Synthesis and characterisation of fluorine-silicon acrylate latex emulsified by novel green surfactants

2018 ◽  
Vol 47 (3) ◽  
pp. 255-260 ◽  
Author(s):  
Lijun Chen ◽  
Xin Zhang ◽  
Cuifeng Zhang ◽  
Zhongbin Bao ◽  
Tingting Xu
Keyword(s):  
Water Resistance ◽  
Mixed Surfactants ◽  
Mass Ratio ◽  
Acrylic Copolymer ◽  
Content Type ◽  
Acrylate Copolymer ◽  
Emulsion Polymerisation ◽  
Alkyl Polyglycoside ◽  
Acrylate Latex ◽  
Practical Implications

Purpose Motivated by the globally increasing concern over environmental protection, the interest of a large part of the scientific community focuses on the development of green surfactants aiming to replace traditional toxic surfactants-based alternatives. The purpose of this paper is to prepare acrylate copolymer latex modified with fluorine and silicone monomer, which is emulsified with the green surfactants of sodium rosinate and alkyl polyglycoside (APG). Design/methodology/approach A series of acrylic copolymer latexes containing fluorine–silicon have been prepared by semi-continuous seed emulsion polymerisation of mixed monomers of methyl methacrylate (MMA), butyl acrylate (BA), hexafluorobutylmethacrylate (HFMA) and vinyltriethoxysilane (VTES) and emulsified by green mixed surfactants of sodium rosinate and APG. Findings The optimum recipe of preparing the emulsion is as follows: the amount of emulsifiers is 6 per cent and the mass ratio of sodium rosinate to APG is 1:3. The amount of initiator is 0.4 per cent, and the amounts of the silicon monomer and fluorine monomer are 5 and 7 per cent, respectively. In comparison with the acrylate latex prepared without fluorine monomer and silicon monomer, the thermal stability and the water resistance of the film of the resultant latex clearly improved. Practical implications The acrylic copolymer latexes containing fluorine–silicon emulsified with green surfactants can be used in the coatings, adhesives, finishing agents and so on. Originality/value The acrylic copolymer latexes containing fluorine–silicon have been prepared by semi-continuous seed emulsion polymerisation. The green mixed surfactants of sodium rosinate and APG have been used as the emulsifiers to replace traditional toxic surfactants-based alternatives.

Preparation and characterisation of modified VAc-VeoVa10 latex

2019 ◽  
Vol 48 (3) ◽  
pp. 210-215 ◽  
Author(s):  
Yilu Gong ◽  
Tantan Shao ◽  
Xiuming Wang ◽  
Xin Zhang ◽  
Zhijuan Sun ◽  
...  
Keyword(s):  
Vinyl Ester ◽  
Water Repellency ◽  
Latex Film ◽  
Mixed Surfactants ◽  
The Novel ◽  
Mass Ratio ◽  
Optimum Conditions ◽  
Content Type ◽  
Emulsion Polymerisation ◽  
Silicon Materials

Purpose Fluorine and silicon materials have received the keen attention of many researchers because of their water repellency and low surface free energy. The purpose this study was to prepare vinyl acetate (VAc)-vinyl ester of neodecanoic acid (VeoVa 10) copolymer latex modified with fluorine and silicone monomer, which is emulsified with the novel surfactants of disodium laureth sulfosuccinate (MES) and octylphenol polyoxyethylene ether (OP-10). Design/methodology/approach A series of modified latices containing fluorine-silicon have been prepared by semi-continuous seeded emulsion polymerisation of mixed monomers of VAc, VeoVa10, hexafluorobutylmethacrylate (HFMA) and vinyltriethoxysilane (VTES) and emulsified by novel surfactants of MES and OP-10. Findings The optimum conditions for preparing the modified latex is as follows: the amount of the surfactant was 4.0 Wt.% and the mass ratio of the anionic and nonionic surfactant was 3:1; the dosage of initiator was 0.4 Wt.% and the mass ratio of the main monomer was 3:1; and the amounts of VTES and HFMA were 2.0 and 6.0 Wt.%, respectively. In comparison with the conventional latex, the hydrophobicity of latex film was improved further. Originality/value The modified p (VAC-VeoVa) latex is prepared via semi-continuous seeded emulsion polymerisation, which is emulsified with the novel mixed surfactants of MES and OP-10. There are two main innovations. One is that the novel p (VAC-VeoVa) latex containing fluorine-silicon is prepared successfully. The other is that the emulsifier is composed of the novel mixed surfactants of MES and OP-10.

