scholarly journals Oscillator-strength enhancement of electric-dipole-forbidden transitions in evanescent light at total reflection

2005 ◽  
Vol 71 (1) ◽  
Author(s):  
Satoshi Tojo ◽  
Masahiro Hasuo
Author(s):  
Fernando Ramirez-Martinez ◽  
Francisco Sebastian Ponciano Ojeda ◽  
Santiago Hernandez-Gomez ◽  
Alberto Del Angel Medina ◽  
Cristian Adrián Moijca-Casique ◽  
...  

2018 ◽  
Author(s):  
F. Ponciano-Ojeda ◽  
S. Hernández-Gómez ◽  
C. Mojica-Casique ◽  
L. M. Hoyos ◽  
J. Flores-Mijangos ◽  
...  

2002 ◽  
Vol 589-590 ◽  
pp. 139-145 ◽  
Author(s):  
Toshiki Hara ◽  
Yasushi Nomura ◽  
Susumu Narita ◽  
Hirotoshi Ito ◽  
Tai-ichi Shibuya

2014 ◽  
Vol 104 (5) ◽  
pp. 051116 ◽  
Author(s):  
Lei Zhang ◽  
Leung-Kway Lee ◽  
Chu-Hsiang Teng ◽  
Tyler A. Hill ◽  
Pei-Cheng Ku ◽  
...  

Atoms ◽  
2020 ◽  
Vol 8 (2) ◽  
pp. 21 ◽  
Author(s):  
Elmar Träbert

Emission lines of singly charged ions populate many astrophysical spectra. However, the interpretation of the line intensities (usually line ratios) often depends on the transition rates of the decays of very long-lived low-lying levels. For example, the line ratio of two electric-dipole forbidden transitions in the 3s 2 3p 3 ground configuration of singly ionized sulfur (ion S + , spectrum S II) has been interpreted in terms of a density diagnostic for planetary nebulae, i.e., for densities in the order of 10 4 cm − 3 . The predicted lifetimes of the 2 D 3 / 2 , 5 / 2 o levels are in the order of one hour. Modeling indicates that a 10% uncertainty of the lifetime determination in this case corresponds to a 50% uncertainty of the density diagnostic. The available theoretical lifetime predictions scatter by much more than 10%. Considerations about an experimental approach are presented with the goal of instigating a measurement of the actual level lifetimes.


2015 ◽  
Vol 723 ◽  
pp. 799-803
Author(s):  
Min Xu

Wavelengths, transition probabilities and oscillator strengths have been calculated for electric dipole (E1) transitions and magnetic dipole (M1) transitions in Cu-like Au ion. These values are obtained in the configuration interaction (CI) and using the fully relativistic multiconfiguration Dirac-Fock (MCDF) method including quantum electrodynamical (QED) effect and Breit correction. Obtained energy levels of some excited states in Cu-like Au ion from the method are generally in good agreement with valuable theoretical and experimental results. The calculation results indicate that for high-Z highly ionized atom, some forbidden transitions are very important.


2009 ◽  
Vol 2009 ◽  
pp. 1-9 ◽  
Author(s):  
H. Debecca Devi ◽  
Ch. Sumitra ◽  
Th. David Singh ◽  
N. Yaiphaba ◽  
N. Mohondas Singh ◽  
...  

Absorption difference and comparative absorption spectrophotometric studies involving 4f-4f transitions of Nd(III) and different amino acids: DL-valine, DL-alanine, and β-alanine in presence and absence of Ca(II) and Zn(II) in aqueous and different aquated organic solvents have been carried out. Variations in the spectral energy parameters: Slater-Condon (FK) factor, Racah (EK), Lande factor (ξ4f), nephelauxetic ratio (β), bonding (b1/2), percentage covalency (δ) are calculated to explore the mode of interaction of Nd(III) with different amino acids: DL-valine, DL-alanine, and β-alanine. The values of experimentally calculated oscillator strength (P) and computed values of Judd-Ofelt electric dipole intensity parameters, Tλ (λ = 2,4,6), are also determined for different 4f-4f transitions. The variation in the values of P and Tλ parameters explicitly shows the relative sensitivities of the 4f-4f transitions as well as the specific correlation between relative intensities, ligand structures, and nature of Nd(III)-ligand interaction.


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