Retrofitting CO2 Capture to Existing Power Plants as a Fast Track Mitigation Strategy

Author(s):  
Hannah Chalmers ◽  
Jon Gibbins ◽  
Mathieu Lucquiaud

Carbon capture and storage (CCS) is often identified as an important technology for mitigating global carbon dioxide (CO2) emissions. For example, the IEA currently suggests that 160GW of CCS may need to be installed globally by 2030 as part of action to limit greenhouse gas concentrations to 550ppm-CO2eq, with a further 190GW CCS capacity required if a 450ppm-CO2eq target is to be achieved. Since global rollout of proven CCS technologies is not expected to commence until 2020 at the earliest this represents a very challenging build rate. In these circumstances retrofitting CO2 capture to existing plants, probably particularly post-combustion capture on pulverized coal-fired plants, could play an important role in the deployment of CCS as a global strategy for implementing CO2 emissions reductions. Retrofitting obviously reduces the construction activity required for CCS deployment, since fewer additional new power plants are required. Retrofitting CCS to an existing fleet is also an effective way to significantly reduce CO2 emissions from this sector of the electricity generation mix; it is obviously not possible to effect an absolute reduction in coal power sector CO2 emissions simply by adding new plants with CCS to the existing fleet. Although it has been proposed that plants constructed now and in the future can be ‘capture ready’, much of the existing fleet will not have been designed to be suitable for retrofit of CO2 capture. Some particular challenges that may be faced by utilities and investors considering a retrofit project are discussed. Since it is expected that post-combustion capture retrofits to pulverized coal plants will be the most widely applied option for retrofit to the existing fleet (probably regardless of whether base plants were designed to be capture ready or not), a review of the technical and potential economic performance of this option is presented. Power cycle performance penalties when capture is retrofitted need to be addressed, but satisfactory options appear to exist. It also seems likely that the economic performance of post-combustion capture retrofit could be competitive when compared to other options requiring more significant capital expenditure. Further work is, however, required both to develop a generally accepted methodology for assessing retrofit economics (including consideration of the implications of lost output after retrofit under different electricity selling price assumptions) and to apply general technical principles to case studies where site-specific constraints are considered in detail. The overall conclusion from the screening-level analysis reported in this paper is that, depending on project-specific and market-specific conditions, retrofit could be an attractive option, especially for fast track initial demonstration and deployment of CCS. Any unnecessary regulatory or funding barriers to retrofit of existing plants and to their effective operation with CCS should, therefore, be avoided.

Author(s):  
John R. Fyffe ◽  
Stuart M. Cohen ◽  
Michael E. Webber

Coal-fired power plants are a source of inexpensive, reliable electricity for many countries. Unfortunately, their high carbon dioxide (CO2) emissions rates contribute significantly to global climate change. With the likelihood of future policies limiting CO2 emissions, CO2 capture and sequestration (CCS) could allow for the continued use of coal while low- and zero-emission generation sources are developed and implemented. This work compares the potential impact of flexibly operating CO2 capture systems on the economic viability of using CCS in gas- and coal-dominated electricity markets. The comparison is made using a previously developed modeling framework to analyze two different markets: 1) a natural-gas dominated market (the Electric Reliability Council of Texas, or ERCOT) and 2) a coal-dominated market (the National Electricity Market, or NEM in Australia). The model uses performance and economic parameters for each power plant to determine the annual generation, CO2 emissions, and operating profits for each plant for specified input fuel prices and CO2 emissions costs. Previous studies of ERCOT found that flexible CO2 capture operation could improve the economic viability of coal-fired power plants with CO2 capture when there are opportunities to reduce CO2 capture load and increase electrical output when electricity prices are high. The model was used to compare the implications of using CO2 capture systems in the two electricity systems under CO2 emissions penalties from 0–100 US dollars per metric ton of CO2. Half the coal-fired power plants in each grid were selected to be considered for a CO2 capture retrofit based on plant efficiency, whether or not SO2 scrubbers are already installed on the plant, and the plant’s proximity to viable sequestration sites. Plants considered for CO2 capture systems are compared with and without inflexible CO2 capture as well as with two different flexible operation strategies. With more coal-fired power plants being dispatched as the marginal generator and setting the electricity price in the NEM, electricity prices increase faster due to CO2 prices than in ERCOT where natural gas-plants typically set the electricity price. The model showed moderate CO2 emissions reductions in ERCOT with CO2 capture and no CO2 price because increased costs at coal-fired power plants led to reduced generation. Without CO2 prices, installing CO2 capture on coal-fired power plants resulted in moderately reduced CO2 emissions in ERCOT as the coal-fired power plants became more expensive and were replaced with less expensive natural gas-fired generators. Without changing the makeup of the plant fleet in NEM, a CO2 price would not currently promote significant replacement of coal-fired power plants because there is minimal excess capacity with low CO2 emissions rates that can displace existing coal-fired power plants. Additionally, retrofitting CO2 capture onto half of the coal-based fleet in NEM did not reduce CO2 emissions significantly without CO2 costs being implemented because the plants with capture become more expensive and were replaced by the coal-fired power plants without CO2 capture. Operating profits at NEM capture plants increased as CO2 price increased much faster than capture plants in ERCOT. The higher rate of increasing profits for plants in NEM is due to the marginal generators in NEM being coal-based facilities with higher CO2 emissions penalties than the natural gas-fired facilities that set electricity prices in ERCOT. Overall, coal-fired power plants were more profitable with CO2 capture systems than without in both ERCOT and NEM when CO2 prices were higher than USD25/ton.


