Verification for Electrical Tomography in Flame Monitoring by Ion Probe

Author(s):  
Die Hu ◽  
Lijun Xu ◽  
Zhang Cao ◽  
Shijie Sun ◽  
Jiangtao Sun
2018 ◽  
Vol 18 (21) ◽  
pp. 8847-8854 ◽  
Author(s):  
Die Hu ◽  
Zhang Cao ◽  
Shijie Sun ◽  
jiangtao sun ◽  
Lijun Xu

Author(s):  
J.K. Lampert ◽  
G.S. Koermer ◽  
J.M. Macaoy ◽  
J.M. Chabala ◽  
R. Levi-Setti

We have used high spatial resolution imaging secondary ion mass spectrometry (SIMS) to differentiate mineralogical phases and to investigate chemical segregations in fluidized catalytic cracking (FCC) catalyst particles. The oil industry relies on heterogeneous catalysis using these catalysts to convert heavy hydrocarbon fractions into high quality gasoline and fuel oil components. Catalyst performance is strongly influenced by catalyst microstructure and composition, with different chemical reactions occurring at specific types of sites within the particle. The zeolitic portions of the particle, where the majority of the oil conversion occurs, can be clearly distinguished from the surrounding silica-alumina matrix in analytical SIMS images.The University of Chicago scanning ion microprobe (SIM) employed in this study has been described previously. For these analyses, the instrument was operated with a 40 keV, 10 pA Ga+ primary ion probe focused to a 30 nm FWHM spot. Elemental SIMS maps were obtained from 10×10 μm2 areas in times not exceeding 524s.


2019 ◽  
Author(s):  
Yujie Tu ◽  
Junkai Liu ◽  
Haoke Zhang ◽  
Qian Peng ◽  
Jacky W. Y. Lam ◽  
...  

Aggregation-induced emission (AIE) is an unusual photophysical phenomenon and provides an effective and advantageous strategy for the design of highly emissive materials in versatile applications such as sensing, imaging, and theragnosis. "Restriction of intramolecular motion" is the well-recognized working mechanism of AIE and have guided the molecular design of most AIE materials. However, it sometimes fails to be workable to some heteroatom-containing systems. Herein, in this work, we take more than one excited state into account and specify a mechanism –"restriction of access to dark state (RADS)" – to explain the AIE effect of heteroatom-containing molecules. An anthracene-based zinc ion probe named APA is chosen as the model compound, whose weak fluorescence in solution is ascribed to the easy access from the bright (π,π*) state to the closelying dark (n,π*) state caused by the strong vibronic coupling of the two excited states. By either metal complexation or aggregation, the dark state is less accessible due to the restriction of the molecular motion leading to the dark state and elevation of the dark state energy, thus the emission of the bright state is restored. RADS is found to be powerful in elucidating the photophysics of AIE materials with excited states which favor non-radiative decay, including overlap-forbidden states such as (n,π*) and CT states, spin-forbidden triplet states, which commonly exist in heteroatom-containing molecules.


2018 ◽  
Vol 5 (1) ◽  
pp. 33
Author(s):  
C.MANE MAMTA ◽  
J.S. KULKARNI ◽  
◽  

2020 ◽  
Vol 211 ◽  
pp. 112-123
Author(s):  
Tomoaki Yatsufusa ◽  
Keigo Kii ◽  
Naoya Miura ◽  
Hiroki Yamamoto ◽  
Akira Kawasaki ◽  
...  
Keyword(s):  

Sensors ◽  
2021 ◽  
Vol 21 (3) ◽  
pp. 697
Author(s):  
Hanqing Xu ◽  
Weijun Fan ◽  
Jianwei Feng ◽  
Peiliang Yan ◽  
Shuchan Qi ◽  
...  

Flame monitoring of industrial combustors with high-reliability sensors is essential to operation security and performance. An ion current flame sensor with a simple structure has great potential to be widely used, but a weak ion current is the critical defect to its reliability. In this study, parameters of the ion current sensor used for monitoring flames on a Bunsen burner are suggested, and a method of further improving the ion current is proposed. Effects of the parameters, including the excitation voltage, electrode area, and electrode radial and vertical positions on the ion current, were investigated. The ion current grew linearly with the excitation voltage. Given that the electrodes were in contact with the flame fronts, the ion current increased with the contact area of the cathode but independent of the contact area of the anode. The smaller electrode radial position resulted in a higher ion current. The ion current was insensitive to the anode vertical position but largely sensitive to the cathode vertical position. Based on the above ion current regularities, the sensor parameters were suggested as follows: The burner served as a cathode and the platinum wire acted as an anode. The excitation voltage, anode radial and vertical positions were 120 V, 0 mm, and 6 mm, respectively. The method of further improving the ion current by adding multiple sheet cathodes near the burner exit was proposed and verified. The results show that the ion current sensor with the suggested parameters could correctly identify the flame state, including the ignition, combustion, and extinction, and the proposed method could significantly improve the magnitude of the ion current.


2020 ◽  
Vol 12 (1) ◽  
pp. 1094-1104
Author(s):  
Nima Dastanboo ◽  
Xiao-Qing Li ◽  
Hamed Gharibdoost

AbstractIn deep tunnels with hydro-geological conditions, it is paramount to investigate the geological structure of the region before excavating a tunnel; otherwise, unanticipated accidents may cause serious damage and delay the project. The purpose of this study is to investigate the geological properties ahead of a tunnel face using electrical resistivity tomography (ERT) and tunnel seismic prediction (TSP) methods. During construction of the Nosoud Tunnel located in western Iran, ERT and TSP 303 methods were employed to predict geological conditions ahead of the tunnel face. In this article, the results of applying these methods are discussed. In this case, we have compared the results of the ERT method with those of the TSP 303 method. This work utilizes seismic methods and electrical tomography as two geophysical techniques are able to detect rock properties ahead of a tunnel face. This study shows that although the results of these two methods are in good agreement with each other, the results of TSP 303 are more accurate and higher quality. Also, we believe that using another geophysical method, in addition to TSP 303, could be helpful in making decisions in support of excavation, especially in complicated geological conditions.


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