Synthesis and Characterization of Polysilane-Organometallic Complexes
2007 ◽
Vol 19
(5-6)
◽
pp. 510-519
◽
Keyword(s):
A new polysilane with pendant metal complex segments was synthesized and characterized. For this purpose a macroligand has been prepared starting from a iodopropyl-functionalized polysilane and a bis(salicylideneimine) derivative. Under mild reaction temperature this polymeric ligand was able to form crosslinked structures. The material was then doped with metal cations and was investigated to observe the system behavior near the gelation point. The UV-vis spectrum of the new material indicated that the electronic structures of the conjugate polysilane chain and metal complex remained unaffected by the condensation reaction process. Similar polymeric structures could be useful to build new organic electroconductive devices.
1994 ◽
Vol 52
◽
pp. 760-761
2009 ◽
Vol 13
(02)
◽
pp. 223-234
◽
2010 ◽
Vol 695
(9)
◽
pp. 1293-1299
◽
2015 ◽
Vol 1095
◽
pp. 341-344
◽
Keyword(s):
2021 ◽