Cavitation control in steels of high residual element content

The cavitational mode of failure of prior austenite grain boundaries in bainitic creep-resisting low alloy steels is now well established as a principal factor in the high incidence of cracking problems which has developed on modern power plant in recent years. The microstructural features dominating the cavitation process at the reheat temperature in a ½CMV bainitic steel of high classical residual level have been determined. The prior austenite grain boundaries become zones of comparative weakness ca . 1 pm thick at 700 °C and are incapable of sustaining significant shear loads. Deformation is therefore initiated by a relaxation of load, through a process of prior austenite grain boundary zone shear, from inclined to transverse boundaries such that a concentration of normal stress develops across the latter. The overall deformation is thereafter determined by cavitation of the transverse boundary zones, the necessary inclined boundary displacements being accommodated by further grain boundary zone shear. Transverse boundary cavitation is shown to be an essentially time-independent process of localized ductile microvoid coalescence resulting from the plastic deformation of the boundary zone.

1999 ◽  
Vol 5 (S2) ◽  
pp. 238-239
Author(s):  
Yong-Jun Oh ◽  
Min-Chul Kim ◽  
Jun Hwa Hong

Bainitic low alloy steel has a complex microstructure exhibiting several types of boundaries. The boundaries in bainitic steel, although certain boundaries are absent with respect to the alloy composition and the manufacturing process, could be typically divided into 4 types; dislocation cell boundary, lath boundary, packet boundary, and prior austenite grain boundary, in increasing order of size. The size and distribution of the respective boundaries are an important factor which controls the mechanical properties of the steels, including brittle fracture. In the present research, the characteristics of the boundaries in the bainitic low alloy steels were investigated in view of misorientation between grains enclosed by the respective boundaries.The alloys investigated were Mn-Mo-Ni low alloy forging steels having chemical compositions shown in TABLE 1. Steel-A was manufactured by the Vacuum Carbon Deoxidation(VCD) process. For the finer prior austenite grain size, Steel-B was produced by the aluminium addition and the silicon killing process. Before EBSD analysis, the microstructures of the alloys were observed using SEM and TEM. EBSD measurements were obtained using a Link OPAL system(Oxford) linked to a JEOL JSM 6300 SEM operating at 15KeV with the sample tilted at 70°.


2008 ◽  
Vol 59 (6) ◽  
pp. 786-793 ◽  
Author(s):  
K.S. Cho ◽  
H.S. Sim ◽  
J.H. Kim ◽  
J.H. Choi ◽  
K.B. Lee ◽  
...  

Author(s):  
Yuxin Cao ◽  
Xiangliang Wan ◽  
Feng Zhou ◽  
Yu Shen ◽  
Yu Liu ◽  
...  

Abstract The present study elucidates the influence of Mo content on the microstructure – toughness relationship in the coarsegrained heat-affected zone of high-strength low-alloy steels. The low-Mo and high-Mo steels were subjected to 100 kJ cm–1 heat input welding thermal cycling. The results indicated that (Ti,Mo)-carbonitrides were formed in high-Mo steel, whereas (Ti,Nb)-carbonitrides were formed in low-Mo steel. The finer and dispersed precipitates in high-Mo steel refined the prior austenite grain in the coarse-grained heat-affected zone based on the grain boundary pinning effect. However, the smaller prior austenite grain and excessive Mo content induced the formation of an entirely bainitic microstructure in high-Mo steel. Furthermore, a higher fraction of martensite –austenite constituents was observed in high-Mo steel. These results could be responsible for the deterioration of the toughness in the coarse-grained heat-affected zone of high-Mo steel.


A previous study of reheat cracking in a CrMoV steel (Ducol W-30), in which the fracture toughness of the coarse grain size region of the h.a.z. was measured as a function of temperature, revealed a large decrease in toughness at 600 °C accompanied by prior austenite grain boundary (p.a.g.b.) fracture (Ritter & McPherson 1974). This severe embrittlement was eliminated if the steel was heated to 680 °C before testing at 600 °C suggesting that the effect may have been associated with a p.a.g.b. segregation effect. This hypothesis has been examined by comparing the degree of embrittlement at 600 °C of specimens with stimulated h.a.z. microstructures prepared from laboratory heats, with the same alloying element composition as the commercial steel used previously, but doped with the trace elements, S, P, As, Sb, Sn, Gu, A1 and B, singly or in various combinations.


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