Michele Trancossi ◽  
Jose Pascoa
Keyword(s):  
Fluid Dynamics ◽  
Entropy Generation ◽  
Fluid Dynamic ◽  
Second Law Of Thermodynamics ◽  
Integral Form ◽  
Second Law ◽  
Bejan Number ◽  
Definition Of ◽  
New Formulation ◽  
Dimensionless Formulation

In a recent paper, Liversage and Trancossi have defined a new formulation of drag as a function of the dimensionless Bejan and Reynolds numbers. Further analysis of this hypothesis has permitted to obtain a new dimensionless formulation of the fundamental equations of fluid dynamics in their integral form. The resulting equations have been deeply discussed for the thermodynamic definition of Bejan number evidencing that the proposed formulation allows solving fluid dynamic problems in terms of entropy generation, allowing an effective optimization of design in terms of the Second law of thermodynamics. Some samples are discussed evidencing how the new formulation can support the generation of an optimized configuration of fluidic devices and that the optimized configurations allow minimizing the entropy generation.

scholarly journals Thermodynamics in the Universe Described by the Emergence of Space and the Energy Balance Relation

Entropy ◽  
2019 ◽  
Vol 21 (2) ◽  
pp. 167
Author(s):  
Fei-Quan Tu ◽  
Yi-Xin Chen ◽  
Qi-Hong Huang
Keyword(s):  
Energy Balance ◽  
Present Model ◽  
Thermodynamic Description ◽  
Energy Condition ◽  
Second Law Of Thermodynamics ◽  
Second Law ◽  
First Law Of Thermodynamics ◽  
Generalized Second Law ◽  
Balance Relation ◽  
The Universe

It has previously been shown that it is more common to describe the evolution of the universe based on the emergence of space and the energy balance relation. Here we investigate the thermodynamic properties of the universe described by such a model. We show that the first law of thermodynamics and the generalized second law of thermodynamics (GSLT) are both satisfied and the weak energy condition are also fulfilled for two typical examples. Finally, we examine the physical consistency for the present model. The results show that there exists a good thermodynamic description for such a universe.

scholarly journals Quantum Thermodynamics in the Refined Weak Coupling Limit

Entropy ◽  
2019 ◽  
Vol 21 (8) ◽  
pp. 725 ◽  
Author(s):  
Ángel Rivas
Keyword(s):  
System Dynamics ◽  
Internal Energy ◽  
Weak Coupling ◽  
Weak Coupling Limit ◽  
Second Law ◽  
Quantum Thermodynamics ◽  
Thermodynamic Framework ◽  
Definition Of

We present a thermodynamic framework for the refined weak coupling limit. In this limit, the interaction between system and environment is weak, but not negligible. As a result, the system dynamics becomes non-Markovian breaking divisibility conditions. Nevertheless, we propose a derivation of the first and second law just in terms of the reduced system dynamics. To this end, we extend the refined weak coupling limit for allowing slowly-varying external drivings and reconsider the definition of internal energy due to the non-negligible interaction.

Thermodynamic Modeling for Discrete-Time Large-Scale Dynamical Systems

2011 ◽  
Author(s):  
Wassim M. Haddad ◽  
Sergey G. Nersesov
Keyword(s):  
Dynamical System ◽  
Dynamical Systems ◽  
Thermodynamic Modeling ◽  
Discrete Time ◽  
Large Scale ◽  
Type Inequality ◽  
Second Law Of Thermodynamics ◽  
Second Law ◽  
Thermodynamic Models ◽  
Definition Of

This chapter describes the thermodynamic modeling of discrete-time large-scale dynamical systems. In particular, it develops nonlinear discrete-time compartmental models that are consistent with thermodynamic principles. Since thermodynamic models are concerned with energy flow among subsystems, the chapter constructs a nonlinear compartmental dynamical system model characterized by conservation of energy and the first law of thermodynamics. It then provides a deterministic definition of entropy for a large-scale dynamical system that is consistent with the classical thermodynamic definition of entropy and shows that it satisfies a Clausius-type inequality leading to the law of entropy nonconservation. The chapter also considers nonconservation of entropy and the second law of thermodynamics, nonconservation of ectropy, semistability of discrete-time thermodynamic models, entropy increase and the second law of thermodynamics, and thermodynamic models with linear energy exchange.

Entropy Increase as Tendency: Drive and Effector

2017 ◽  
pp. 93-96
Author(s):  
Alberto Gianinetti
Keyword(s):  
Particle Motion ◽  
Second Law Of Thermodynamics ◽  
Second Law ◽  
Entropy Increase ◽  
Probable State ◽  
Definition Of

A useful definition of entropy is “a function of the system equilibration, stability, and inertness”, and the tendency to an overall increase of entropy, which is set forth by the second law of thermodynamics, should be meant as “the tendency to the most probable state”, that is, to a state having the highest equilibration, stability, and inertness that the system can reach. The tendency to entropy increase is driven by the probabilistic distributions of matter and energy and it is actualized by particle motion.

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