Review and Analysis of Bluff Body Flame Stabilization Data

Author(s):  
Sajjad A. Husain ◽  
Ganesh Nair ◽  
Santosh Shanbhogue ◽  
Tim C. Lieuwen

This paper compiles and analyzes bluff body stabilized flame blowoff data from the literature. Many of these studies contain semi-empirical blowoff correlations that are, in essence, Damko¨hler number correlations of their data. This paper re-analyzes these data, utilizing various Damko¨hler number correlations based upon detailed kinetic modeling for determining chemical time scales. While the results from this compilation are similar to that deduced from many earlier studies, it demonstrates that a rather comprehensive data set taken over a large range of conditions can be correlated from “first-principles” based calculations that do not rely on empirical fits or adjustable constants (e.g., global activation energy or pressure exponents). The paper then discusses the implications of these results on understanding of blowoff. Near blowoff flames experience local extinction of the flame sheet, manifested as “holes” that form and convect downstream. However, local extinction is distinct from blowoff — in fact, under certain conditions the flame can apparently persist indefinitely with certain levels of local extinction. We hypothesize that simple Damko¨hler number correlations contain the essential physics describing this first stage of blowoff; i.e., they are correlations for the conditions where local extinction on the flame begins, but do not fundamentally describe the ultimate blowoff condition itself. However, such correlations are reasonably successful in correlating blowoff limits because the ultimate blowoff event appears to be correlated to some extent to the onset of this first stage.

2016 ◽  
Vol 3 (1) ◽  
Author(s):  
Matti Ropo ◽  
Markus Schneider ◽  
Carsten Baldauf ◽  
Volker Blum

ACS Omega ◽  
2021 ◽  
Vol 6 (17) ◽  
pp. 11436-11446
Author(s):  
Yui Numazawa ◽  
Yuki Hara ◽  
Yoshiya Matsukawa ◽  
Yohsuke Matsushita ◽  
Hideyuki Aoki ◽  
...  

Metals ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 1176
Author(s):  
Fuqiang Zheng ◽  
Yufeng Guo ◽  
Feng Chen ◽  
Shuai Wang ◽  
Jinlai Zhang ◽  
...  

The effects of F− concentration, leaching temperature, and time on the Ti leaching from Ti-bearing electric furnace slag (TEFS) by [NH4+]-[F−] solution leaching process was investigated to reveal the leaching mechanism and kinetics of titanium. The results indicated that the Ti leaching rate obviously increased with the increase of leaching temperature and F− concentration. The kinetic equation of Ti leaching was obtained, and the activation energy was 52.30 kJ/mol. The fitting results of kinetic equations and calculated values of activation energy both indicated that the leaching rate of TEFS was controlled by surface chemical reaction. The semi-empirical kinetics equation was consistent with the real experimental results, with a correlation coefficient (R2) of 0.996. The Ti leaching rate reached 92.83% after leaching at 90 °C for 20 min with F− concentration of 14 mol/L and [NH4+]/[F−] ratio of 0.4. The leaching rates of Si, Fe, V, Mn, and Cr were 94.03%, 7.24%, 5.36%, 4.54%, and 1.73%, respectively. The Ca, Mg, and Al elements were converted to (NH4)3AlF6 and CaMg2Al2F12 in the residue, which can transform into stable oxides and fluorides after pyro-hydrolyzing and calcinating.


2019 ◽  
Vol 27 (4) ◽  
pp. 420-430
Author(s):  
D. P. Krylov

Zircon β-factors have been calibrated against temperature for isotopic substitutions of 18O/16O and 30Si/28Si. Calculations were performed using the density functional theory (DFT) with the “frozen phonon” approach. The deduced geometric parameters of the zircon unit cell, and the phonon frequencies calculated, agree well with the experimental data. The results are expressed by the cubic polynomials on x = 106/T(K)2: 1000lnβzrn(18O/16O) = 9.83055x – 0.19499x2 + 0.00388x3;  1000lnβzrn(30Si/28Si) = 7.89907x – 0.17978x2 + 0.00377x3. The expressions deduced can be utilized to construct geothermometers if combined with β-factors of coexisting phases. New calibrations of quartz-zircon are given. The new values of 1000lnβzrn and the estimated isotope fractionation factors between quartz and zircon (1000lnβqtz–1000lnβzrn) deviate considerably from previously used experimental, empirical, and semi-empirical calibration of the isotopic equilibrium.


Author(s):  
Z. Gu ◽  
M. A. R. Sharif

Abstract The two-dimensional turbulent recirculating flow fields behind a V-shaped bluff body have been investigated numerically. Similar bluff bodies are used in combustion chambers for flame stabilization. The governing transport equations in conservative form are solved by a pressure based predictor-corrector method. The standard k-ϵ turbulence closure model and a boundary fitted multi-block curvilinear grid system are used in the computation. The code is validated against turbulent flow over a backward facing step problem. The predicted flow field behind the bluff body is also compared with experiment. It is found that while the qualitative features of the flow are well predicted, there is quantitative disagreement between the measurement and prediction. This disagreement can be partially attributed to the k-ϵ turbulence model which is known to be inadequate for recirculating flows. Parametric investigation of the flow field by varying the shape and size of the bluff body is also performed and the results are reported.


2021 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Xiang Qiu ◽  
Kun Zhang ◽  
Qin Kang ◽  
Yicheng Fan ◽  
Hongyu San ◽  
...  

Purpose This paper aims to study the mechanism of hydrogen embrittlement in 12Cr2Mo1R(H) steel, which will help to provide valuable information for the subsequent hydrogen embrittlement research of this kind of steel, so as to optimize the processing technology and take more appropriate measures to prevent hydrogen damage. Design/methodology/approach The hydrogen diffusion coefficient of 12Cr2Mo1R(H) steel was measured by the hydrogen permeation technique of double electrolytic cells. Moreover, the influence of hydrogen traps in the material and experimental temperature on hydrogen diffusion behavior was discussed. The first-principles calculations based on density functional theory were used to study the occupancy of H atoms in the bcc-Fe cell, the diffusion path and the interaction with vacancy defects. Findings The results revealed that the logarithm of the hydrogen diffusion coefficient of the material has a linear relationship with the reciprocal of temperature and the activation energy of hydrogen atom diffusion in 12Cr2Mo1R(H) steel is 23.47 kJ/mol. H atoms stably exist in the nearly octahedral interstices in the crystal cell with vacancies. In addition, the solution of Cr/Mo alloy atom does not change the lowest energy path of H atom, but increases the diffusion activation energy of hydrogen atom, thus hindering the diffusion of hydrogen atom. Cr/Mo and vacancy have a synergistic effect on inhibiting the diffusion of H atoms in α-Fe. Originality/value This article combines experiments with first-principles calculations to explore the diffusion behavior of hydrogen in 12Cr2Mo1R(H) steel from the macroscopic and microscopic perspectives, which will help to establish a calculation model with complex defects in the future.


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