Impact of outliers on determining relationships between variables in large-scale industrial processes using Transfer Entropy

2020 ◽  
Author(s):  
Michal Falkowski ◽  
Pawel D. Domanski
Keyword(s):  
Large Scale ◽  
Transfer Entropy ◽  
Industrial Processes

scholarly journals Application properties of methods for fault detection and isolation in the diagnosis of complex large-scale processes

2014 ◽  
Vol 62 (3) ◽  
pp. 571-582 ◽  
Author(s):  
J.M. Kościelny ◽  
M. Syfert
Keyword(s):  
Fault Detection ◽  
Large Scale ◽  
Fault Detection And Isolation ◽  
Industrial Processes ◽  
Industrial Practice ◽  
Potential Applicability ◽  
Diagnostic Approaches ◽  
Level Of Knowledge ◽  
High Level ◽  
Selection Of

Abstract The survey presents a selection of the methods of the fault detection and isolation suitable to be useful for the diagnostics of the complex, large scale industrial processes. The paper focuses on these methods that have appropriately high level of potential applicability in industrial practice. The novelty of the paper relies on the discussion of the dependency of the level of knowledge about diagnosed process and recommended diagnostic approaches. Appropriate recommendations were given in the convenient form of the table

Photocatalytic decarboxylative alkylations mediated by triphenylphosphine and sodium iodide

Science ◽  
2019 ◽  
Vol 363 (6434) ◽  
pp. 1429-1434 ◽  
Author(s):  
Ming-Chen Fu ◽  
Rui Shang ◽  
Bin Zhao ◽  
Bing Wang ◽  
Yao Fu
Keyword(s):  
Large Scale ◽  
Sodium Iodide ◽  
Organic Dyes ◽  
Industrial Processes ◽  
Enol Ethers ◽  
Light Emitting ◽  
Silyl Enol Ethers ◽  
Redox Active ◽  
Decarboxylative Coupling ◽  
The Cost

Most photoredox catalysts in current use are precious metal complexes or synthetically elaborate organic dyes, the cost of which can impede their application for large-scale industrial processes. We found that a combination of triphenylphosphine and sodium iodide under 456-nanometer irradiation by blue light–emitting diodes can catalyze the alkylation of silyl enol ethers by decarboxylative coupling with redox-active esters in the absence of transition metals. Deaminative alkylation using Katritzky’s N-alkylpyridinium salts and trifluoromethylation using Togni’s reagent are also demonstrated. Moreover, the phosphine/iodide-based photoredox system catalyzes Minisci-type alkylation of N-heterocycles and can operate in tandem with chiral phosphoric acids to achieve high enantioselectivity in this reaction.

Use of Ash from the Incineration of Elephant Grass (Pennisetum purpureums shaum) into Clayey Ceramic

2012 ◽  
Vol 727-728 ◽  
pp. 993-998 ◽  
Author(s):  
A.M.F.D. Silva ◽  
L.S. Lovise ◽  
Sérgio Neves Monteiro ◽  
Carlos Maurício Fontes Vieira
Keyword(s):  
Mechanical Properties ◽  
Flexural Strength ◽  
Large Scale ◽  
Chemical Characterization ◽  
Physical And Mechanical Properties ◽  
Linear Shrinkage ◽  
The Other ◽  
Industrial Processes ◽  
Elephant Grass ◽  
Calcium Compounds

Ashes generated in industrial processes are usually discarded and contribute to environmental pollution. Large scale incorporation into clayey ceramic products for civil construction, such as bricks and tiles, could be a permanent solution. Based on this rationale, this works has as its objective to characterize an ash waste from the incineration of elephant grass and to evaluate its incorporation into a clay to produce red ceramic. The waste was submitted to mineralogical and chemical characterization. Compositions were prepared with incorporation of the waste in amounts of up to 20 wt.% into the clay. Specimens were prepared by extrusion and fired in a laboratory furnace at 850°C. The physical and mechanical properties evaluated were: linear shrinkage, water absorption and flexural strength. The results showed that the waste is mainly composed of quartz and calcium compounds that sensibly reduce the linear shrinkage and does not change the other properties of the ceramic.

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