Research on Nickel-Plated Hydrogen-Absorption Device in Fuel Rod and Performance Testing

Author(s):  
Zhou Qin ◽  
Li Jiwei ◽  
Dang Yu ◽  
Ding Yang

The hydrogen may be introduced into the fuel rod during the process of production and manufacture. During the operation in reactor, the irradiated fuel pellets also produce radioactive isotopes of hydrogen and tritium. Under the operating condition in pile, the hydrogen in fuel rod will enter the zirconium alloy cladding tube forming hydride, lead to the hydrogen brittleness of cladding tube, and severe cases can lead to the cladding tube broken. The radioactive tritium inside fuel rod has high activity, and it possibly goes through the cladding tube by diffusion penetration into the reactor coolant. With the reactor in waste water or steam waste emissions to the environment, such as lead to tritium radiation safety problems of environmental pollution. Thus, reduce the hydrogen source and tritium pressure in fuel rod, is the way to reduce the hydrogen absorption effect and the release of tritium to coolant. By conducting the Zr-4 alloy nickel-plated hydrogen-absorption device design research, through nickel plating process on the surface of Zr-4 alloy structure parts, eliminating the influence of the oxide film to maintain its excellent absorbing hydrogen isotope activity. During the design operating temperature conditions of fuel rods, the reaction of zirconium hydride has lower hydrogen balance pressure, while the gas cavity kept low pressure hydrogen isotope, can significantly reduce the hydrogen pickup of fuel rod zirconium alloy cladding tube and reduce the tritium permeation emissions by cladding tube. Through nickel-plated hydrogen-absorption device structure design, manufacture, performance testing, analysis and evaluation, demonstrates that the flat plate and cross nickel-plated hydrogen-absorption device can meet the expected effect.

2020 ◽  
Vol 86 (8) ◽  
pp. 32-37
Author(s):  
V. V. Larionov ◽  
Xu Shupeng ◽  
V. N. Kudiyarov

Nickel films formed on the surface of zirconium alloys are often used to protect materials against hydrogen penetration. Hydrogen adsorption on nickel is faster since the latter actively interacts with hydrogen, oxidizes and forms a protective film. The goal of the study is to develop a method providing control of hydrogen absorption by nickel films during vacuum-magnetron sputtering and hydrogenation via measuring thermoEMF. Zirconium alloy E110 was saturated from the gas phase with hydrogen at a temperature of 350°C and a pressure of 2 atm. A specialized Rainbow Spectrum unit was used for coating. It is shown that a nickel film present on the surface significantly affects the hydrogen penetration into the alloy. A coating with a thickness of more than 2 μm deposited by magnetron sputtering on the surface of a zirconium alloy with 1% Nb, almost completely protects the alloy against hydrogen penetration. The magnitude of thermoemf depends on the hydrogen concentration in the zirconium alloy and film thickness. An analysis of the hysteresis width of the thermoEMF temperature loop and a method for determining the effective activation energy of the conductivity of a hydrogenated material coated with a nickel film are presented. The results of the study can be used in assessing the hydrogen concentration and, hence, corrosion protection of the material.


2019 ◽  
Vol 11 (6) ◽  
pp. 349-355 ◽  
Author(s):  
Weitao Cheng ◽  
Akinobu Teramoto ◽  
Tadahiro Ohmi

1963 ◽  
Vol 9 (3) ◽  
pp. 339-347 ◽  
Author(s):  
J.E. Harris ◽  
P.G. Partridge ◽  
W.T. Eeles ◽  
G.K. Rickards

2008 ◽  
Vol 23 (2) ◽  
pp. 190-190
Author(s):  
M. Kerr ◽  
M. R. Daymond ◽  
R. A. Holt ◽  
J. D. Almer

Nanoscale ◽  
2020 ◽  
Vol 12 (4) ◽  
pp. 2648-2656 ◽  
Author(s):  
Dechao Guo ◽  
Zeng Xu ◽  
Dezhi Yang ◽  
Dongge Ma ◽  
Benzhong Tang ◽  
...  

High performance photomultiplication-type organic photodetectors based on an AIE material were successfully fabricated by designing a device structure.


