scholarly journals Linking Fungal and Bacterial Proliferation to Microbiologically Influenced Corrosion in B20 Biodiesel Storage Tanks

2018 ◽  
Author(s):  
Blake W. Stamps ◽  
Caitlin L. Bojanowski ◽  
Carrie A. Drake ◽  
Heather S. Nunn ◽  
Pamela F. Lloyd ◽  
...  
Keyword(s):  
Methyl Esters ◽  
Microbiologically Influenced Corrosion ◽  
Storage Tanks ◽  
Bacterial Populations ◽  
Animal Fats ◽  
Ultra Low Sulfur Diesel ◽  
Fungal Populations ◽  
Microbial Proliferation ◽  
Low Sulfur

ABSTRACTBiodiesel is a renewable substitute, or extender, for petroleum diesel that is composed of a mixture of fatty acid methyl esters (FAME) derived from plant and animal fats. Ultra-low sulfur diesel (ULSD) blended with up to 20% FAME can be used interchangeably with ULSD, is compatible with existing infrastructure, but is also more susceptible to biodegradation. Microbial proliferation and fuel degradation in biodiesel blends has not been directly linked in situ to microbiologically influenced corrosion. We, therefore, conducted a yearlong study of B20 storage tanks in operation at two locations, identified the microorganisms responsible for observed fuel fouling and degradation, and measured in situ corrosion. The bacterial populations were more diverse than the fungal populations, and largely unique to each location. The bacterial populations included members of the Acetobacteraceae, Clostridiaceae, and Proteobacteria. The abundant Eukaryotes at both locations consisted of the same taxa, including a filamentous fungus within the family Trichocomaceae, and the Saccharomycetaceae family of yeasts. Increases in the absolute and relative abundances of the Trichocomaceae were correlated with significant, visible fouling and pitting corrosion. This study identified the relationship between recurrent fouling of B20 with increased rates of corrosion, largely at the bottom of the sampled storage tanks.

scholarly journals In situ Linkage of Fungal and Bacterial Proliferation to Microbiologically Influenced Corrosion in B20 Biodiesel Storage Tanks

2020 ◽  
Vol 11 ◽  
Author(s):  
Blake W. Stamps ◽  
Caitlin L. Bojanowski ◽  
Carrie A. Drake ◽  
Heather S. Nunn ◽  
Pamela F. Lloyd ◽  
...  
Keyword(s):  
Microbiologically Influenced Corrosion ◽  
Storage Tanks ◽  
Bacterial Proliferation

Cotton Seed FAME Combustion and Emissions Research in a DI Diesel Engine

2013 ◽  
Author(s):  
Valentin Soloiu ◽  
Jabeous Weaver ◽  
Henry Ochieng ◽  
Marvin Duggan ◽  
Sherwin Davoud ◽  
...  
Keyword(s):  
Diesel Engine ◽  
Cotton Seed ◽  
Methyl Esters ◽  
Direct Injection ◽  
Mechanical Efficiency ◽  
Ultra Low Sulfur Diesel ◽  
Indicated Mean Effective Pressure ◽  
A Value ◽  
Carbon Dioxide Co2 ◽  
Low Sulfur

This study investigates the combustion characteristics of cotton seed fatty acid methyl esters (FAME), with C100 (100% cotton seed biodiesel) and C20 (20% cotton seed biodiesel, 80% ultra-low sulfur diesel #2), in a direct injection diesel engine and compares the results with ultra-low sulfur diesel #2 (ULSD#2). The dynamic viscosity of C100 was found to meet the American Society for Testing and Materials (ASTM) standard. The lower heating value obtained for C100 was 37.7 MJ/kg, compared to 42.7 MJ/kg for ULSD#2. ULSD#2 and C100 displayed ignition delays of 9.6 crank angle degrees (CAD) and 7 CAD representing 1.14 ms and 0.83 ms respectively and a combustion time of 4ms (35 CAD) at 1400 rpm and 8 bar indicated mean effective pressure (IMEP) (100% load). The apparent heat release of the tested fuels at 8 bar IMEP showed both a premixed and diffusion phase and produced maximum values of 122 and 209 J/CAD for C100 and ULSD#2 respectively, with a decreasing trend occurring with increase in percentage of FAME. The 50% mass burnt (CA50) for 100% biodiesel was found to be 3 CAD advanced, compared with ULSD#2. The maximum total heat flux rates showed a value of 3.2 MW/m2 for ULSD#2 at 8 bar IMEP with a 6% increase observed for C100. Mechanical efficiency of ULSD#2 was 83% and presented a 5.35% decrease for C100, while the overall efficiency was 36% for ULSD#2 and 33% for C100 at 8 bar IMEP. The nitrogen oxides (NOx) for C100 presented an 11% decrease compared with ULSD#2. Unburned hydrocarbons value (UHC) for ULSD#2 was 2.8 g/kWh at 8 bar IMEP, and improved by 18% for C100. The carbon monoxide (CO) emissions for C100 decreased by 6% when compared to ULSD#2 at 3 bar IMEP but were relatively constant at 8 bar IMEP, presenting a value of 0.82 g/kWh for both fuels. The carbon dioxide (CO2) emissions for C100 increased by 1% compared with ULSD#2, at 3 bar IMEP. The soot value for ULSD#2 was 1.5 g/kWh and presented a 42% decrease for C100 at 8 bar IMEP. The results suggest a very good performance of cotton seed biodiesel, even at very high content of 100%, especially on the emissions side that showed decreasing values for regulated and non-regulated species.

