A multi-objective optimization model for multiple home users intelligent power management and control is proposed. A photovoltaic power model, an electric vehicle battery model and a load model are developed first, and then a strategy of home intelligent power management is presented based on battery operation and PV spontaneous self-use. Secondly, a multi-objective optimization model of multiple home users intelligent power management, including the user comfort, economy and optimization of load curve, is provided under the constraints. Then using a multi-objective optimization algorithm and Nash equilibrium game theory to solve the multi-objective problem. Finally, the 100-home power management and control simulation case show that the presented algorithm can improve the comfort and the economy of users effectively, but also help the power grid to peak load shifting.