2019 ◽  
Vol 5 (2) ◽  
Author(s):  
Felix Boldt

During operation of light water reactors, the Zircaloy fuel rod cladding is susceptible for hydrogen uptake. When the local solubility limit of hydrogen in Zircaloy is reached, additional hydrogen precipitates as zirconium hydride, which affects the ductility of the fuel rod cladding. Especially, the radially aligned hydrides enhance embrittlement, while circumferential (azimuthal) hydrides have a less detrimental effect. In this work, the influence of high temperatures during the dry storage period on hydride dissolution and precipitation is demonstrated. Therefore, in a descriptive example scenario being discussed, the simulation of a limited heat removal from the cask will heat up the dry storage cask for days and causes dissolution of hydrides in the cladding. Depending on the threshold stress for reorientation, the following cooldown results on different hydride precipitation behavior. The threshold stress leads to an enhanced or delayed precipitation of radial hydrides. The GRS fuel rod code TESPA-ROD is equipped with a new model for hydrogen solubility and applied to long-term storage transients. In this article, hydride refers to zirconium hydrides formed inside the fuel rod cladding.


2011 ◽  
Vol 675-677 ◽  
pp. 1171-1174
Author(s):  
Mei Ling Zhang ◽  
Rui Wang ◽  
Zhan Gang Wang

Flexible fabric keyboard is a field of smart textile. It can overcome traditional horniness keyboard can’t be foldable and washing. In this laboratory study there is Three Layers Weaved Once structure designed which consists of three kinds of orifice dimension, for example 4 wefts, 8 wefts and 12 wefts. At the same time three kinds of conductive filaments number combined are planed for each orifice dimension. There are 1, 4 and 8 roots of filaments combined together so that contact areas of the conductive material are changed. Then the immediate regain, connection pressure and connection ratio are tested and analyzed for every kind of fabric keyboard switch. It is concluded that 4 wefts orifice dimension and 4 roots of filaments combined is a better project. These findings may assist in recommendations regarding the further development of flexible fabric keyboard. The fabric keyboard switch forms the foundation for many smart textile applications.


Author(s):  
Martin Booth ◽  
Michael Martin

Zirconium alloys, as used in water-cooled nuclear reactors, are susceptible to a time-dependent failure mechanism known as Delayed Hydride Cracking, or DHC. Corrosion of zirconium alloy in the presence of water generates hydrogen that subsequently diffuses through the metallic structure in response to concentration, temperature and hydrostatic stress gradients. As such, regions of increased hydrogen concentration develop at stress concentrating features, leading to zirconium hydride precipitation. Regions containing zirconium hydride are brittle and prone to failure if plant transient loads are sufficient. This paper demonstrates the application of the Extended Finite Element Method, or XFEM, to the assessment of the DHC susceptibility of stress concentrating features, typical of those considered in the structural integrity assessment of heavy water pressure tube reactors. The method enables the calculation of a DHC threshold load. This paper builds on the process-zone approach that is currently used to provide the industry-standard DHC assessment of zirconium alloy pressure tubes and also recent developments that have extended the application of the process-zone approach to arbitrary geometries by the use of finite element cohesive-zone analysis. In the standard cohesive-zone approach, regions of cohesive elements are situated in discrete locations where the formation of zirconium hydride is anticipated. In contrast, the use of XFEM based cohesive formulations removes the requirement to define cohesive zones a priori, thereby allowing the assessment of geometries in which the location of hydride material is not known.


2020 ◽  
Author(s):  
Haibo Zeng ◽  
Xiaoming Li ◽  
Jiaxin Chen ◽  
Dandan Yang ◽  
Xi Chen ◽  
...  

Abstract Fluorescent type nuclear battery (NB) consisting of scintillator and photovoltaic device (PVD) enables semipermanent power source for both small and large devices working under harsh circumstances without instant energy supply. In spite of the progress of device structure design, the development of scintillators with high light yield (LY) and longer emission wavelength catering to PVDs is far behind. Here, a novel Cs3Cu2I5: Mn scintillator, which exhibits an ultrahigh LY of ~ 67000 ph/MeV at an emission wavelength of 564 nm is presented, and this is the highest value at such a long wavelength based on low cost precursors. Besides, doping and intrinsic features endow Cs3Cu2I5: Mn with robust thermal stability and irradiation hardness that 71% or > 90% of the initial radioluminescence (RL) intensity can be maintained in an ultra-broad temperature range of 77 K-433 K or after a total irradiation dose of 38.7 Gy at 333 K, respectively. These superiorities allow the fabrication of an efficient and stable NB, which showed an output improvement of 337% respect to that without scintillator. Luminescence mechanisms including self-trapped exciton, energy transfer, and impact excitation are proposed for the dramatic RL improvement. It is expected that such a new and robust scintillator will open a window for the fields of NBs and radiography.


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