Experimental Testing of a Novel Kilowatt-Scale Multistack Solid-Oxide Fuel Cell Assembly for Combined Heat and Power

Author(s):  
Gladys Anyenya ◽  
Buddy Haun ◽  
Mark Daubenspeck ◽  
Robert Braun ◽  
Neal P. Sullivan

This paper describes experimental testing of a “geothermic fuel cell (GFC),” a novel application of solid-oxide fuel cells for combined heat and power. The geothermic fuel cell (GFC) is designed for in situ oil-shale processing. When implemented, the GFC is placed underground within an oil-shale formation; the heat released by the fuel cells while generating electricity is transferred to the oil shale, converting it into high-quality crude oil and natural gas. The GFC module presented here is comprised of three 1.5-kWe solid-oxide fuel cell (SOFC) stack-and-combustor assemblies packaged within a stainless-steel housing for the ease of installation within a bore hole drilled within the earth. The results from above-ground, laboratory testing of the geothermic fuel cell module are presented, with a number of operating conditions explored. Operation is demonstrated under hydrogen and natural-gas reformate fuels. The combined heat-and-power efficiency ranges from 56.2% to 74.2% at operating conditions that generally favor heat generation over electricity production. Testing of the geothermic fuel cell module over a wide operating range in a controlled, laboratory setting provides a valuable data set for developing more-detailed electrochemical and heat transfer models of module operation.

Author(s):  
K. J. Bosch ◽  
N. Woudstra ◽  
K. V. van der Nat

In conventional gas turbine systems combustion results in high exergy losses (∼30%) of fuel exergy input. Replacing the combustor with a high temperature fuel cell, like the Solid Oxide Fuel Cell (SOFC), will significantly reduce these exergy losses. As the SOFC electrochemically converts the natural gas, exergy losses are far lower (∼10%) compared to combustion. Natural gas entering a SOFC system has to be reformed first to hydrogen and carbon monoxide by steam reforming. Here it is chosen to use the heat generated by the fuel cell to drive the endothermic reforming reactions: internal reforming. The SOFC-GT system has the advantage that both fuel cell and gas turbine technology contribute to power production. In earlier work [1] several fuel cell system configurations with PEMFC, MCFC or SOFC, were analyzed studying the exergy flows. Here is focused on the SOFC-GT configuration, to get a detailed understanding of the exergy flows and losses through all individual components. Several configurations, combining the SOFC with the GT are possible. The selected operating conditions should prevent carbon deposition. Systems studies are performed to get more insight in the exergy losses in these combined systems. Exergy analysis facilitates the search for the high efficient SOFC-GT hybrid systems. Using exergy analysis, several useful configurations are found. Exergy losses are minimized by varying pressure ratio and turbine inlet temperature. Sensitivity studies, of equivalent cell resistance and fuel cell temperature, show that total system exergy efficiencies of more than 80% are conceivable, without using a bottoming cycle.


2021 ◽  
Vol 103 (1) ◽  
pp. 31-39
Author(s):  
Kazuo Nakamura ◽  
Takahiro Ide ◽  
Yasuharu Kawabata ◽  
Tatsuya Nakajima ◽  
Tatsuki Dohkoh ◽  
...  

2020 ◽  
Vol 477 ◽  
pp. 229007
Author(s):  
Brent B. Skabelund ◽  
Hisashi Nakamura ◽  
Takuya Tezuka ◽  
Kaoru Maruta ◽  
Jeongmin Ahn ◽  
...  

2005 ◽  
Author(s):  
Comas L. Haynes ◽  
J. Chris Ford

During latter-stage, “start-up” heating of a solid oxide fuel cell (SOFC) stack to a desired operating temperature, heat may be generated in an accelerating manner during the establishment of electrochemical reactions. This is because a temperature rise in the stack causes an acceleration of electrochemical transport given the typical Arrhenius nature of the electrolyte conductivity. Considering a potentiostatic condition (i.e., prescribed cell potential), symbiosis thus occurs because greater current prevalently leads to greater by-product heat generation, and vice versa. This interplay of the increasing heat generation and electrochemistry is termed “light off”, and an initial model has been developed to characterize this important thermal cycling phenomenon. The results of the simulation begin elucidating the prospect of using cell potential as well as other electrochemical operating conditions (e.g., reactants utilization) as dynamic controls in managing light off transients and possibly mitigating thermal cycling issues.


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