Synthesis and properties of novel self-crosslinked cationic fluorinated acrylic latex prepared with novel emulsified system

2016 ◽  
Vol 45 (4) ◽  
pp. 259-264
Author(s):  
Wen Li ◽  
Zhongbin Bao ◽  
Lijun Chen ◽  
Dongshun Deng
Keyword(s):  
Particle Size ◽  
Gemini Surfactants ◽  
Average Particle Size ◽  
Water Soluble ◽  
Average Particle ◽  
Mixed Surfactants ◽  
The Novel ◽  
Content Type ◽  
Acrylic Latex ◽  
Emulsion Polymerisation

Purpose At present, the conventional method of preparing cationic fluorinated acrylic latex is to emulsify copolymerised monomers with cationic surfactants. However, there has been a wide concern about using Gemini surfactants to prepare cationic polymer latex to improve its properties. The purpose of this paper was to focus on the synthesis of novel self-crosslinked cationic fluorinated acrylic latex (SCFAL), during which the copolymerised monomers were initiated with a water soluble azo initiator and emulsified with mixed surfactants of Gemini emulsifier and alkyl polyglycoside (APG). Design/methodology/approach The novel SCFAL was prepared successfully by the semi-continuous seeded emulsion polymerisation of butyl acrylate, methyl methacrylate, hexafluorobutyl methacrylate (HFMA) and hydroxy propyl methacrylate (HPMA) in aqueous medium. Findings The conversion is the maximum and the coagulation percentage the minimum when the amounts of emulsifier and initiator are 8 and 0.6 per cent, respectively. The average particle size of the latex is significantly reduced with the increase of the amount of emulsifiers used. However, the average particle size of the latex is increased with the increase of the amount of HPMA. The particle size of the latex is of a unimodal distribution, which means that the particle size was reasonably uniform. Contact angle is increased with the increase of the amount of the HFMA. Practical implications The novel SCFAL can be widely used as significant components in the field of coatings, leather, textile, paper, adhesives and so on. Originality/value SCFAL, which was emulsified with novel mixed surfactants of Gemini surfactant and APG, has been prepared successfully. Influences of amount of initiator, emulsifier, HPMA and HFMA on emulsion polymerisation and/or properties of novel latex are investigated in detail.

Synthesis and characterization of alicyclic two-component waterborne polyurethane

2018 ◽  
Vol 47 (4) ◽  
pp. 315-322 ◽  
Author(s):  
Jizhi Zhang ◽  
Xiankai Jiang
Keyword(s):  
Thermal Stability ◽  
Water Resistance ◽  
Aqueous Dispersion ◽  
Waterborne Polyurethane ◽  
Molar Ratio ◽  
Mechanical And Thermal Properties ◽  
Content Type ◽  
Two Component ◽  
Practical Implications

Purpose The purpose of this paper is to synthesize and characterize a series of alicyclic two-component waterborne polyurethane (2K-WPU) which is composed of non-ionic polyisocyanate aqueous dispersion and hydroxyl aqueous dispersion. Design/methodology/approach The appearances of aqueous dispersions and 2K-WPU films were observed by photographs. The micromorphology of alicyclic polyisocyanate aqueous dispersion was examined by scanning electron microscopy (SEM). The molecule structures of WPU were studied by Fourier transform infrared (FTIR). The effect of NCO:OH molar ratio of two components and trimethylolpropane (TMP) content on the thermal stability, mechanical and water resistance properties of 2K-WPU films was studied. Findings It was found by SEM that alicyclic polyisocyanate particles in aqueous dispersion showed a kind of spherical particle appearance, in which hydrophobic polyisocyanate was encapsulated by hydrophilic ether linkages segment. FTIR showed that WPU was polymerized through mixture of polyisocyanate component and hydroxyl component and increasing NCO:OH molar ratio of two components from 1.1:1 to 1.5:1 had increased the content of urea, urethane and allophanate of 2K-WPU films. Increasing NCO:OH molar ratio had improved the mechanical and thermal properties of the 2K-WPU film, but the water resistance of the 2K-WPU film increased first and then weakened. Increasing TMP contents from 1 to 0.75 mol for 1:5 system had improved the mechanical, thermal and water resistance properties of the 2K-WPU film. Practical implications The investigation established a method to prepare alicyclic 2K-WPU which is composed of non-ionic polyisocyanate aqueous dispersion and hydroxyl aqueous dispersion. The prepared 2K-WPU film could be applied in the field of waterborne surface coating, e.g. textile, wood and synthetic leather surfaces (Hasan et al., 2017; Akindoyo et al., 2016). Originality/value The paper established a method to synthesize alicyclic two-component 2K-WPU. The effect of NCO:OH molar ratio and TMP content on the thermal stability, mechanical and water resistance properties of 2K-WPU films were studied.

