scholarly journals Approaching high-performance potassium-ion batteries via advanced design strategies and engineering

2019 ◽  
Vol 5 (5) ◽  
pp. eaav7412 ◽  
Author(s):  
Wenchao Zhang ◽  
Yajie Liu ◽  
Zaiping Guo

Potassium-ion batteries (PIBs) have attracted tremendous attention due to their low cost, fast ionic conductivity in electrolyte, and high operating voltage. Research on PIBs is still in its infancy, however, and achieving a general understanding of the drawbacks of each component and proposing research strategies for overcoming these problems are crucial for the exploration of suitable electrode materials/electrolytes and the establishment of electrode/cell assembly technologies for further development of PIBs. In this review, we summarize our current understanding in this field, classify and highlight the design strategies for addressing the key issues in the research on PIBs, and propose possible pathways for the future development of PIBs toward practical applications. The strategies and perspectives summarized in this review aim to provide practical guidance for an increasing number of researchers to explore next-generation and high-performance PIBs, and the methodology may also be applicable to developing other energy storage systems.

Author(s):  
Baixue Ouyang ◽  
Tao Chen ◽  
Ran Qin ◽  
Penggao Liu ◽  
Xiaowen Fan ◽  
...  

Titanium based oxides are pomising electrode materials due to the appropriate operating voltage, small strain expansion, fast rate capability, safety, and low cost. Carbon materials exhibit a high cyclic stability...


2020 ◽  
Vol 1 (1) ◽  
Author(s):  
Hanxiang Chen ◽  
Jianjian Yi ◽  
Zhao Mo ◽  
Yanhua Song ◽  
Wenshu Yang ◽  
...  

Abstract Photocatalysis technology has potential application in the field of energy and environment. How to expand visible light utilization and promote the separation efficiency of the carriers are the key issues for the high active photocatalysts preparation and future practical applications. In this work, a ternary metal sulfide Nb0.9Ta0.1S2 was prepared and used as an electron collector in the photocatalytic application. As a result, the generated electrons are quickly transferred to the surface of the composite to participate in the reaction. It was demonstrated that the photocatalytic activity of 2D-C3N4 was enhanced after the modification of Nb0.9Ta0.1S2. The Nb0.9Ta0.1S2/2D-C3N4 composite material was synthesized by solvothermal method. The composition of 5% Nb0.9Ta0.1S2/2D-C3N4 showed the highest H2 evolution rate of 1961.6 μmolg−1h−1, which was 6.6 times that of 2D-C3N4. The 15% Nb0.9Ta0.1S2/2D-C3N4 exhibited the best activity in Rhodamine B degradation rate of 97% in 2 h, which is 50% higher than that of 2D-C3N4. Nb0.9Ta0.1S2/2D-C3N4 can be used as electron trap to promote the effective separation of electron–hole pairs. This work provides benchmarks in exploring low-cost and efficient cocatalyst.


Author(s):  
Kathryn Holguin ◽  
Motahareh Mohammadiroudbari ◽  
Kaiqiang Qin ◽  
Chao Luo

Na-ion batteries (NIBs) are promising alternatives to Li-ion batteries (LIBs) due to the low cost, abundance, and high sustainability of sodium resources. However, the high performance of inorganic electrode materials...


2016 ◽  
Vol 4 (34) ◽  
pp. 13046-13052 ◽  
Author(s):  
Pin Liu ◽  
Yunming Li ◽  
Yong-Sheng Hu ◽  
Hong Li ◽  
Liquan Chen ◽  
...  

This study reports a hard carbon material derived from a waste biomass of corn cob and the influence of carbonized temperature on electrochemical performance. This study provides a promising anode material with low cost, high initial coulombic efficiency and excellent cycle performance, making sodium-ion batteries closer to practical applications.


2017 ◽  
Vol 43 (3) ◽  
pp. 2956-2961 ◽  
Author(s):  
Shuoqing Zhao ◽  
Tianmo Liu ◽  
Le Yu ◽  
Wen Zeng ◽  
Yangyang Zhang ◽  
...  

