Effect of Hydrogen on Creep Behavior of a Vanadium-Modified CRMO Steel and its Continuum Damage Analysis

Author(s):  
Yu Zhou ◽  
Xuedong Chen ◽  
Zhichao Fan ◽  
Peng Xu ◽  
Xiaoliang Liu

Creep properties both in hot hydrogen and in air of a vanadium-modified CrMo steel 2.25Cr1Mo0.25V, widely used in hydroprocessing reactors in petrochemical industry, were investigated to determine the effect of hydrogen on high-temperature creep behavior of the low-alloy ferritic steel. The minimum creep strain rate in hydrogen is higher than that in air, whereas the creep strain at failure in hydrogen is relatively smaller. Many tiny spherical cavities are dispersively distributed in the ruptured specimen under hydrogen, which has relatively higher Vickers hardness. Based on the thermodynamics theory, the pressure of methane generated by the so-called “methane reaction” in the vanadium-modified CrMo steel can be calculated by using corresponding thermodynamic data, assuming that methane can reach its equilibrium state during cavitation. Meanwhile, a creep constitutive model based on continuum damage mechanics (CDM) was proposed, taking methane pressure into consideration. The results show that methane pressure increases nonlinearly with increase of hydrogen pressure while it decreases gradually with increase of temperature. The constitutive model considering the damage induced by methane pressure can be used to predict the effect of hydrogen pressure and temperature on creep life, indicating that the influence of hydrogen at elevated temperatures becomes smaller when increasing temperature or decreasing hydrogen pressure.

Author(s):  
Ricardo Vega ◽  
Jaime A. Cano ◽  
Calvin M. Stewart

Abstract The objective of this study is to introduce a method for creating “material specific” creep continuum damage mechanics-based constitutive models. Herein, material specific is defined as a constitutive model based on the mechanism-informed minimum creep strain rate (MCSR) equations found in deformation mechanism maps and calibrated to available material data. The material specific models are created by finding the best MCSR model for a dataset. Once the best MCSR model is found, the Monkman Grant inverse relationship between the MCSR and rupture time is employed to derive a rupture equation. The equations are substituted into continuum damage mechanics-based creep strain rate and damage evolution equations to furnish predictions of creep deformation and damage. Material specific modeling allows for the derivation of creep constitutive models that can better the material behavior specific to the available data of a material. The material specific framework is also advantageous since it has a systematic framework that moves from finding the best MCSR model, to rupture time, to damage evolution and, creep strain rate. Data for Alloy P91 was evaluated and a material specific constitutive model derived. The material specific model was able to accurately predict the MCSR, creep deformation, damage, and rupture of alloy P91.


2015 ◽  
Vol 750 ◽  
pp. 266-271 ◽  
Author(s):  
Yu Zhou ◽  
Xue Dong Chen ◽  
Zhi Chao Fan ◽  
Yi Chun Han

The creep behavior of 2.25Cr-1Mo-0.25V ferritic steel was investigated using a set of physically-based creep damage constitutive equations. The material constants were determined according to the creep experimental data, using an efficient genetic algorithm. The user-defined subroutine for creep damage evolution was developed based on the commercial finite element software ANSYS and its user programmable features (UPFs), and the numerical simulation of the stress distribution and the damage evolution of the semi V-type notched specimen during creep were studied. The results showed that the genetic algorithm is a very efficient optimization approach for the parameter identification of the creep damage constitutive equations, and finite element simulation based on continuum damage mechanics can be used to analyze and predict the creep damage evolution under multi-axial stress states.


2015 ◽  
Vol 10 (Special-Issue1) ◽  
pp. 782-788 ◽  
Author(s):  
Mehdi Shekarbeigi ◽  
Hasan Sharafi

In the last three decades, the constitutive modelling of concrete evolved considerably. This paper describes various developments in this field based on different approaches such anelasticity, plasticity, continuum damage mechanics, plastic fracturing, endochronic theory, microplane models, etc. In this article the material is assumed to undergo small deformations. Only time independent constitutive models and the issues related to their implementation are discussed