Properties and characterization of acrylic latex prepared with novel emulsifiers

2018 ◽  
Vol 9 (3-4) ◽  
pp. 145-151 ◽  
Author(s):  
Lijun Chen ◽  
Tantan Shao ◽  
Xin Zhang ◽  
Xiuming Wang ◽  
Dawei Chen
Keyword(s):  
Mixed Surfactants ◽  
The Novel ◽  
Mass Ratio ◽  
Optimum Conditions ◽  
Seeded Emulsion Polymerization ◽  
Scanning Calorimetry ◽  
Acrylic Latex ◽  
Properties And Characterization ◽  
Alkyl Polyglycoside

The polyacrylate latex has been successfully prepared by semicontinuous seeded emulsion polymerization with methyl methacrylate (MMA), butyl acrylate (BA), and acrylic acid (AA), which were initiated with potassium persulfate and emulsified with the novel green mixed surfactants of alkyl polyglycoside (APG1214) and disodium laureth sulfosuccinate (MES). The particle size of the latex was measured by Zetatrac dynamic light scattering detector. The structure of the latex was tested by Fourier-transform infrared spectroscopy. The film of latex was tested by differential scanning calorimetry and thermogravimetric analysis. Factors, which had an influence on the properties of the latex, were studied in detail. The optimum conditions for preparing the polyacrylate latex were as follows: the amount of emulsifiers was 7.0%, the mass ratio of APG1214 to MES was 3:1, the amount of the initiator was 0.7%, the mass ratio of MMA to BA was 1:1, and the amount of AA was 2.0%. In this case, the conversion of the mixed monomers was high and the mechanical and ionic stability of the latex was good.

scholarly journals New water-based copolymer nanoparticles and their use as eco-friendly binders for industry of flexographic ink, part I

2020 ◽  
Vol 49 (3) ◽  
pp. 239-248
Author(s):  
H. Abd El-Wahab ◽  
G. El-Meligi ◽  
M.G. Hassaan ◽  
A. Kazlauciunas ◽  
Long Lin
Keyword(s):  
Water Resistance ◽  
Gel Permeation Chromatography ◽  
Adhesion Properties ◽  
Content Type ◽  
Low Viscosity ◽  
Base Paper ◽  
Transmission Electron ◽  
Emulsion Polymerisation ◽  
Water Based ◽  
Excellent Adhesion

Purpose The purpose of this paper is to prepare, characterise and evaluate nano-emulsions of copolymers of various compositions as eco-friendly binders for flexographic ink industry. Design/methodology/approach Various nano-emulsions of copolymers were prepared using styrene (St), butyl acrylate (BuAc), acrylic acid (AA) and acrylamide (AAm) monomers by means of a conventional seeded emulsion polymerisation technique, using K2S2O8 as the initiator. The characterisation of the prepared emulsions was performed using Fourier transform infrared (FT-IR), thermogravimetric analysis (TGA), gel permeation chromatography (GPC) and transmission electron microscopy (TEM). A selection of copolymers was formulated with pigments and additional ingredients, as water-based flexographic inks. The inks were characterised for their viscosity, pH, degree of dispersion, water resistance and colour density. Findings It was found that the low viscosity of the prepared copolymers may reduce the film thickness of the flexographic inks and may also increase the spreading of the ink on the surface. As a result, stable modified polyacrylate-based latex with improved physico-mechanical properties were obtained. The prepared latexes were showed improving and enhancing in water resistance; gloss values, and the print density that ranged from 2.06 to 2.51 and the maximum gloss values (39 and 48) were also obtained. Also, these binders provide excellent adhesion properties for both the pigment particles and the base paper. Practical implications This study focuses on the preparation of new water-based copolymer nanoparticles and their use as eco-friendly binders for flexographic ink industry. Social implications The ink formulations developed could find use in industrial-scale printing. Originality/value Eco-friendly environment ink formulations for printing on paper substrates are novel.

