Numerical Study of Thermal Stresses in a Planar Solid Oxide Fuel Cell Stack

Author(s):  
Cun Wang ◽  
Tao Zhang ◽  
Cheng Zhao ◽  
Jian Pu

A three dimensional numerical model of a practical planar solid oxide fuel cell (SOFC) stack based on the finite element method is constructed to analyze the thermal stress generated at different uniform temperatures. Effects of cell positions, different compressive loads, and coefficient of thermal expansion (CTE) mismatch of different SOFC components on the thermal stress distribution are investigated in this work. Numerical results indicate that the maximum thermal stress appears at the corner of the interface between ceramic sealants and cells. Meanwhile the maximum thermal stress at high temperature is significantly larger than that at room temperature (RT) and presents linear growth with the increase of operating temperature. Since the SOFC stack is under the combined action of mechanical and thermal loads, the distribution of thermal stress in the components such as interconnects and ceramic sealants are greatly controlled by the CTE mismatch and scarcely influenced by the compressive loads.

Author(s):  
Dustin Lee ◽  
Jing-Kai Lin ◽  
Chun-Huang Tsai ◽  
Szu-Han Wu ◽  
Yung-Neng Cheng ◽  
...  

The effects of isothermally long-term and thermal cycling tests on the performance of an ASC type commercial solid oxide fuel cell (SOFC) have been investigated. For the long-term test, the cells were tested over 5000 h in two stages, the first 3000 h and the followed 2000 h, under the different flow rates of hydrogen and air. Regarding the thermal cycling test, 60 cycles in total were also divided into two sections, the temperature ranges of 700 °C to 250 °C and 700 °C to 50 °C were applied for the every single cycle of first 30 cycles and the later 30 cycles, respectively. The results of long-term test show that the average degradation rates for the cell in the first 3000 h and the followed 2000 h under different flow rates of fuel and air are 1.16 and 2.64%/kh, respectively. However, there is only a degradation of 6.6% in voltage for the cell after 60 thermal cycling tests. In addition, it is found that many pores formed in the anode of the cell which caused by the agglomeration of Ni after long-term test. In contrast, the vertical cracks penetrating through the cathode of the cell and the in-plane cracks between the cathode and barrier layer of the cell formed due to the coefficient of thermal expansion (CTE) mismatch after 60 thermal cycling tests.


ChemInform ◽  
2014 ◽  
Vol 45 (30) ◽  
pp. no-no
Author(s):  
S. A. Hajimolana ◽  
S. M. Tonekabonimoghadam ◽  
M. A. Hussain ◽  
M. H. Chakrabarti ◽  
N. S. Jayakumar ◽  
...  

2021 ◽  
Vol 103 (1) ◽  
pp. 767-784
Author(s):  
Jianmin Zheng ◽  
Liusheng Xiao ◽  
Ming Chen ◽  
Jinliang Yuan

2020 ◽  
Vol 167 (4) ◽  
pp. 044517
Author(s):  
Congying Jiang ◽  
Yuchen Gu ◽  
Wanbing Guan ◽  
Meng Ni ◽  
Junkang Sang ◽  
...  

Materials ◽  
2016 ◽  
Vol 9 (10) ◽  
pp. 814 ◽  
Author(s):  
Paulina Pianko-Oprych ◽  
Tomasz Zinko ◽  
Zdzisław Jaworski

Author(s):  
Wenchun Jiang ◽  
Yun Luo ◽  
Weiya Zhang ◽  
Wanchuck Woo ◽  
S. T. Tu

The creep and failure probability of a planar solid oxide fuel cell (SOFC) through a duty cycle is calculated by finite element method (FEM) and Weibull method, respectively. Two sealing methods, namely, rigid seal and bonded compliant seal (BCS), are compared. For the rigid seal, failure is predicted in the glass ceramic because of a failure probability of 1 and maximum creep strain. For the BCS design, the foil can absorb part of thermal stresses in the cell by its own elastoplastic deformation, which considerably decreases failure probability and creep strain in the SOFC. The creep strength of BCS method is achieved by sealing foil with excellent creep properties. Temperature fluctuation during the operating stage leads to the increase in thermal stress and failure probability. In particular, temperature change from low-power to high-power state results in a considerable increase in the creep strain, leading to creep failure for the rigid seal. A failure probability of 1 is generated during start-up and shut-down stages. Therefore, temperature fluctuation should be controlled to ensure structural integrity, and lowering the operating temperature can decrease failure probability and creep failure.


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