New developments in image-based characterization of coated particle nuclear fuel

Author(s):  
Jeffery R. Price ◽  
Deniz Aykac ◽  
John D. Hunn ◽  
Andrew K. Kercher ◽  
Robert N. Morris
Author(s):  
P.A. Crozier ◽  
M. Pan

Heterogeneous catalysts can be of varying complexity ranging from single or double phase systems to complicated mixtures of metals and oxides with additives to help promote chemical reactions, extend the life of the catalysts, prevent poisoning etc. Although catalysis occurs on the surface of most systems, detailed descriptions of the microstructure and chemistry of catalysts can be helpful for developing an understanding of the mechanism by which a catalyst facilitates a reaction. Recent years have seen continued development and improvement of various TEM, STEM and AEM techniques for yielding information on the structure and chemistry of catalysts on the nanometer scale. Here we review some quantitative approaches to catalyst characterization that have resulted from new developments in instrumentation.HREM has been used to examine structural features of catalysts often by employing profile imaging techniques to study atomic details on the surface. Digital recording techniques employing slow-scan CCD cameras have facilitated the use of low-dose imaging in zeolite structure analysis and electron crystallography. Fig. la shows a low-dose image from SSZ-33 zeolite revealing the presence of a stacking fault.


2017 ◽  
Vol 105 (11) ◽  
Author(s):  
Thierry Wiss ◽  
Vincenzo V. Rondinella ◽  
Rudy J. M. Konings ◽  
Dragos Staicu ◽  
Dimitrios Papaioannou ◽  
...  

AbstractThe formation of the high burnup structure (HBS) is possibly the most significant example of the restructuring processes affecting commercial nuclear fuel in-pile. The HBS forms at the relatively cold outer rim of the fuel pellet, where the local burnup is 2–3 times higher than the average pellet burnup, under the combined effects of irradiation and thermo-mechanical conditions determined by the power regime and the fuel rod configuration. The main features of the transformation are the subdivision of the original fuel grains into new sub-micron grains, the relocation of the fission gas into newly formed intergranular pores, and the absence of large concentrations of extended defects in the fuel matrix inside the subdivided grains. The characterization of the newly formed structure and its impact on thermo-physical or mechanical properties is a key requirement to ensure that high burnup fuel operates within the safety margins. This paper presents a synthesis of the main findings from extensive studies performed at JRC-Karlsruhe during the last 25 years to determine properties and behaviour of the HBS. In particular, microstructural features, thermal transport, fission gas behaviour, and thermo-mechanical properties of the HBS will be discussed. The main conclusion of the experimental studies is that the HBS does not compromise the safety of nuclear fuel during normal operations.


2013 ◽  
Vol 430 ◽  
pp. 012113 ◽  
Author(s):  
M A Denecke ◽  
T Petersmann ◽  
R Marsac ◽  
K Dardenne ◽  
T Vitova ◽  
...  

Rare Metals ◽  
2006 ◽  
Vol 25 (6) ◽  
pp. 337-342 ◽  
Author(s):  
B LIU ◽  
T LIANG ◽  
C TANG

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