Evaluation of Thermodynamic Properties of Cerium in Liquid Cadmium Cathode Within LiCl-KCl Salt System

2016 ◽  
Author(s):  
Dalsung Yoon ◽  
Supathorn Phongikaroon
Keyword(s):  
Thermodynamic Properties ◽  
Gibbs Energy ◽  
Intermetallic Compounds ◽  
Linear Trend ◽  
Open Circuit ◽  
Salt System ◽  
Free Energies ◽  
Enthalpy And Entropy ◽  
Molten Salt System

Thermodynamic properties of Ce-Cd intermetallic compound were investigated in LiCl-KCl-CeCl3-CdCl2 molten salt system at various temperatures. Six Ce-Cd intermetallic compounds, CeCd, CeCd2, CeCd3, Ce13Cd58, CeCd6, and CeCd11 could be observed via cyclic voltammetry (CV) and the relative Gibbs free energies for the intermetallic formations were estimated by the analysis of the anodic peaks in the CV experiments. Furthermore, an open circuit chronopotentiometry which is known as a suitable method for measuring thermodynamic values of intermetallic compounds were performed. The linear trends of the relative Gibbs free energies were found by using potential difference from CV and CP methods. It can be noted that CV method can be easy and fast tool to estimate relative Gibbs energy for intermetallic compounds of Cd-Ms (metals). For the determination of standard Gibbs free energy, enthalpy, and entropy for the intermetallic formation, CP results were used. The linear trend of the Gibbs energy were obtained against temperature changing from 698 K to 823 K. From the linear relationship, the enthalpy and entropy of the formation were calculated.

Electrochemical formation of Sc-Al intermetallic compounds in the eutectic LiCl-KCl. Determination of thermodynamic properties.

2014 ◽  
Vol 118 ◽  
pp. 58-66 ◽  
Author(s):  
Y. Castrillejo ◽  
A. Vega ◽  
M. Vega ◽  
P. Hernández ◽  
J.A. Rodriguez ◽  
...  
Keyword(s):  
Thermodynamic Properties ◽  
Intermetallic Compounds

Electrochemical behavior of La(iii) on liquid Bi electrode in LiCl–KCl melts. Determination of thermodynamic properties of La–Bi and Li–Bi intermetallic compounds

RSC Advances ◽  
2015 ◽  
Vol 5 (100) ◽  
pp. 82471-82480 ◽  
Author(s):  
Mei Li ◽  
Qunqun Gu ◽  
Wei Han ◽  
Xingmei Zhang ◽  
Yang Sun ◽  
...  
Keyword(s):  
Thermodynamic Properties ◽  
Intermetallic Compounds ◽  
Electrochemical Behavior ◽  
Emf Measurements

Electrochemical behavior of La(iii) was studied on liquid Bi electrode. Thermodynamic properties of five La–Bi intermetallic compounds and Li3Bi were calculated from emf measurements.

Phosphorylated Calixarenes as Receptors of L-Amino Acids and Dipeptides: Calorimetric Determination of Gibbs Energy, Enthalpy and Entropy of Complexation

2006 ◽  
Vol 18 (3) ◽  
pp. 167-176 ◽  
Author(s):  
Wojciech Zielenkiewicz ◽  
Agniaszka Marcinowicz ◽  
Sergey Cherenok ◽  
Vitaly I. Kalchenko ◽  
Jaroslaw Poznański
Keyword(s):  
Amino Acids ◽  
Gibbs Energy ◽  
Entropy Of Complexation ◽  
Enthalpy And Entropy ◽  
Calorimetric Determination

Thermodynamic rationalization of molten-salt clectrodeposition in oxide-based systems

1989 ◽  
Vol 4 (6) ◽  
pp. 1495-1504 ◽  
Author(s):  
S. Crouch-Baker ◽  
R. A. Huggins
Keyword(s):  
Phase Diagram ◽  
Thermodynamic Properties ◽  
Molten Salt ◽  
Salt System ◽  
Single Crystalline ◽  
Crystalline Materials ◽  
Electrodeposition Process ◽  
Isothermal Phase Diagram ◽  
Molten Salt System ◽  
Salt Systems

Electrodeposition from molten-salt systems has been studied extensively as a method of producing both polycrystalline and single-crystalline materials. In this work, the thermodynamic aspects of the electrodeposition process are examined in a number of cases in which the molten-salt system behaves effectively as an oxygen-transporting medium, with particular reference to the thermodynamic properties of the melt. It is demonstrated how information gained from the construction of the appropriate isothermal phase diagram may be used to control and/or rationalize the behavior found in a given melt system on electrolysis.

Models of Thermodynamic Properties of Prominences

1979 ◽  
Vol 44 ◽  
pp. 349-355
Author(s):  
R.W. Milkey
Keyword(s):  
Thermodynamic Properties ◽  
Mass Transport ◽  
Emission Spectrum ◽  
Thermodynamic Parameters ◽  
Working Group ◽  
Physical Processes ◽  
Theoretical Concepts ◽  
Group 3 ◽  
Observational Techniques

The focus of discussion in Working Group 3 was on the Thermodynamic Properties as determined spectroscopically, including the observational techniques and the theoretical modeling of physical processes responsible for the emission spectrum. Recent advances in observational techniques and theoretical concepts make this discussion particularly timely. It is wise to remember that the determination of thermodynamic parameters is not an end in itself and that these are interesting chiefly for what they can tell us about the energetics and mass transport in prominences.

Determination of the Nucleophilicity of Tricarbonyliron Coordinated Cyclohepta-1,3,5-triene

1999 ◽  
Vol 64 (11) ◽  
pp. 1770-1779 ◽  
Author(s):  
Herbert Mayr ◽  
Karl-Heinz Müller
Keyword(s):  
Gibbs Energy ◽  
Ambient Temperature ◽  
Rate Constants ◽  
Second Order ◽  
Order Rate ◽  
Electrophilic Additions ◽  
Kinetics Of

The kinetics of the electrophilic additions of four diarylcarbenium ions (4a-4d) to tricarbonyl(η4-cyclohepta-1,3,5-triene)iron (1) have been studied photometrically. The second-order rate constants match the linear Gibbs energy relationship log k20 °C = s(E + N) and yield the nucleophilicity parameter N(1) = 3.69. It is concluded that electrophiles with E ≥ -9 will react with complex 1 at ambient temperature.

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