scholarly journals Investigating spin coupling across a three-dimensional interface in core/shell magnetic nanoparticles

2020 ◽  
Vol 4 (3) ◽  
Author(s):  
C. Kons ◽  
Manh-Huong Phan ◽  
Hariharan Srikanth ◽  
D. A. Arena ◽  
Zohreh Nemati ◽  
...  
2021 ◽  
Vol 11 (1) ◽  
Author(s):  
F. G. Silva ◽  
J. Depeyrot ◽  
Yu. L. Raikher ◽  
V. I. Stepanov ◽  
I. S. Poperechny ◽  
...  

AbstractExchange bias properties of MnFe$$_2$$ 2 O$$_4$$ 4 @$$\gamma$$ γ –Fe$$_2$$ 2 O$$_3$$ 3 core–shell nanoparticles are investigated. The measured field and temperature dependencies of the magnetization point out a well-ordered ferrimagnetic core surrounded by a layer with spin glass-like arrangement. Quasi-static SQUID magnetization measurements are presented along with high-amplitude pulse ones and are cross-analyzed by comparison against ferromagnetic resonance experiments at 9 GHz. These measurements allow one to discern three types of magnetic anisotropies affecting the dynamics of the magnetic moment of the well-ordered ferrimagnetic NP’s core viz. the easy-axis (uniaxial) anisotropy, the unidirectional exchange-bias anisotropy and the rotatable anisotropy. The uniaxial anisotropy originates from the structural core–shell interface. The unidirectional exchange-bias anisotropy is associated with the spin-coupling at the ferrimagnetic/spin glass-like interface; it is observable only at low temperatures after a field-cooling process. The rotatable anisotropy is caused by partially-pinned spins at the core/shell interface; it manifests itself as an intrinsic field always parallel to the external applied magnetic field. The whole set of experimental results is interpreted in the framework of superparamagnetic theory, i.e., essentially taking into account the effect of thermal fluctuations on the magnetic moment of the particle core. In particular, it is found that the rotatable anisotropy of our system is of a uniaxial type.


2019 ◽  
Vol 9 (1) ◽  
Author(s):  
Chin-Wei Lin ◽  
Jian-Ming Chen ◽  
You-Jun Lin ◽  
Ling-Wei Chao ◽  
Sin-Yi Wei ◽  
...  

Abstract Recently, gold-coated magnetic nanoparticles have drawn the interest of researchers due to their unique magneto-plasmonic characteristics. Previous research has found that the magneto-optical Faraday effect of gold-coated magnetic nanoparticles can be effectively enhanced because of the surface plasmon resonance of the gold shell. Furthermore, gold-coated magnetic nanoparticles are ideal for biomedical applications because of their high stability and biocompatibility. In this work, we synthesized Fe3O4@Au core-shell nanoparticles and coated streptavidin (STA) on the surface. Streptavidin is a protein which can selectively bind to biotin with a strong affinity. STA is widely used in biotechnology research including enzyme-linked immunosorbent assay (ELISA), time-resolved immunofluorescence (TRFIA), biosensors, and targeted pharmaceuticals. The Faraday magneto-optical characteristics of the biofunctionalized Fe3O4@Au nanoparticles were measured and studied. We showed that the streptavidin-coated Fe3O4@Au nanoparticles still possessed the enhanced magneto-optical Faraday effect. As a result, the possibility of using biofunctionalized Fe3O4@Au nanoparticles for magneto-optical biomedical assays should be explored.


2014 ◽  
Vol 50 (11) ◽  
pp. 1-4 ◽  
Author(s):  
Galina V. Kurlyandskaya ◽  
Inaki Madinabeitia ◽  
A. M. Murzakaev ◽  
M. Belen Sanchez-Ilarduya ◽  
V. Beketov ◽  
...  

Nanoscale ◽  
2013 ◽  
Vol 5 (17) ◽  
pp. 7906 ◽  
Author(s):  
Qin-qin Xiong ◽  
Jiang-ping Tu ◽  
Xin-hui Xia ◽  
Xu-yang Zhao ◽  
Chang-dong Gu ◽  
...  

2003 ◽  
Vol 36 (4) ◽  
pp. 1069-1074 ◽  
Author(s):  
D. Eberbeck ◽  
A. Lange ◽  
M. Hentschel

Different very dilute suspensions of magnetic nanoparticles (magnetite surrounded by an organic shell) in water (ferrofluids) were investigated using small-angle X-ray scattering. It is shown that the scattering originates not only from noncorrelated core–shell nanoparticles, but also from larger structures. By modelling, these structures can be identified as close-packed clusters consisting of core–shell particles (core diameter ∼10 nm). The analysis of the radial distance distribution function, obtained by Fourier transformation of the scattered intensity, reveals a lower bound of the mean cluster size of about 40 nm. The formation of clusters is persistent, even in very dilute suspensions.


Author(s):  
Abdullah Guvendi

We investigate the dynamics of a composite system ([Formula: see text]) consisting of an interacting fermion–antifermion pair in the three-dimensional space–time background generated by a static point source. By considering the interaction between the particles as Dirac oscillator coupling, we analyze the effects of space–time topology on the energy of such a [Formula: see text]. To achieve this, we solve the corresponding form of a two-body Dirac equation (fully-covariant) by assuming the center-of-mass of the particles is at rest and locates at the origin of the spatial geometry. Under this assumption, we arrive at a nonperturbative energy spectrum for the system in question. This spectrum includes spin coupling and depends on the angular deficit parameter [Formula: see text] of the geometric background. This provides a suitable basis to determine the effects of the geometric background on the energy of the [Formula: see text] under consideration. Our results show that such a [Formula: see text] behaves like a single quantum oscillator. Then, we analyze the alterations in the energy levels and discuss the limits of the obtained results. We show that the effects of the geometric background on each energy level are not same and there can be degeneracy in the energy levels for small values of the [Formula: see text].


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