scholarly journals Locating and Quantifying Carbon Steel Corrosion Rates Linked to Fungal B20 Biodiesel Degradation

2021 ◽  
Author(s):  
James G. Floyd ◽  
Blake W. Stamps ◽  
Wendy J. Goodson ◽  
Bradley S. Stevenson
Keyword(s):  
Carbon Steel ◽  
Methyl Esters ◽  
Fungal Growth ◽  
Steel Corrosion ◽  
The United States ◽  
Microbiologically Influenced Corrosion ◽  
Valuable Insight ◽  
Storage Tanks ◽  
Corrosion Rates ◽  
Biodiesel Fuels

Fungi that degrade B20 biodiesel in storage tanks have also been linked to microbiologically influenced corrosion (MIC). A member of the filamentous fungal genus Byssochlamys , and a yeast from the genus Wickerhamomyces were isolated from heavily contaminated B20 storage tanks from multiple Air Force bases. Although these taxa were linked to microbiologically influenced corrosion in situ , precise measurement of their corrosion rates and pitting severity on carbon steel was not available. In the experiments described here, we directly link fungal growth on B20 biodiesel to higher corrosion rates and pitting corrosion of carbon steel under controlled conditions. When these fungi were growing solely on B20 biodiesel for carbon and energy, consumption of FAME and n-alkanes was observed. The corrosion rates for both fungi were highest at the interface between the B20 biodiesel and the aqueous medium, where they acidified the medium and produced deeper pits than abiotic controls. Byssochlamys produced the most corrosion of carbon steel and produced the greatest pitting damage. This study characterizes and quantifies the corrosion of carbon steel by fungi that are common in fouled B20 biodiesel through their metabolism of the fuel, providing valuable insight for assessing MIC associated with storage and dispensing B20 biodiesel. IMPORTANCE Biodiesel is widely used across the United States and worldwide, blended with ultralow sulfur diesel in various concentrations. In this study we were able to demonstrate that the filamentous fungi Byssochlamys AF004 and the yeast Wickerhamomyces SE3 were able to degrade fatty acid methyl esters and alkanes in biodiesel causing increases in acidity. Both fungi also accelerated the corrosion of carbon steel, especially at the interface of the fuel and water, where their biofilms were located. This research provides controlled, quantified measurements and the localization of microbiologically influenced corrosion caused by common fungal contaminants in biodiesel fuels.

scholarly journals Preparation and Evaluation of Jojoba Oil Methyl Esters as Biodiesel and as a Blend Component in Ultra-Low Sulfur Diesel Fuel

2009 ◽  
Vol 3 (2) ◽  
pp. 214-223 ◽  
Author(s):  
Shailesh N. Shah ◽  
Brajendra K. Sharma ◽  
Bryan R. Moser ◽  
Sevim Z. Erhan
Keyword(s):  
Diesel Fuel ◽  
Methyl Esters ◽  
Jojoba Oil ◽  
Ultra Low Sulfur Diesel ◽  
Low Sulfur ◽  
Preparation And Evaluation

scholarly journals Locating and Quantifying Carbon Steel Corrosion Rates Linked to Fungal B20 Biodiesel Degradation

2021 ◽  
Author(s):  
James G Floyd ◽  
Blake W Stamps ◽  
Wendy J Crookes-Goodson ◽  
Bradley Scott Stevenson
Keyword(s):  
Carbon Steel ◽  
Air Force ◽  
Fungal Growth ◽  
Steel Corrosion ◽  
Microbiologically Influenced Corrosion ◽  
Valuable Insight ◽  
Storage Tanks ◽  
Corrosion Rates ◽  
Abiotic Controls

Fungi that degrade B20 biodiesel in storage tanks have also been linked to microbiologically influenced corrosion (MIC). A member of the filamentous fungal genus Byssochlamys, and a yeast from the genus Wickerhamomyces were isolated from heavily contaminated B20 storage tanks from multiple Air Force bases. Although these taxa were linked to microbiologically influenced corrosion in situ, precise measurement of their corrosion rates and pitting severity on carbon steel was not available. In the experiments described here, we directly link fungal growth on B20 biodiesel to higher corrosion rates and pitting corrosion of carbon steel under controlled conditions. When these fungi were growing solely on B20 biodiesel for carbon and energy, consumption of FAME and n-alkanes was observed. The corrosion rates for both fungi were highest at the interface between the B20 biodiesel and the aqueous medium, where they acidified the medium and produced deeper pits than abiotic controls. Byssochlamys produced the most corrosion of carbon steel and produced the greatest pitting damage. This study characterizes and quantifies the corrosion of carbon steel by fungi that are common in fouled B20 biodiesel through their metabolism of the fuel, providing valuable insight for assessing MIC associated with storage and dispensing B20 biodiesel.

Formulation and tribological behavior of ultra-low sulfur diesel fuels microemulsified with glycerin

Fuel ◽  
2021 ◽  
Vol 292 ◽  
pp. 120257
Author(s):  
Igor M.A. Uchôa ◽  
Marcell S. Deus ◽  
Eduardo L. Barros Neto
Keyword(s):  
Tribological Behavior ◽  
Diesel Fuels ◽  
Ultra Low Sulfur Diesel ◽  
Low Sulfur
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