A Generalized Model for Dynamic Contact Angle

Author(s):  
Joseph J. Thalakkottor ◽  
Kamran Mohseni

Contact angle is an important parameter that characterizes the degree of wetting of a material. While for a static case, estimation and measurement of contact angle has been well established, same can not be said for the dynamic case. There is still a lack of understanding and consensus as to the fundamental factors governing the microscopic dynamic contact angle. With the aim of understanding the physics and identifying the parameters that govern the actual or microscopic dynamic contact angle, we derive a model based on first principles, by performing a force balance around the region containing the contact line. It is found that in addition to the surface tension, the microscopic dynamic contact angle is also a function of surface tension gradient and the jump in normal stress across the interface. In addition to having a significant contribution in determining the microscopic dynamic contact angle, surface tension gradient is also a key cause for contact angle hysteresis.

Author(s):  
Fangjun Hong ◽  
Ping Cheng ◽  
Zhen Sun ◽  
Huiying Wu

In this paper, the electrowetting dynamics of a droplet on a dielectric surface was investigated numerically by a mathematical model including dynamic contact angle and contact angle hysteresis. The fluid flow is described by laminar N-S equation, the free surface of the droplet is modeled by the Volume of Fluid (VOF) method, and the electrowetting force is incorporated by exerting an electrical force on the cells at the contact line. The Kilster’s model that can deal with both receding and advancing contact angle is adopted. Numerical results indicate that there is overshooting and oscillation of contact radius in droplet spreading process before it ceases the movement when the excitation voltage is high; while the overshooting is not observed for low voltage. The explanation for the contact line overshooting and some special characteristics of variation of contact radius with time were also conducted.


Author(s):  
Zhang Shi ◽  
Yi Zhang ◽  
Mingchao Liu ◽  
Dorian A.H. Hanaor ◽  
Yixiang Gan

Author(s):  
Eiji Ishii ◽  
Taisuke Sugii

Predicting the spreading behavior of droplets on a wall is important for designing micro/nano devices used for reagent dispensation in micro-electro-mechanical systems, printing processes of ink-jet printers, and condensation of droplets on a wall during spray forming in atomizers. Particle methods are useful for simulating the behavior of many droplets generated by micro/nano devices in practical computational time; the motion of each droplet is simulated using a group of particles, and no particles are assigned in the gas region if interactions between the droplets and gas are weak. Furthermore, liquid-gas interfaces obtained from the particle method remain sharp by using the Lagrangian description. However, conventional surface tension models used in the particle methods are used for predicting the static contact angle at a three-phase interface, not for predicting the dynamic contact angle. The dynamic contact angle defines the shape of a spreading droplet on a wall. We previously developed a surface tension model using inter-particle force in the particle method; the static contact angle of droplets on the wall was verified at various contact angles, and the heights of droplets agreed well with those obtained theoretically. In this study, we applied our surface tension model to the simulation of a spreading droplet on a wall. The simulated dynamic contact angles for some Weber numbers were compared with those measured by Šikalo et al, and they agreed well. Our surface tension model was useful for simulating droplet motion under static and dynamic conditions.


2000 ◽  
Vol 222 (1) ◽  
pp. 51-54 ◽  
Author(s):  
V.D. Sobolev ◽  
N.V. Churaev ◽  
M.G. Velarde ◽  
Z.M. Zorin

2012 ◽  
Vol 461 ◽  
pp. 138-141
Author(s):  
Yin Xia Chang ◽  
Si Xiang Zhang ◽  
Wei Zhou ◽  
Bao Liu

This paper discusses the modeling of Electrowetting On Dielectric (EWOD) device that moves fluid droplets through surface tension effects and electric force. Instead of using a static contact angle as most papers did, we take the dynamic contact angle into count by using expression proposed by Voinov and Tanner. Firstly, the level set model and its initial values is present. Then the governing equations are discussed, and the diffused format is adopted for density and viscosity varies to smooth over the interface. The detailed expression for surface tension and electric force are also described for Navier–Stokes equations. After presenting the boundary conditions, the steps of numerical implementation are detailed.


