Optimized piezoelectric properties and temperature stability in PSN‐PMN‐PT by adjusting the phase structure and grain size

Author(s):  
Feifei Guo ◽  
Chao Yang ◽  
Hongqiao Zhou ◽  
Shasha Dong ◽  
Pinyang Fang ◽  
...  
Author(s):  
Zhenyong Cen ◽  
Shuaishuai Bian ◽  
Ze Xu ◽  
Ke Wang ◽  
Limin Guo ◽  
...  

AbstractIt is a very difficult work to sinter K0.5Na0.5NbO3 (KNN)-based materials with good reduction resistance in strong reducing atmosphere. 0.945K0.48Na0.52Nb0.96Ta0.04O3−0.055BaZrO3 + 0.03ZrO2 + y mol%MnO (KNNT−0.055BZ + 0.03Zr + yMn) ceramics sintered in reducing atmosphere were prepared successfully by conventional solid-state reaction methods. MnO dopant increases grain size at y = 5–8 due to strong lattice distortion and then decreases grain size at y = 9 due to much Mn4Nb2O9 accumulated at the grain boundary. MnO dopant as an excellent sintering aid can effectively reduce volatilization of alkali metal by decreasing the sintering temperature (Tsinter). Reducing alkali metal volatilization can greatly reduce oxygen vacancies and improve piezoelectric properties. MnO dopant can improve the anti-reduction properties. The KNNT−0.055BZ + 0.03Zr + yMn ceramics at y = 6–9 show outstanding anti-fatigue of unipolar piezoelectric strain under the synergistic effect of reduced oxygen vacancies due to reduced volatilization and increased grain size. Piezoelectric properties and temperature stability of KNNT−0.055BZ + 0.03Zr ceramics sintered in reducing atmosphere are improved simultaneously by MnO dopant. Optimum inverse piezoelectric coefficient (d 33 * ) of ceramics at y = 8 reaches up to 480 pm/V under low driving electric field E = 20 kV/cm at room temperature, and its temperature stability of d 33 * reaches 158 °C. It will be an excellent lead-free material candidate for the preparation of multilayer piezoelectric actuators co-fired with nickel electrode.


2020 ◽  
Vol 13 (05) ◽  
pp. 2051023 ◽  
Author(s):  
Quanlin Wang ◽  
Jinfeng Lin ◽  
Yang Zhou ◽  
Cong Lin ◽  
Tengfei Lin ◽  
...  

The lead-free multifunctional ceramics Sm3+-doped (Ba0.85Ca0.15)(Ti0.9Zr0.1)O3 were synthesized via conventional sintering. The influences of Sm3+ concentration on phase structure, grain size, Curie temperature, ferro-/piezoelectric properties, as well as photoluminescence (PL) performances of the ceramics have been investigated. The results show that with the Sm3+ concentration of 0.4[Formula: see text]mol%, the integrated optoelectronic performances are best. In order to further study the relationship between ferroelectric and PL features, the poling effect on PL intensities of the ceramics has been focused on, giving the highest enhancement factors of 52.6% induced by both lattice distortion and phase transformation. The electric poling is an effective route to enhance the PL performance of luminescent ferroelectrics.


2009 ◽  
Vol 475 (1-2) ◽  
pp. 619-623 ◽  
Author(s):  
Gao Feng ◽  
Hong Rongzi ◽  
Liu Jiaji ◽  
Li Zhen ◽  
Cheng Lihong ◽  
...  

2017 ◽  
Vol 100 (9) ◽  
pp. 3920-3927 ◽  
Author(s):  
Yi Chen ◽  
Dandan Xue ◽  
Meng Shi ◽  
Xianquan Jiang ◽  
Zhiqian Chen ◽  
...  

2019 ◽  
Vol 39 (4) ◽  
pp. 957-962 ◽  
Author(s):  
Xinchun Xie ◽  
Tianzi Wang ◽  
Zhiyong Zhou ◽  
Guofeng Cheng ◽  
Ruihong Liang ◽  
...  

2011 ◽  
Vol 492 ◽  
pp. 194-197 ◽  
Author(s):  
Yue Fang Wang ◽  
Xiu Jie Yi ◽  
Wei Pan ◽  
Guo Zhong Zang ◽  
Juan Du

Lead-free (1-x-y)Na1/2Bi1/2TiO3-xBaTiO3-yBiFeO3 ceramics were synthesized by ordinary sintering technique. The compositional dependence of phase structure and electrical properties of the ceramics was systematically investigated. All samples possessed pure perovskite structure. The dielectric and piezoelectric properties of ceramics were investigated with the amount of different BiFeO3 substitutions. The addition of BiFeO3 can not only decrease Ec and Pr but also lead to a significant degradation of the dielectric loss tanδ.


2004 ◽  
Vol 43 (9B) ◽  
pp. 6525-6529 ◽  
Author(s):  
Kiyotaka Tanaka ◽  
Kazuyuki Suzuki ◽  
Desheng Fu ◽  
Kaori Nishizawa ◽  
Takeshi Miki ◽  
...  

2007 ◽  
Vol 280-283 ◽  
pp. 223-226 ◽  
Author(s):  
Jin Song Pan ◽  
Xiao Wen Zhang ◽  
Ke Pi Chen ◽  
Chao Lei

(1-x)(0.64PNN-0.36PT)-x(0.91PZN-0.09PT) ferroelectric ceramics with different x were synthesized by the columbite precursor method. The phase structure and piezoelectric properties were investigated. XRD profiles implied that with the increasing of x, samples could no longer maintain the pure perovskite phase. All the compositions were found to lie within the region of the morphotropic phase boundaries (MPBs) with different contents of rhombohedral and tetragonal phases. The piezoelectric coefficients for compositions with x £ 0.30 were obviously better than those for the rest ones and the composition with x = 0.15 exhibited the largest value of d33 among all the samples. The relationship between the structure and the piezoelectric properties was discussed.


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