Theoretical and experimental investigations of polarization switching in ferroelectric materials

2004 ◽  
Vol 69 (6) ◽  
Author(s):  
A. Picinin ◽  
M. H. Lente ◽  
J. A. Eiras ◽  
J. P. Rino
RSC Advances ◽  
2016 ◽  
Vol 6 (74) ◽  
pp. 70557-70562 ◽  
Author(s):  
F. Wang ◽  
B. Li ◽  
Y. Ou ◽  
L. F. Liu ◽  
C. Z. Peng ◽  
...  

The elastocaloric effect in PbTiO3 with 90° domain structure under the applied stress field at room temperature has been studied. A negative ΔTσ of −7.2 K can be obtained by controlled polarization switching under the applied stress fields.


Author(s):  
S. H. Baek ◽  
C. B. Eom

As a room temperature multi-ferroic with coexisting anti-ferromagnetic, ferroelectric and ferroelastic orders, BiFeO 3 has been extensively studied to realize magnetoelectric devices that enable manipulation of magnetic ordering by an electric field. Moreover, BiFeO 3 is a promising candidate for ferroelectric memory devices because it has the largest remanent polarization ( P r >100 μC cm −2 ) of all ferroelectric materials. For these applications, controlling polarization switching by an electric field plays a crucial role. However, BiFeO 3 has a complex switching behaviour owing to the rhombohedral symmetry: ferroelastic (71 ° , 109 ° ) and ferroelectric (180 ° ) switching. Furthermore, the polarization is switched through a multi-step process: 180 ° switching occurs through three sequential 71 ° switching steps. By using monodomain BiFeO 3 thin-film heterostructures, we correlated such multi-step switching to the macroscopically observed reliability issues of potential devices such as retention and fatigue. We overcame the retention problem (i.e. elastic back-switching of the 71 ° switched area) using monodomain BiFeO 3 islands. Furthermore, we suppressed the fatigue problem of 180 ° switching, i.e. loss of switchable polarization with switching cycles, using a single 71 ° switching path. Our results provide a framework for exploring a route to reliably control multiple-order parameters coupled to ferroelastic order in other rhombohedral and lower-symmetry materials.


2011 ◽  
Vol 21 (5) ◽  
pp. 802-802 ◽  
Author(s):  
Martyn A. McLachlan ◽  
David W. McComb ◽  
Mary P. Ryan ◽  
Anna N. Morozovska ◽  
Eugene A. Eliseev ◽  
...  

Author(s):  
Jie Wang ◽  
Marc Kamlah

A three-dimensional nonlinear finite element formulation for ferroelectric materials is developed based on a principle of virtual work. The formulation includes the coupling of three physical fields, namely polarization field, electric field and strain field. The developed finite element formulation is employed to investigate the polarization distribution near a flaw in a ferroelectric single crystal under mechanical loadings. It is found that the polarization switching takes place near the flaw tip if the loadings exceed a critical value. In the simulation, we do not take any prior assumptions, i.e. without any switching criterion, on the polarization switching. The polarization switching is a result of the minimization of the total energy in the simulated system.


Author(s):  
Naoki Yamamoto ◽  
Makoto Kikuchi ◽  
Tooru Atake ◽  
Akihiro Hamano ◽  
Yasutoshi Saito

BaZnGeO4 undergoes many phase transitions from I to V phase. The highest temperature phase I has a BaAl2O4 type structure with a hexagonal lattice. Recent X-ray diffraction study showed that the incommensurate (IC) lattice modulation appears along the c axis in the III and IV phases with a period of about 4c, and a commensurate (C) phase with a modulated period of 4c exists between the III and IV phases in the narrow temperature region (—58°C to —47°C on cooling), called the III' phase. The modulations in the IC phases are considered displacive type, but the detailed structures have not been studied. It is also not clear whether the modulation changes into periodic arrays of discommensurations (DC’s) near the III-III' and IV-V phase transition temperature as found in the ferroelectric materials such as Rb2ZnCl4.At room temperature (III phase) satellite reflections were seen around the fundamental reflections in a diffraction pattern (Fig.1) and they aligned along a certain direction deviated from the c* direction, which indicates that the modulation wave vector q tilts from the c* axis. The tilt angle is about 2 degree at room temperature and depends on temperature.


Sign in / Sign up

Export Citation Format

Share Document