THERMODYNAMIC ASSESSMENT OF MEMBRANE ASSISTED PREMIXED AND NON-PREMIXED OXY-FUEL COMBUSTION POWER CYCLES
Abstract This study focuses on the investigations of gas turbine power generation system that works on oxy-combustion technology utilizing membrane assisted oxygen separation. The two investigated systems are: (i) a premixed oxy-combustion power generation cycle utilizing an ion transport membrane (ITM) based air separation unit (ASU), and (ii) a non-premixed oxy-fuel combustion power cycle, where oxygen separation takes place, with co-generation of hydrogen in an integrated combustor. The two novel cycle designs were proposed and evaluated in comparison to the conventional cycle. The first law efficiency of the premixed combustion power cycle was calculated to be 45.9%, a loss of 2.4% as energy penalty for the oxygen separation. The non-premixed cycle had the lowest first law efficiency of 39.6%, which was 8.7% lower than the efficiency of the base cycle. The lower effectiveness of the cycle could be attributed to the highly endothermic H2O splitting reaction for the oxygen production. High irreversibility in the H2O splitter and the reactor was identified as the main cause for exergy losses. The overall second law efficiency of the non-premixed power cycle was around 50% lesser than the other cycles. The energy penalty related with air separation dominated as the parameter that reduces the efficiencies of the oxy-fuel combustion cycles, however, the premixed combustion cycle performance was found to be comparable to the conventional air combustion cycle.