Moisture-curing polyurethane resins modified by multi-hydroxymethylated phenol

2014 ◽  
Vol 43 (2) ◽  
pp. 69-74 ◽  
Author(s):  
Xiaofeng Zhang ◽  
Shuangying Wei ◽  
Zhenhua Gao
Keyword(s):  
Thermogravimetric Analysis ◽  
Heat Resistance ◽  
Active Sites ◽  
Design Methodology ◽  
Water Resistance ◽  
Cross Linking ◽  
Primary Concern ◽  
Content Type ◽  
Practical Implications ◽  
Bond Durability

Purpose – The purpose of this paper is to investigate the effects of multi-hydroxymethylated phenol (MHMP) on the properties of moisture-curing polyurethane (PU) resin, especially on the heat resistance. Design/methodology/approach – The MHMPs with various active sites from 2.52 to 3.91 were synthesised and used as a modifier. The bond test (according to the JIS K6806-2003 standard) and thermogravimetric analysis (TGA) were used, respectively, to characterise the bond durability and heat resistance of MHMP-modified PU resin. Findings – The MHMP with various F/P mole ratios had great effects on the properties of resultant PU resins. The increase of active sites of MHMP can improve the water resistance of resin due to the more cross-linking densities, while the decrease of active sites of MHMP can improve heat resistance of resin because more stable benzene ring introduced into the PU backbone. Research limitations/implications – In cases where heat resistance of the PU resin is of primary concern, the use of MHMP with fewer active sites or a lower F/P ratio is recommended. In other cases where bond durability is focussed, the modifier MHMP shall be synthesised with higher F/P ratio. Practical implications – MHMP as a modifier can be used to improve the heat resistance of PU resin. Originality/value – The MHMPs with various hydroxymethyl groups were synthesised and used as modifier of moisture-curing PU resins to improve their heat resistance.

Preparation and characterisation of novel cross-linked poly (IBOMA-BA-DFMA) latex

2015 ◽  
Vol 44 (6) ◽  
pp. 333-338 ◽  
Author(s):  
Lijun Chen ◽  
Zhongbin Bao ◽  
Zhengrong Fu ◽  
Wen Li
Keyword(s):  
Thermal Stability ◽  
Water Resistance ◽  
Mechanical Stability ◽  
Sodium Dodecyl ◽  
Bornyl Acetate ◽  
The Novel ◽  
Content Type ◽  
Film Forming ◽  
Emulsion Polymerisation ◽  
Ion Stability

Purpose – The purpose of this research was to synthesize a novel cross-linked latex copolymerised by butyl acrylate (BA), isobornyl methacrylate (IBOMA), hydroxy propyl methacrylate (HPMA) and dodecafluoroheptyl methacrylate (DFMA). IBOMA is a very useful functional monomer. Its molecular structure not only contains bornyl acetate alkoxy but also includes a double bond, which can be copolymerised with other unsaturated monomers via free radical polymerization. The large nonpolar bicyclic alkyl in bornyl acetate alkoxy offers the polymer chain strong space steric protection, which endows the polymer with some special properties. Design/methodology/approach – The semi-continuous seeded emulsion polymerisation technology was adopted to copolymerise BA, IBOMA, HPMA and DFMA in the water phase, which was initiated with potassium persulfate (KPS) and emulsified with the mixed surfactants of sodium dodecyl sulphate (SDS) and OP-10. Findings – The particle size of the latex decreases with an increase in the amount of IBOMA. All the latexes have good mechanical stability and calcium ion stability. The latex has good film-forming property when the IBOMA amount is controlled moderately. The optimal IBOMA amount is 10.00 g. The thermal stability and water resistance of the film are improved. Practical implications – The latexes can be applied as a binder of coatings and adhesions. Originality/value – The effect of the amount of IBOMA and BA on the properties of the resultant latex and its film were investigated in detail. In comparison with the latexes copolymerised without IBOMA, the novel latex has better thermal stability and water resistance.

Consumer value creation through WhatsApp use

2019 ◽  
Vol 32 (4) ◽  
pp. 455-471
Author(s):  
Jorge Cruz-Cárdenas ◽  
Jorge Guadalupe-Lanas ◽  
Ekaterina Zabelina ◽  
Andrés Palacio-Fierro ◽  
Margarita Velín-Fárez ◽  
...  
Keyword(s):  
Latin American ◽  
Value Creation ◽  
Emotional Support ◽  
Design Methodology ◽  
Instant Messaging ◽  
Role Performance ◽  
Content Type ◽  
Consumer Value ◽  
Depth Interviews ◽  
Practical Implications