Author(s):  
Abhishek P. Ratanpara ◽  
Alexander Shaw ◽  
Sanat Deshpande ◽  
Myeongsub Kim

Abstract As the consumption of fossil fuel resources has continuously increased to meet global fuel demands for power generation, atmospheric emissions of greenhouse gases, particularly carbon dioxide (CO2), have rapidly increased over the last century. Increased CO2 emissions have caused serious international concerns about global warming, sea-level rise, and ocean acidification. Although post-combustion carbon capture technology that separates CO2 from flue gas in fossil fuel-fired power plants has contributed to significant migration of atmospheric CO2 emissions, this approach generates considerable amounts of toxic wastewater containing a heavy chemical which is difficult to treat, raises concerns about acute corrosion of metal structures in the facility, and waste of significant amounts of freshwater. In this research, we are particularly interested in reducing the use of freshwater for CO2 capture and generating carbonate minerals, byproducts of CO2 with calcium (Ca2+) or magnesium ions (Mg2+) in ocean water which are useful building blocks for marine animals, such as seashells and coral reefs. In our experimental approach, we attempted to use ocean water with different monoethanolamine (MEA) concentrations and compared the CO2 capturing efficiency with that in DI water. We found that there are considerable benefits of the use of ocean water in CO2 dissolution, showing that a replacement of freshwater with ocean water would be a possible option. In the future, we will further enhance the dissolution of CO2 in ocean water by using nanoparticle catalysts without using MEA, which will be an environmentally friendly method for CO2 capture.


1993 ◽  
Author(s):  
C. Wilkes ◽  
R. A. Wenglarz ◽  
P. J. Hart ◽  
H. C. Mongia

This paper describes the application of Allison’s rich-quench-lean (RQL) coal combustor technology to large utility gas turbines in the 100 MWe+ class. The RQL coal combustor technology was first applied to coal derived fuels in the 1970s and has been under development since 1986 as part of a Department of Energy (DOE)-sponsored heat engine program aimed at proof of concept testing of coal-fired gas turbine technology. The 5 MWe proof of concept engine/coal combustion system was first tested on coal water slurry (CWS); it is now being prepared for testing on dry pulverized coal. A design concept to adapt the RQL coal combustor technology developed under the DOE program to large utility-sized gas turbines has been proposed for a Clean Coal V program. The engine and combustion system modifications required for application to coal-fueled combined cycle power plants using 100 MWe+ gas turbines are described. Estimates for emissions and cycle performance are given. Included are comparisons with a conventional pulverized coal plant that illustrates the advantages of incorporating a gas turbine on cycle efficiency and emission rate.


