Effects of Trace Pb on Creep and Fracture of 25Cr35Ni-Nb Alloy

2015 ◽  
Author(s):  
Tao Chen ◽  
Chen Xuedong ◽  
Yunrong Lv ◽  
Juan Ye ◽  
Xiyun Hao
Keyword(s):  
High Temperature ◽  
Grain Boundary ◽  
Centrifugal Casting ◽  
Boundary Surface ◽  
Local Stress ◽  
Composition Analysis ◽  
Early Failure ◽  
Creep Properties ◽  
Loading Rates ◽  
Fractographic Observation

The centrifugal casting 25Cr35Ni-Nb ethylene pyrolysis furnace tubes with different contents of Pb were selected to study the effects of Pb content on the creep and fracture properties. Both the high temperature rupture test at 1100 °C /17 MPa and the slow straining test at 850 °C with different loading rates show that the increase of Pb content significantly degrades the high temperature creep properties of centrifugal casting 25Cr35Ni-Nb alloy furnace tubes. The fractographic observation and the chemical composition analysis show that Pb segregates to the grain boundary at high temperature. It shows that the segregation of Pb to grain boundary occurs even when the content of Pb is several ppm, which leads to the reduction of grain boundary surface energy at high temperature. The initiation of creep cavities becomes easier. The creep cavities coalesce together under the local stress, forming cracks and finally causing the early failure of furnace tubes.

scholarly journals Effect of Grain Boundary Precipitates on High Temperature Creep Properties of Ni-2OCr-Nb-W Alloys

1986 ◽  
Vol 72 (10) ◽  
pp. 1605-1612 ◽  
Author(s):  
Masao TAKEYAMA ◽  
Kaoru KAWASAKI ◽  
Takashi MATSUO ◽  
Ryohei TANAKA
Keyword(s):  
High Temperature ◽  
Grain Boundary ◽  
High Temperature Creep ◽  
Creep Properties ◽  
Temperature Creep

Study on Creep Properties of SiCp/AZ61 Composites

2011 ◽  
Vol 189-193 ◽  
pp. 4227-4230
Author(s):  
Hong Yan ◽  
Zhi Min Huang
Keyword(s):  
Thermal Analysis ◽  
High Temperature ◽  
Grain Boundary ◽  
Grain Boundaries ◽  
Dynamic Mechanical Thermal Analysis ◽  
Creep Properties ◽  
Casting Technique ◽  
Sic Particles ◽  
The Matrix ◽  
Semi Solid

SiCp/AZ61 composites reinforced with SiC particles were fabricated by semi-solid stirring-melt casting technique. The creep properties of the composites have been studied by dynamic mechanical thermal analysis, micro-structural and XRD observation. The results show that the matrix grains were refined obviously at high temperature with SiC particles introducing and the creep properties of SiCp/AZ61 composites were improved comparing with AZ61 alloy. SiC particles were substituted for Mg17Al12 phase that was easily intenerated at high temperature on grain boundaries. The pinning of SiC particles prevents dislocation and slip of grain boundary at high temperature.

NICROFER 5520 Co

Alloy Digest ◽  
1995 ◽  
Vol 44 (3) ◽  
Keyword(s):  
High Temperature ◽  
Chemical Composition ◽  
Physical Properties ◽  
Tensile Properties ◽  
High Temperatures ◽  
Heat Treating ◽  
High Temperature Corrosion ◽  
Creep Properties ◽  
Nickel Chromium ◽  
Temperature Performance

Abstract NICROFER 5520 Co is a nickel-chromium-cobalt-molybdenum alloy with excellent strength and creep properties up to high temperatures. Due to its balanced chemical composition the alloy shows outstanding resistance to high temperature corrosion in the form of oxidation and carburization. This datasheet provides information on composition, physical properties, elasticity, and tensile properties. It also includes information on high temperature performance as well as forming, heat treating, machining, and joining. Filing Code: Ni-480. Producer or source: VDM Technologies Corporation.

scholarly journals Grain-Boundary Surface Terminations Incorporating Oxygen Vacancies for Selectively Boosting CO2 Photoreduction Activity

Nano Energy ◽  
2021 ◽  
pp. 105869
Author(s):  
Xiaojie She ◽  
Xingwang Zhu ◽  
Jinman Yang ◽  
Yanhua Song ◽  
Yuanbin She ◽  
...  
Keyword(s):  
Grain Boundary ◽  
Oxygen Vacancies ◽  
Boundary Surface ◽  
Co2 Photoreduction

Increased Thermal Stability of Co-silicide Using Co-Ta Alloy Films

2001 ◽  
Vol 670 ◽  
Author(s):  
Min-Joo Kim ◽  
Hyo-Jick Choi ◽  
Dae-Hong Ko ◽  
Ja-Hum Ku ◽  
Siyoung Choi ◽  
...  
Keyword(s):  
Thermal Stability ◽  
High Temperature ◽  
Grain Boundary ◽  
Reaction Rate ◽  
Boundary Migration ◽  
Grain Boundary Migration ◽  
Alloy Films ◽  
Post Annealing ◽  
Alloy Process ◽  
Thermal Stability Of

ABSTRACTThe silicidation reactions and thermal stability of Co silicide formed from Co-Ta/Si systems have been investigated. In case of Co-Ta alloy process, the formation of low resistive CoSi2phase is delayed to about 660°C, as compared to conventional Co/Si system. Moreover, the presence of Ta in Co-Ta alloy films reduces the silicidation reaction rate, resulting in the strong preferential orientation in CoSi2 films. Upon high temperature post annealing in the furnace, the sheet resistance of Co-silicide formed from Co/Si systems increases significantly, while that of Co-Ta/Si systems maintains low. This is due to the formation of TaSi2 at the grain boundaries and surface of Co-silicide films, which prevents the grain boundary migration thereby slowing the agglomeration. Therefore, from our research, increased thermal stability of Co-silicide films was successfully obtained from Co-Ta alloy process.

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