INFLUENCE OF BEAM ENERGY OF IONS ON PROPERTIES OF NICKEL NANOWIRES

Electrical conductivity and optical transmittance of nickel nanowire (Ni-NW) networks are reported in this work. The Ni-NWs were irradiated with 3.5, 3.8 and 4.11[Formula: see text]MeV proton (H[Formula: see text]) ions at room temperature. The electrical conductivity of Ni-NW networks was observed to increase with the increase in beam energies of H[Formula: see text] ions. With the increase in ions beam energies, electrical conductivity increases and this may be attributed to a reduction in the wire–wire point contact resistance due to the irradiation-induced welding of NWs. Welding is probably initiated due to H[Formula: see text] ion-irradiation induced heating effect that also improved the crystalline quality of the NWs. After ion beam irradiation, localized heat is generated in the NWs due to ionization which was also verified by SRIM simulation. Optical transmittance is increased with increase in the energy of H[Formula: see text] ions. The Ni-NW networks subjected to an ion beam irradiation to observe corresponding changes in electrical conductivity and optical transparencies are promising for various nanotechnological applications, such as highly transparent and conducting electrodes.

Electrodeposition of palladium-dotted nickel nanowire networks as a robust self-supported methanol electrooxidation catalyst

Mass activity and long-term stability are two major issues in current fuel cell catalyst designs. While supported catalysts normally suffer from poor long-term stability but show high mass activity, unsupported catalysts tend to perform better in the first point while showing deficits in the latter one. In this study, a facile synthesis route towards self-supported metallic electrocatalyst nanoarchitectures with both aspects in mind is outlined. This procedure consists of a palladium seeding step of ion track-etched polymer templates followed by a nickel electrodeposition and template dissolution. With this strategy, free-standing nickel nanowire networks which contain palladium nanoparticles only in their outer surface are obtained. These networks are tested in anodic half-cell measurements for demonstrating their capability of oxidising methanol in alkaline electrolytes. The results from the electrochemical experiments show that this new catalyst is more tolerant towards high methanol concentrations (up to $${5}\,\hbox{mol}\,\hbox{L}^{-1}$$ 5 mol L - 1 ) than a commercial carbon supported palladium nanoparticle catalyst and provides a much better long-term stability during potential cycling. Graphical Abstract

Anisotropic Magnetoresistance Effect of Nickel Nanowires

In this work, we study the magnetic properties of nickel nanowires by measuring their anisotropic magnetoresistance at room temperature. The single nickel nanowire is grown by electrodeposition in a polymer membrane (Polycarbonate). We measure the anisotropic magnetoresistance effect of nickel nanowires for the various values of the magnitudes and orientations of an external magnetic field. The results clearly show the existence the anisotropic magnetoresistance effect in the nickel nanowires. Besides, the experimental data are best fit to the analytical calculations using the Stoner-Wohlfarth model for the magnetization of the wires.

Physical and Chemical Properties Characterization of 3D-Printed Substrates Loaded with Copper-Nickel Nanowires

This study deals with the laser stereolithography manufacturing feasibility of copper-nickel nanowire-loaded photosensitive resins. The addition of nanowires resulted in a novel resin suitable for additive manufacturing technologies based on layer-by-layer photopolymerization. The pure and nanowire-loaded resin samples were 3D printed in a similar way. Their morphological, mechanical, thermal, and chemical properties were characterized. X-ray computed tomography revealed that 0.06 vol % of the composite resin was filled with nanowires forming randomly distributed aggregates. The increase of 57% in the storage modulus and 50% in the hardness when loading the resin with nanowire was attributed to the load transfer. Moreover, the decrease in the glass transition temperature from 57.9 °C to 52.8 °C in the polymeric matrix with nanowires evidenced a decrease in the cross-linking density, leading to a higher mobility of the polymer chains during glass transition. Consequently, this research demonstrates the successful dispersion and use of copper-nickel nanowires as a reinforcement material in a commercial resin for laser stereolithography.

Transformation of industrial wastewater into copper–nickel nanowire composites: straightforward recycling of heavy metals to obtain products of high added value

Large amounts of industrial metal containing process and waste solutions are a growing issue. In this work, we demonstrated that they could be transformed into materials of high added values such as copper-nickel nanowires (CuNi NWs) by simple chemical reduction. A thorough investigation of the parameter space was conducted. The microstructure of the obtained material was found tunable depending on the employed concentration of precursor, reducing agent, capping agent, pH, temperature, and reaction time. Moreover, the obtained product had a strong magnetic character, which enabled us to separate it from the reaction medium with ease. The results open new perspectives for materials science by proposing a new type of nanostructure: composite NWs of very promising properties, with metallic elements originating directly from industrial process solution.