Ordering of agarose near the macroscopic gelation point

2004 ◽  
Vol 69 (4) ◽  
Author(s):  
Donatella Bulone ◽  
Daniela Giacomazza ◽  
Vincenzo Martorana ◽  
Jay Newman ◽  
Pier L. San Biagio
Keyword(s):  
1998 ◽  
Vol 37 (Part 1, No. 5B) ◽  
pp. 2815-2817 ◽  
Author(s):  
Hirotaka Okabe ◽  
Keiichi Kuboyama ◽  
Kazuhiro Hara ◽  
Shoich Kai
Keyword(s):  

1961 ◽  
Vol 5 (16) ◽  
pp. S16-S18 ◽  
Author(s):  
H. S. Lilley
Keyword(s):  

2007 ◽  
Vol 19 (5-6) ◽  
pp. 510-519 ◽  
Author(s):  
Liviu Sacarescu ◽  
Rodinel Ardeleanu ◽  
Gabriela Sacarescu ◽  
Mihaela Simionescu

A new polysilane with pendant metal complex segments was synthesized and characterized. For this purpose a macroligand has been prepared starting from a iodopropyl-functionalized polysilane and a bis(salicylideneimine) derivative. Under mild reaction temperature this polymeric ligand was able to form crosslinked structures. The material was then doped with metal cations and was investigated to observe the system behavior near the gelation point. The UV-vis spectrum of the new material indicated that the electronic structures of the conjugate polysilane chain and metal complex remained unaffected by the condensation reaction process. Similar polymeric structures could be useful to build new organic electroconductive devices.


2012 ◽  
Vol 10 (6) ◽  
pp. 1859-1866 ◽  
Author(s):  
Luiza Gradinaru ◽  
Constantin Ciobanu ◽  
Stelian Vlad ◽  
Maria Bercea ◽  
Marcel Popa

AbstractPolyurethanes based on poly(ethylene oxide)-poly(propylene oxide)-poly(ethylene oxide) triblock copolymer, succinic or citric acid, and ethyl ester L-lysine diisocyanate were synthesized and characterized by FT-IR and GPC. Wetting properties were evaluated by contact angle determinations. The critical micelle concentration was determined from surface tension measurements. Their abillity to undergo self-aggregation and temperature induced gelation was investigated through dynamic oscillatory measurements. The gelation point, sol-gel transitions, and gel structure are influenced by polymer structure, composition, molecular weight, concentration, and heating rate.


1992 ◽  
Vol 195 (5-6) ◽  
pp. 509-512 ◽  
Author(s):  
Toshikazu Takigawa ◽  
Masaoki Takahashi ◽  
Kenji Urayama ◽  
Toshiro Masuda

1999 ◽  
Vol 263-264 ◽  
pp. 73-76 ◽  
Author(s):  
Hirotaka Okabe ◽  
Keiichi Kuboyama ◽  
Kazuhiro Hara ◽  
Shoichi Kai

Sign in / Sign up

Export Citation Format

Share Document