Author(s):  
Guixiang Wang ◽  
Haitao Zou ◽  
Xiaobo Zhu ◽  
Mei Ding ◽  
Chuankun Jia

Abstract Zinc-based redox flow batteries (ZRFBs) have been considered as ones of the most promising large-scale energy storage technologies owing to their low cost, high safety, and environmental friendliness. However, their commercial application is still hindered by a few key problems. First, the hydrogen evolution and zinc dendrite formation cause poor cycling life, of which needs to ameliorated or overcome by finding suitable anolytes. Second, the stability and energy density of catholytes are unsatisfactory due to oxidation, corrosion, and low electrolyte concentration. Meanwhile, highly catalytic electrode materials remain to be explored and the ion selectivity and cost efficiency of membrane materials demands further improvement. In this review, we summarize different types of ZRFBs according to their electrolyte environments including ZRFBs using neutral, acidic, and alkaline electrolytes, then highlight the advances of key materials including electrode and membrane materials for ZRFBs, and finally discuss the challenges and perspectives for the future development of high-performance ZRFBs.


2020 ◽  
Vol 4 (9) ◽  
pp. 4780-4788 ◽  
Author(s):  
Qiang Ma ◽  
Jiakang Qu ◽  
Xiang Chen ◽  
Zhuqing Zhao ◽  
Yan Zhao ◽  
...  

Low-cost feedstocks and rationally designed structures are the keys to determining the lithium-storage performance and practical applications of Si-based anodes for lithium-ion batteries (LIBs).


2019 ◽  
Vol 19 (6) ◽  
pp. 3610-3615 ◽  
Author(s):  
Lifeng Wang ◽  
Kaiyuan Wei ◽  
Pengjun Zhang ◽  
Hong Wang ◽  
Xiujun Qi ◽  
...  

Potassium-ion batteries (PIBs), as one of the alternatives to lithium-ion batteries (LIBs), have attracted considerable attention on account of the affluence and low-cost of potassium. Moreover, CoC2O4 and graphene oxide (GO) have been used very well in lithium-ion batteries. Hence, the hybrid CoC2O4/GO was investigated as a new anode material for PIBs. The hybrid CoC2O4/GO was synthesized by a facile and cheap method combined with supersonic dispersion. Electrochemical measurements reveal that the hybrid CoC2O4/GO delivered an excellent cycling stability of 166 mAh g−1 at 50 mA g−1 and a superior rate capability even at 1 A g−1. These results demonstrate although the cycle ability was insufficient for practical applications, transition-metal oxalates composites can still bring new hope to the development of PIBs.


Molecules ◽  
2019 ◽  
Vol 24 (12) ◽  
pp. 2263 ◽  
Author(s):  
Xiaoning Wang ◽  
Dan Wu ◽  
Xinhui Song ◽  
Wei Du ◽  
Xiangjin Zhao ◽  
...  

Polyaniline has been widely used in high-performance pseudocapacitors, due to its low cost, easy synthesis, and high theoretical specific capacitance. However, the poor mechanical properties of polyaniline restrict its further development. Compared with polyaniline, functionalized carbon materials have excellent physical and chemical properties, such as porous structures, excellent specific surface area, good conductivity, and accessibility to active sites. However, it should not be neglected that the specific capacity of carbon materials is usually unsatisfactory. There is an effective strategy to combine carbon materials with polyaniline by a hybridization approach to achieve a positive synergistic effect. After that, the energy storage performance of carbon/polyaniline hybridization material has been significantly improved, making it a promising and important electrode material for supercapacitors. To date, significant progress has been made in the synthesis of various carbon/polyaniline binary composite electrode materials. In this review, the corresponding properties and applications of polyaniline and carbon hybrid materials in the energy storage field are briefly reviewed. According to the classification of different types of functionalized carbon materials, this article focuses on the recent progress in carbon/polyaniline hybrid materials, and further analyzes their corresponding properties to provide guidance for the design, synthesis, and component optimization for high-performance supercapacitors.


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