2018 ◽  
Author(s):  
M. Elsharafi ◽  
K. Vidal ◽  
R. Thomas

Contact angle measurements are important to determine surface and interfacial tension between solids and fluids. A ‘water-wet’ condition on the rock face is necessary in order to extract oil. In this research, the objectives are to determine the wettability (water-wet or oil-wet), analyze how different brine concentrations will affect the wettability, and study the effect of the temperature on the dynamic contact angle measurements. This will be carried out by using the Cahn Dynamic Contact Angle. Analyzer DCA 315 to measure the contact angle between different fluids such as surfactant, alkaline, and mineral oil. This instrument is also used to measure the surface properties such as surface tension, contact angle, and interfacial tension of solid and liquid samples by using the Wilhelmy technique. The work used different surfactant and oil mixed with different alkaline concentrations. Varying alkaline concentrations from 20ml to 1ml were used, whilst keeping the surfactant concentration constant at 50ml.. It was observed that contact angle measurements and surface tension increase with increased alkaline concentrations. Therefore, we can deduce that they are directly proportional. We noticed that changing certain values on the software affected our results. It was found that after calculating the density and inputting it into the CAHN software, more accurate readings for the surface tension were obtained. We anticipate that the surfactant and alkaline can change the surface tension of the solid surface. In our research, surfactant is desirable as it maintains a high surface tension even when alkaline percentage is increased.


1985 ◽  
Vol 154 ◽  
pp. 1-28 ◽  
Author(s):  
Kalvis M. Jansons

The dynamic contact angle for a contact line moving over a solid surface with random sparse spots of roughness is determined theoretically in the limit of zero capillary number. The model exhibits many of the observed characteristics of moving contact lines on real rough surfaces, including contact-angle hysteresis and stick-slip. Several types of rough surface are considered, and a comparison is made between periodic and random rough surfaces.


1997 ◽  
Vol 334 ◽  
pp. 211-249 ◽  
Author(s):  
YULII D. SHIKHMURZAEV

A general mathematical model which describes the motion of an interface between immiscible viscous fluids along a smooth homogeneous solid surface is examined in the case of small capillary and Reynolds numbers. The model stems from a conclusion that the Young equation, σ1 cos θ = σ2 − σ3, which expresses the balance of tangential projection of the forces acting on the three-phase contact line in terms of the surface tensions σi and the contact angle θ, together with the well-established experimental fact that the dynamic contact angle deviates from the static one, imply that the surface tensions of contacting interfaces in the immediate vicinity of the contact line deviate from their equilibrium values when the contact line is moving. The same conclusion also follows from the experimentally observed kinematics of the flow, which indicates that liquid particles belonging to interfaces traverse the three-phase interaction zone (i.e. the ‘contact line’) in a finite time and become elements of another interface – hence their surface properties have to relax to new equilibrium values giving rise to the surface tension gradients in the neighbourhood of the moving contact line. The kinematic picture of the flow also suggests that the contact-line motion is only a particular case of a more general phenomenon – the process of interface formation or disappearance – and the corresponding mathematical model should be derived from first principles for this general process and then applied to wetting as well as to other relevant flows. In the present paper, the simplest theory which uses this approach is formulated and applied to the moving contact-line problem. The model describes the true kinematics of the flow so that it allows for the ‘splitting’ of the free surface at the contact line, the appearance of the surface tension gradients near the contact line and their influence upon the contact angle and the flow field. An analytical expression for the dependence of the dynamic contact angle on the contact-line speed and parameters characterizing properties of contacting media is derived and examined. The role of a ‘thin’ microscopic residual film formed by adsorbed molecules of the receding fluid is considered. The flow field in the vicinity of the contact line is analysed. The results are compared with experimental data obtained for different fluid/liquid/solid systems.


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