Author(s):  
Mohammad Shafinul Haque ◽  
Calvin M. Stewart

The MPC Omega and Theta models for creep deformation and life prediction have become popular in recent years. Both models offer better prediction than classical constitutive models such as Norton Power law, Bailey-Norton law, and Norton-Soderberg law to name a few. The Omega model uses a strain hardening approach and requires two material constants for creep deformation and life prediction. An analytical solution to the constants are available and it is easy to manipulate and implement numerically. However, the analytical damage of the Omega model predicts an unrealistic linear damage evolution. The Theta model uses a time-hardening approach, and requires four constant that are a function of stress and temperature. For materials under isothermal conditions, with tertiary creep dominant deformation, the Theta model constants can be determined using only two constants. Life prediction using the Theta and Omega models depends on the final creep strain. The final creep strain observed in an experiment is stochastic; dependent on the material, testing conditions, and operator. The statistics of final creep strain must be investigated before the Theta or Omega models can be applied. In literature, some authors add a nonlinear damage variable to the Theta model; however, critical damage at rupture is not unity violating the assumptions of continuum damage mechanics. There is a superior Sin-hyperbolic continuum damage model available in the literature that can be used to overcome these problems. It is hypothesized that a functional relationships exist between the three models and these relationships can be exploited to achieve more accurate and easy to implement creep deformation and life predictions. In this study, the relationships between the constants of MPC Omega, Theta, and a Sin-hyperbolic CDM models are determined analytically. The sin-hyperbolic model incorporates a continuum damage variable in the creep strain rate equation. The damage function exhibits a more realistic elliptical path and is constructed such that damage is always unity at rupture. This function facilitates conversion of one models’ constants to the constants of the other two. The relationships between the constants are identified, while maintaining dimensional homogeneity. Using the derived relationships, the three models can be easily compared and the disadvantages of each respective model can be avoided. Experimental data at four different configurations of stress (6.3 to 36.5 ksi) and temperature (1200 to 1800°F) (sixteen data sets) for Hastelloy X is used to compare the models. Creep rupture data at seven temperature levels (600 to 1000°C) and a wide stress range (5 to 500 MPa) is used to analyze life prediction. The constants for each model are determined. Using one models’ constants and the derived relationships; the predictions of the other two models are generated. It is observed that the relationship generated curves agree with experimental data. Finally, it is demonstrated that using the derived relationships, the most useful aspects of each model can combined. An elliptical damage evolution curve is obtained for the Omega model. The final creep strain rate dependency problem of the Theta model can be avoided. It is observed that the Sinh model becomes more flexible and easy to implement.


2009 ◽  
Vol 610-613 ◽  
pp. 951-954 ◽  
Author(s):  
Ying Tong ◽  
Guo Zheng Quan ◽  
Bin Chen

The elasto-plastic behavior and the drawing limit of a kind of magnesium alloy tube were investigated based on the foundational theories of the larger deformation of material and continuum damage constitutive model. The corresponding finite element numerical algorithm was developed based on the constitutive model. The non-mandrel drawing limit graph according to the diameter at different tube thickness of an AZ31B tube with diameter 10mm at 250°C and drawing velocity 100mm/s was achieved, and safe & unsafe area got partitioned. The maximum damage value was evaluated to be 0.324 according to height reduction ratio limit and rigid-plastic FE analysis.


Author(s):  
K. E. Bagnoli ◽  
Z. A. Cater-Cyker ◽  
R. L. Holloman ◽  
C. A. Hay ◽  
S. Chavoshi ◽  
...  

Abstract Hydrogen attack is a degradation phenomenon that affects process equipment operated at elevated temperatures in an environment containing a high hydrogen partial pressure. It has been the subject of numerous studies over the years prompted by damage discovered during routine inspections, or incidents that have occurred in service. As non-destructive evaluation (NDE) techniques have improved, damage is being detected during earlier stages where safe operation may still be possible for some time period. This work focuses on the fitness for service evaluation of equipment containing high temperature hydrogen attack (HTHA) using a continuum damage mechanics (CDM) approach. The model can be employed to assess the loss in load bearing capacity due to damage in the form of widespread micro-fissuring and voids (i.e. up to the point of macro-crack coalescence). Experimental data from literature sources have been used to develop a relationship between damage rate and operational loading conditions. The predictions are compared to field experience to illustrate key aspects of this approach.


Sign in / Sign up

Export Citation Format

Share Document