Nonadiabatic quantum fluctuations in the neutral ground state of tetrathiafulvalene- p -chloranil

2019 ◽  
Vol 100 (20) ◽  
Author(s):  
Yuko Watanabe ◽  
Hideo Ando ◽  
Akira Takahashi ◽  
Norikazu Tomita
Author(s):  
Abhiroop Lahiri ◽  
Swapan K Pati

Abstract We have considered and alternating spin-½/spin-1 chain with nearest-neighbor (J1), next-nearest neighbor (J2) antiferromagnetic Heisenberg interactions along with z-component of the Dzyaloshinskii-Moriya(DM) (Dz) interaction. The Hamiltonian has been studied using (a) Linear Spin-Wave Theory(LSWT) and (b) Density Matrix Renormalization Group (DMRG). The system had been reported earlier as a classical ferrimagnet only when nearest neighbor exchange interactions are present. Both the antiferromagnetic next-nearest neighbor interactions and DM interactions introduce strong quantum fluctuations and due to which all the signatures of ferrimagnetism vanishes. We find that the nonzero J2 introduces strong quantum fluctuations in each of the spin sites due to which the z-components of both spin-1 and spin-1/2 sites average out to be zero. The ground state becomes a singlet. The presence of J1 along with Dzintroduces a short range order but develops long range order along the XY plane. J1 along with J2induces competing phases with structure factor showing sharp and wide peaks, at two different angles reflecting the spin spiral structure locally as well as in the underlying lattice. Interestingly, we find that the Dz term removes the local spin spiral structure in z-direction, while developing a spiral order in the XY plane.


2000 ◽  
Vol 284-288 ◽  
pp. 1623-1624
Author(s):  
B.S. Dumesh ◽  
V.A. Panfilov ◽  
A.M. Tikhonov ◽  
D.N. Fourzikov

2006 ◽  
Vol 128 (21) ◽  
pp. 6847-6853 ◽  
Author(s):  
Yi Liao ◽  
Sanchali Bhattacharjee ◽  
Kimberly A. Firestone ◽  
Bruce E. Eichinger ◽  
Rajan Paranji ◽  
...  

1998 ◽  
Vol 13 (01) ◽  
pp. 33-37 ◽  
Author(s):  
M. N. SERGEENKO

Quasiclassical solution of the three-dimensional Schrödinger's equation is given. It is shown apparently that the exitence of nonzero minimal angular momentum M0=ℏ/2 corresponds to the quantum fluctuations of the angular momentum and contributes to the energy of the ground state.


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