Author(s):  
Jesu´s M. Escosa ◽  
Cristo´bal Cortes ◽  
Luis M. Romeo

Fossil fuel power plants account for about a third of global carbon dioxide emissions. Coal is the major power-generation fuel, being used twice as extensively as natural gas (IEA, 2003). Moreover, on a global scale, coal demand is expected to double over the period to 2030; IEA estimates that 4500 GWe of new installed power will be required. Coal is expected to provide 40% of this figure. It is thus obvious that coal power plants must be operative to provide such amount of energy in the short term, at the same time reducing their CO2 emissions in a feasible manner and increasing their efficiency and capacity. However, the main technologies currently considered to effect CO2 capture, both post-and pre-combustion, introduce a great economic penalty and largely reduce the capacity and efficiency. One of these technologies involves the separation of CO2 from high temperature flue gases using the reversible carbonation reaction of CaO and the calcination of CaCO3. The process is able to simultaneously capture sulfur dioxide. The major disadvantage of this well-known concept is the great amount of energy consumption in the calcinator and auxiliary equipment. This paper proposes a new, feasible approach to supply this energy which leads to an optimal integration of the process within a conventional coal power plant. Calcination is accomplished in a kiln fired by natural gas, whereas a gas turbine is used to supply all the auxiliary power. Flue gases from the kiln and the gas turbine can substitute a significant part of the heat duty of the steam cycle heaters, thus accomplishing feed water repowering of the steam turbine. This novel CO2-capture cycle is proposed to be integrated with aging coal-fired power plants. The paper shows that an optimal integration of both elements represents one of the best methods to simultaneously achieve: a) an increase of specific generating capacity in a very short period of time, b) a significant abatement of CO2 emissions, and c) an increase of plant efficiency in a cost-effective way.


2014 ◽  
Vol 5 (3) ◽  
pp. 268-276 ◽  
Author(s):  
Fontina Petrakopoulou ◽  
Diego Iribarren ◽  
Javier Dufour

Author(s):  
Keiichi Ishida

Coal is a valuable primary energy source that has excellent supply stability and economic efficiency. Japan has extremely low energy self-sufficiency and coal-fired power generation is positioned as an important base load power supply. One urgent issue we face is to find realistic countermeasures that greatly reduce CO2 emissions from coal-fired power plants which produce a large volume of CO2 emissions. Therefore, we have launched the Osaki CoolGen Project since April 2012 as an “Integrated Coal Gasification Fuel Cell Combined Cycle (IGFC) Demonstration Project” subsidized by the Ministry of Economy, Trade and Industry (until 2015 FY) and New Energy and Industrial Technology Development Organization (from 2016 FY). This project aims to realize innovative low-carbon coal-fired power generation that combines an IGFC, an extremely efficient coal-fired power generation technology with high-performance CO2 capture technology for the purpose of dramatically reducing CO2 emissions from coal-fired power generation. This project consists of three steps. The first step will implement demonstration tests of the oxygen-blown Integrated coal Gasification Combined Cycle (IGCC) which is the base technology for IGFC. Toward the start of demonstration testing in March 2017, construction was started in March 2013 and commissioning was started in April 2016. In the second step, we plan to carry out demonstration tests of the oxygen-blown IGCC with CO2 capture equipment. In the third step, we plan to demonstrate an IGFC system combining the demonstration plant of the second step with a fuel cell.


2013 ◽  
Author(s):  
Liang Zeng ◽  
Fanxing Li ◽  
Ray Kim ◽  
Samuel Bayham ◽  
Omar McGiveron ◽  
...  

Author(s):  
Qin Chen ◽  
Ashok Rao ◽  
Scott Samuelsen

Existing coal fired power plants are expected to continue providing a significant portion of power generation and a majority of these are subcritical pulverized coal (PC) units which have higher CO2 emissions on a MWe basis due to their higher heat rates, while CO2 emissions are an increasing concern due to global pressure on limiting greenhouse gas accumulation in the atmosphere. Current state-of-the-art CO2 capture technology uses an aqueous amine solution to chemically absorb the CO2 from the flue gas and thus requires a large amount of energy for solvent regeneration. Novel solid sorbent based CO2 capture technologies are under development to capture the CO2 via physical adsorption and desorption, thereby consuming far less energy for the sorbent regeneration process. This present work is focused on retrofitting a subcritical PC power plant with solid sorbent post combustion CO2 capture technology. Thermal performance and costs are compared with an amine based CO2 capture plant as well as the plant with no CO2 capture. The design of the solid sorbent based CO2 capture system is optimized for integration to minimize plant modifications and the associated downtime. In an existing PC plant with a net power efficiency of 36.57%, use of the amine based capture reduces the net efficiency to 26.01% while with the solid sorbent based capture, the reduction in net efficiency is far less at 28.67% when 90% of the CO2 is captured. As a consequence, the increase in plant cooling duty is significantly lower for the solid sorbent CO2 capture case, with the water usage on a per MW basis being almost 17% lower than the amine based PC plant. The calculated levelized cost of electricity is increased from $60.5/MWh without CO2 capture to $124.3/MWh for amine based capture while that with the solid sorbent based capture is much lower at $115.8/MWh.


2009 ◽  
Vol 4 (2) ◽  
pp. 196-206 ◽  
Author(s):  
Y. Huang ◽  
S. Rezvani ◽  
D. McIlveen-Wright ◽  
N. Hewitt ◽  
A. Minchener ◽  
...  

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