Application of Valve-Less Impedance Pumps to a Direct Sodium Borohydride–Hydrogen Peroxide Fuel Cell

Author(s):  
C. Y. Wen ◽  
A. S. Yang ◽  
J. W. Tseng

In this study, two novel valve-less impedance pumps are applied, for the first time, in the liquid fuel supply of a Direct Sodium Borohydride–Hydrogen Peroxide Fuel Cell (DBHPFC). This valve-less pump prevents the pump corrosion and serves appropriately to reduce the volume and weight of fuel cell systems. It comprises an amber latex rubber tube, connected at both ends to rigid stainless steel tubes of different acoustic impedance, and a simple actuation mechanism which combines a small DC motor and a cam. The motor activated cam periodically compresses the elastic tube at a position asymmetric from the tube ends. Traveling waves, emitted from the compression, combine with reflected waves at the impedance-mismatched rubber tube/stainless tube interfaces. The resulting wave interference creates a pressure gradient and generates a net flow. A DBHPFC with the active area of 25 cm2 is constructed. It is shown that the maximum pumping rate can achieve 30 ml/min with the DBHPFC connected. The corresponding maximum power and current are 13.0 W and 25.5 A, respectively. Specific power, volumetric power density, and back work ratio of the DBHPFC using this pumping method are shown superior to those of the other pumping configuration with the peristaltic pumps.

Author(s):  
A. S. Yang ◽  
J. W. Tseng ◽  
C. Y. Wen ◽  
H. Zhang

Abstract A valveless impedance pump is designed and applied for the first time to supply the liquid fuels for a direct sodium borohydride–hydrogen peroxide fuel cell (DBHPFC). This valveless pump consists of an amber latex rubber tube, which is connected at both ends to rigid stainless-steel tubes of different acoustic impedance, and a simple actuation mechanism with a small direct control (DC) motor and a cam combined. The cam is activated by the motor and periodically compresses the elastic tube at a position asymmetrical from the tube ends. The traveling waves emitted from the compression combine with the reflected waves at the impedance-mismatched rubber tube/stainless-steel tube interfaces. The resulting wave interference creates a pressure gradient and generates a net flow. When connected to a DBHPFC with an active area of 25 cm2, the pump can deliver the fuel at a maximum pumping rate of 30 ml/min, resulting in corresponding DBHPFC maximum power and a current of 13.0 W and 25.5 A, respectively. The specific power, volumetric power density, and back work ratio of the DBHPFC with this pumping method have been proven superior to those of the other pumping configuration with peristaltic pumps. This valveless impedance pump is mechanically simply and less susceptible to corrosion, and it can reduce the volume and weight of fuel cell systems to a measurable extent. The experimental results demonstrate the feasibility of the device for practical DBHPFC applications.


2020 ◽  
Vol 8 (39) ◽  
pp. 20543-20552
Author(s):  
Guillaume Braesch ◽  
Zhongyang Wang ◽  
Shrihari Sankarasubramanian ◽  
Alexandr G. Oshchepkov ◽  
Antoine Bonnefont ◽  
...  

Due to its unmatched theoretical voltage of 2.18 V, a direct alkaline fuel cell using sodium borohydride solution at the anode and hydrogen peroxide at the cathode represents a promising power source for high energy density applications.


2019 ◽  
Vol 29 (3) ◽  
Author(s):  
Mai Ngọc Tuan Anh

Silver nanoplates (SNPs) having different size were synthesized by a seed-mediated method. The seeds -silver nanoparticles with 4 – 6 nm diameters were synthesized first by reducing silver nitrate with sodium borohydride in the present of Trisodium Citrate and Hydrogen peroxide. Then these seeds were developed by continue reducing Ag\(^+\) ions with various amount of L-Ascorbic acid to form SNPs. Our analysis showed that the concentratrion of L-Ascorbic acid, a secondary reducing agent, played an important role to form SNPs. In addition, the size and in-plane dipole plasmon resonance wavelenght of silver nanoplates were increased when the concentration of added silver nitrate increased. The characterization of SNPs were studied by UV-Vis, FE-SEM, EDS and TEM methods.


RSC Advances ◽  
2014 ◽  
Vol 4 (110) ◽  
pp. 65031-65034 ◽  
Author(s):  
L. An ◽  
T. S. Zhao ◽  
X. L. Zhou ◽  
L. Wei ◽  
X. H. Yan

We propose to create the cathode potential by introducing a redox couple to the cathode while using hydrogen peroxide to chemically charge the redox ions, which eliminates the mixed potential associated with direct reduction of hydrogen peroxide.


2009 ◽  
Vol 27 (1) ◽  
pp. 128-133 ◽  
Author(s):  
Fuyuan XU ◽  
Tianshun SONG ◽  
Yuan XU ◽  
Yingwen CHEN ◽  
Shemin ZHU ◽  
...  

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