Purpose The purpose of this paper is to understand in-depth how consumers create value in their lives using WhatsApp, the leading mobile instant messaging (MIM) application. Design/methodology/approach The study adopts the perspective of customer-dominant logic (CDL) and uses a qualitative multimethod design involving 3 focus groups and 25 subsequent in-depth interviews. The research setting was Ecuador, a Latin American country. Findings Analysis and interpretation of the participants’ stories made it possible to identify and understand the creation of four types of value: maintaining and strengthening relationships; improving role performance; emotional support; and entertainment and fun. In addition, the present study proposes a conceptual model of consumer value creation as it applies to MIM. Practical implications Understanding the way consumers create value in their lives using MIM is important not only for organizations that offer MIM applications, but also for those companies that develop other applications for mobile phones or for those who wish to use MIM as an electronic word-of-mouth vehicle. Originality/value The current study is one of the first to address the topic of consumer behavior in the use of technologies from the perspective of CDL; this perspective enables an integrated qualitative vision of value creation in which the consumer is the protagonist.

scholarly journals Advantages and potential challenges of data management in e-maintenance

2019 ◽  
Vol 25 (3) ◽  
pp. 378-396 ◽  
Author(s):  
Arian Razmi-Farooji ◽  
Hanna Kropsu-Vehkaperä ◽  
Janne Härkönen ◽  
Harri Haapasalo
Keyword(s):  
Data Management ◽  
Design Methodology ◽  
Management Practices ◽  
Future Research ◽  
Conceptual Approach ◽  
Content Type ◽  
Different Types ◽  
Maintenance Systems ◽  
Industry Leader ◽  
Practical Implications

Purpose The purpose of this paper is twofold: first, to understand data management challenges in e-maintenance systems from a holistically viewpoint through summarizing the earlier scattered research in the field, and second, to present a conceptual approach for addressing these challenges in practice. Design/methodology/approach The study is realized as a combination of a literature review and by the means of analyzing the practices on an industry leader in manufacturing and maintenance services. Findings This research provides a general understanding over data management challenges in e-maintenance and summarizes their associated proposed solutions. In addition, this paper lists and exemplifies different types and sources of data which can be collected in e-maintenance, across different organizational levels. Analyzing the data management practices of an e-maintenance industry leader provides a conceptual approach to address identified challenges in practice. Research limitations/implications Since this paper is based on studying the practices of a single company, it might be limited to generalize the results. Future research topics can focus on each of mentioned data management challenges and also validate the applicability of presented model in other companies and industries. Practical implications Understanding the e-maintenance-related challenges helps maintenance managers and other involved stakeholders in e-maintenance systems to better solve the challenges. Originality/value The so-far literature on e-maintenance has been studied with narrow focus to data and data management in e-maintenance appears as one of the less studied topics in the literature. This research paper contributes to e-maintenance by highlighting the deficiencies of the discussion surrounding the perspectives of data management in e-maintenance by studying all common data management challenges and listing different types of data which need to be acquired in e-maintenance systems.

Welcome to the marriage of human capability and artificial intelligence

2019 ◽  
Vol 19 (1) ◽  
pp. 10-14
Author(s):  
Ryan Scott ◽  
Malcolm Le Lievre
Keyword(s):  
Artificial Intelligence ◽  
Team Building ◽  
Workplace Change ◽  
Content Type ◽  
The Future ◽  
Human Capability ◽  
Mind Set ◽  
Future Work ◽  
Crucial Part ◽  
Practical Implications

Purpose The purpose of this paper is to explore insights methodology and technology by using behavioral to create a mind-set change in the way people work, especially in the age of artificial intelligence (AI). Design/methodology/approach The approach is to examine how AI is driving workplace change, introduce the idea that most organizations have untapped analytics, add the idea of what we know future work will look like and look at how greater, data-driven human behavioral insights will help prepare future human-to-human work and inform people’s work with and alongside AI. Findings Human (behavioral) intelligence will be an increasingly crucial part of behaviorally smart organizations, from hiring to placement to adaptation to team building, compliance and more. These human capability insights will, among other things, better prepare people and organizations for changing work roles, including working with and alongside AI and similar tech innovation. Research limitations/implications No doubt researchers across the private, public and nonprofit sectors will want to further study the nexus of human capability, behavioral insights technology and AI, but it is clear that such work is already underway and can prove even more valuable if adopted on a broader, deeper level. Practical implications Much “people data” inside organizations is currently not being harvested. Validated, scalable processes exist to mine that data and leverage it to help organizations of all types and sizes be ready for the future, particularly in regard to the marriage of human capability and AI. Social implications In terms of human capability and AI, individuals, teams, organizations, customers and other stakeholders will all benefit. The investment of time and other resources is minimal, but must include C-suite buy in. Originality/value Much exists on the softer aspects of the marriage of human capability and AI and other workplace advancements. What has been lacking – until now – is a 1) practical, 2) validated and 3) scalable behavioral insights tech form that quantifiably informs how people and AI will work in the future, especially side by side.

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