Evaluation of Hydrogen Induced Cracking Resistance of X70 Pipeline Steel Under Severe and Mild Sour Service Conditions Using Ultrasonic Analysis

2021 ◽  
Author(s):  
Steffen Gawor ◽  
J. Barry Wiskel ◽  
Doug G. Ivey ◽  
Jing Liu ◽  
Hani Henein
Author(s):  
S. Gawor ◽  
J. B. Wiskel ◽  
D. G. Ivey ◽  
J. Liu ◽  
H. Henein

Abstract A standard NACE hydrogen induced crack test was used to evaluate the resistance of two compositions of X70 steel (X70-X (Ca/S ratio of 2.5) and X70-B (Ca/S ratio of < 0.5)) under severe (pH = 2.7 and 100% H2S) and mild (pH = 5.5 and 100% H2S) sour service conditions. An ultrasonic technique was developed to quantify the severity of hydrogen cracking in both steels as a function of test conditions, steel type and time. In this procedure, a series of local ultrasonic measurements was taken for each test sample to determine a local crack to backwall signal ratio (LCBR). The LCBR values were integrated over the entire sample to give a global crack to backwall ratio (GCBR). A larger GCBR value corresponds to greater hydrogen cracking severity in the sample. Energy dispersive X-ray (EDX) spectroscopy and glancing angle X-ray diffraction (XRD) were used to characterize the surface corrosion products that formed during testing. For severe sour service conditions, the GCBR value reached an asymptotic value of approximately 33% and 47% for X70-X (after 4 days) and X70-B (after 2 days) steels, respectively. For mild sour service conditions, no cracking was observed for testing of less than 16 days. After 32 days, X70-B showed a GCBR of approximately 18%. The onset of cracking of X70-X steel occurred between 32 and 64 days. Samples tested for 64 days showed a GCBR of 30% and 16% for X70-X and X70-B, respectively. Glancing XRD measurements showed the presence of surface FeS on both steels tested under mild sour service. Quantitative XRD (QXRD) analysis was used to obtain the surface coverage of FeS as a function of test time. EDX mapping confirmed the presence of a high sulfur content over a significant fraction of the surface. XRD measurements of X70-B steel under severe sour service after 8 days did not show a significant amount of FeS. The surface FeS is believed to alter hydrogen ingress into the steel, making it difficult to directly compare measured GCBR values obtained under mild and severe sour service.


Author(s):  
Douglas G. Stalheim ◽  
Bernhard Hoh

Worldwide oil and natural gas reserves can be classified as either sweet or sour service. The sour service classified oil and natural gas reserves contain some level of H2S making the product flowing through a steel pipeline corrosive. Due to this, the majority of the oil and natural gas reserves that have been drilled are of the sweet service nature. However as demand continues and supplies change, many of the remaining oil and natural gas reserves contain the H2S component and are of a sour service nature. These oil and natural gas reserves containing the H2S component through a corrosion mechanism will allow for diatomic hydrogen — in the presence of moisture — to disseminate to monatomic hydrogen and diffuse into the pipeline steel microstructure. Depending on the microstructure and level of cleanliness the monatomic hydrogen can become trapped at areas of high residual stress, recollect to diatomic hydrogen and creating partial pressures that exceed the tensile strength of the steel resulting in cracking. Therefore transmission pipelines are being built to transport sour service oil or natural gas requires steels with hydrogen induced cracking (HIC) resistance. Alloy designs, steel making processing, continuous casting, plate or strip rolling, pipe forming, and last not least corrosion testing are all key components in producing pipeline steels that are resistant to HIC applications and meeting the NACE TM0284 specifications. However, producing steels that have good HIC performance do not necessarily meet other mechanical property requirements such as strength and YT ratios. Balance has to be achieved to meet not only the HIC requirements but the other required mechanical properties. Mastering this complex HIC process poses a serious challenge to pipe producers and their primary material suppliers. The capability of producing HIC steel grades according to critical specifications and/or standards clearly distinguishes excellent steel producers from good steel makers. This paper will discuss the basics of the hydrogen induced cracking phenomenon, the requirements of the NACE TM0284 specification and give guidelines for steel production of API pipeline steels that not only can meet the specification requirements the NACE testing but also fulfill the other mechanical property requirements.


2015 ◽  
Vol 816 ◽  
pp. 755-760 ◽  
Author(s):  
Jing Li ◽  
Xiu Hua Gao ◽  
Yong Lu ◽  
Lin Xiu Du

Anti-H2S X70 pipeline steel was developed. The microstructure of X70 pipeline steel was studied by the analysis of OM, SEM and TEM. The precipitation behavior was discussed. The comprehensive mechanical properties, HIC and SCC performance were systematically studied. The results indicated that the microstructure of the experimental steel was mainly acicular ferrite and granular bainite. The second phase precipitates dispersedly distributed in the matrix. The experimental steel possessed excellent strength, plasticity, low temperature toughness and low yield ratio. And therefore, the X70 pipeline steel in the study is suitable for sour service with the high strength, excellent toughness and low HIC&SSC susceptibility.


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