Nearly-second-order nematic-isotropic phase transition in a cyclic thermotropic liquid crystal

1993 ◽  
Vol 48 (1) ◽  
pp. R1-R4 ◽  
Author(s):  
Jian-Feng Li ◽  
Virgil Percec ◽  
Charles Rosenblatt
1984 ◽  
Vol 29 (2) ◽  
pp. 1010-1012 ◽  
Author(s):  
Charles Rosenblatt ◽  
Satyendra Kumar ◽  
J. D. Litster

2017 ◽  
Author(s):  
Niamh Mac Fhionnlaoich ◽  
Stephen Schrettl ◽  
Nicholas B. Tito ◽  
Ye Yang ◽  
Malavika Nair ◽  
...  

The arrangement of nanoscale building blocks into patterns with microscale periodicity is challenging to achieve via self-assembly processes. Here, we report on the phase transition-driven collective assembly of gold nanoparticles in a thermotropic liquid crystal. A temperature-induced transition from the isotropic to the nematic phase leads to the assembly of individual nanometre-sized particles into arrays of micrometre-sized aggregates, whose size and characteristic spacing can be tuned by varying the cooling rate. This fully reversible process offers hierarchical control over structural order on the molecular, nanoscopic, and microscopic level and is an interesting model system for the programmable patterning of nanocomposites with access to micrometre-sized periodicities.


Author(s):  
I. Andrade-Silva ◽  
U. Bortolozzo ◽  
C. Castillo-Pinto ◽  
M. G. Clerc ◽  
G. González-Cortés ◽  
...  

Order–disorder phase transitions driven by temperature or light in soft matter materials exhibit complex dissipative structures. Here, we investigate the spatio-temporal phenomena induced by light in a dye-doped nematic liquid crystal layer. Experimentally, for planar anchoring of the nematic layer and high enough input power, photoisomerization processes induce a nematic–isotropic phase transition mediated by interface propagation between the two phases. In the case of a twisted nematic layer and for intermediate input power, the light induces a spatially modulated phase, which exhibits stripe patterns. The pattern originates as an instability mediated by interface propagation between the modulated and the homogeneous nematic states. Theoretically, the phase transition, emergence of stripe patterns and front dynamics are described on the basis of a proposed model for the dopant concentration coupled with the nematic order parameter. Numerical simulations show quite a fair agreement with the experimental observations. This article is part of the theme issue ‘Dissipative structures in matter out of equilibrium: from chemistry, photonics and biology (part 2)’.


2017 ◽  
Vol 131 (4) ◽  
pp. 949-951 ◽  
Author(s):  
K. Csach ◽  
A. Juríková ◽  
J. Miškuf ◽  
N. Tomašovičová ◽  
V. Gdovinová ◽  
...  

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